4-BroMo-1-iodo-2-isopropylbenzene
- Product Name
- 4-BroMo-1-iodo-2-isopropylbenzene
- CAS No.
- 1147014-97-8
- Chemical Name
- 4-BroMo-1-iodo-2-isopropylbenzene
- Synonyms
- 5-BroMo-2-iodoisopropyl benzene;4-BroMo-1-iodo-2-isopropylbenzene;4-bromo-1-iodo-2-propan-2-ylbenzene;Benzene, 4-bromo-1-iodo-2-(1-methylethyl)-
- CBNumber
- CB02546049
- Molecular Formula
- C9H10BrI
- Formula Weight
- 324.98
- MOL File
- 1147014-97-8.mol
4-BroMo-1-iodo-2-isopropylbenzene Property
- Boiling point:
- 284.8±28.0 °C(Predicted)
- Density
- 1.828±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
- Appearance
- Yellow to orange Liquid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B802650
- Product name
- 5-Bromo-2-iodoisopropylbenzene
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- B802650
- Product name
- 5-Bromo-2-iodoisopropylbenzene
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- Y3717
- Product name
- 5-Bromo-2-iodoisopropylbenzene
- Packaging
- 1g
- Price
- $137
- Updated
- 2021/12/16
- Product number
- Y3717
- Product name
- 5-Bromo-2-iodoisopropylbenzene
- Packaging
- 5g
- Price
- $313
- Updated
- 2021/12/16
- Product number
- Y3717
- Product name
- 5-Bromo-2-iodoisopropylbenzene
- Packaging
- 25g
- Price
- $1049
- Updated
- 2021/12/16
4-BroMo-1-iodo-2-isopropylbenzene Chemical Properties,Usage,Production
Synthesis
19099-54-8
1147014-97-8
General procedure for the synthesis of 5-bromo-2-iodoisopropylbenzene from 2-isopropyliodobenzene: 1-iodo-2-isopropylbenzene (1.5 g, 6.1 mmol) was mixed with silver sulfate (1.0 g, 3.1 mmol), concentrated sulfuric acid (5.5 mL), water (0.6 mL) and bromine (0.3 mL, 6.4 mmol) to form a three-phase suspension. The reaction mixture was stirred at room temperature for 1 hour. Upon completion of the reaction, the mixture was poured into a mixture of ether (150 mL) and water (75 mL). The solids were removed by filtration and the organic and aqueous layers were separated. The organic layer was concentrated under vacuum and the residue was purified by preparative high performance liquid chromatography (HPLC) to afford the target product 5-bromo-2-iodoisopropylbenzene as a white solid (189 mg, 10% yield). [0257] 1H NMR (500 MHz, DMSO-d6) δ 1.18 (d, J = 6.8 Hz, 6H), 3.07 (qn, J = 6.8 Hz, 1H), 7.15 (dd, J = 8.4,2.5 Hz, 1H), 7.46 (d, J = 2.4 Hz, 1H), 7.75 (d, J = 8.4 Hz, 1H). 2D NOE (500 MHz, DMSO-d6): cross peak between δ 1.18 and 7.46.
References
[1] Patent: WO2009/55674, 2009, A1. Location in patent: Page/Page column 72-73
4-BroMo-1-iodo-2-isopropylbenzene Preparation Products And Raw materials
Raw materials
Preparation Products
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