3,5-DibroMo-biphenyl
- Product Name
- 3,5-DibroMo-biphenyl
- CAS No.
- 16372-96-6
- Chemical Name
- 3,5-DibroMo-biphenyl
- Synonyms
- PBB 14;3,5-DibroMo-biphenyl;3,5-Dibromo-1,1'-biphenyl;1,1'-Biphenyl, 3,5-dibromo-;3,5-DIBROMO-1-PHENYLBENZENE
- CBNumber
- CB02570622
- Molecular Formula
- C12H8Br2
- Formula Weight
- 312
- MOL File
- 16372-96-6.mol
3,5-DibroMo-biphenyl Property
- Melting point:
- 156-157℃
- Boiling point:
- 208 °C(Press: 15 Torr)
- Density
- 1.7197 g/cm3(Temp: 25 °C)
- refractive index
- 1.6541 (589.3 nm 25℃)
- storage temp.
- Sealed in dry,Room Temperature
- form
- crystalline solid
- color
- White
- InChI
- InChI=1S/C12H8Br2/c13-11-6-10(7-12(14)8-11)9-4-2-1-3-5-9/h1-8H
- InChIKey
- HIHYAKDOWUFGBK-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=CC=C2)=CC(Br)=CC(Br)=C1
- EPA Substance Registry System
- 1,1'-Biphenyl, 3,5-dibromo- (16372-96-6)
Safety
- HS Code
- 2903998090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- X7241
- Product name
- 3,5-Dibromo-1,1'-biphenyl
- Packaging
- 25g
- Price
- $371
- Updated
- 2021/12/16
- Product number
- CM243418
- Product name
- 3,5-Dibromo-1,1''-biphenyl
- Purity
- 95+%
- Packaging
- 100g
- Price
- $636
- Updated
- 2021/12/16
- Product number
- CD41001877
- Product name
- 3,5-Dibromo-1,1'-biphenyl
- Purity
- 97%
- Packaging
- 100g
- Price
- $673
- Updated
- 2021/12/16
- Product number
- CD41001877
- Product name
- 3,5-Dibromo-1,1'-biphenyl
- Purity
- 97%
- Packaging
- 500g
- Price
- $2024
- Updated
- 2021/12/16
- Product number
- CD41001877
- Product name
- 3,5-Dibromo-1,1'-biphenyl
- Purity
- 97%
- Packaging
- 1000g
- Price
- $3373
- Updated
- 2021/12/16
3,5-DibroMo-biphenyl Chemical Properties,Usage,Production
Chemical Properties
Colorless liquid
Synthesis
626-39-1
98-80-6
16372-96-6
A suspension of EtOH-H2O (3 mL, v:v = 1:1) with 1,3,5-tribromobenzene (1.0 mmol), phenylboronic acid (1.2 mmol), potassium carbonate (276 mg, 2.0 mmol), and Pd/HCCP-DABP catalyst (20 mg, 0.3 mol%) was added to the Schlenk tube. The system was evacuated and backfilled three times with nitrogen. The reaction mixture was stirred at 50 °C for 2.5 hours. After completion of the reaction, it was cooled to room temperature and extracted with dichloromethane (CH2Cl2). The organic phases were combined, dried with anhydrous sodium sulfate, concentrated under reduced pressure and purified by silica gel column chromatography to give 1-phenyl-3,5-dibromobenzene. The aqueous phase was filtered through filter paper, the solid was washed with CH2Cl2, and the recovered catalyst could be used in subsequent reactions.
References
[1] Reactive and Functional Polymers, 2017, vol. 110, p. 38 - 46
[2] Patent: KR2016/69021, 2016, A. Location in patent: Paragraph 0155-0157
[3] Journal of the American Chemical Society, 1990, vol. 112, # 22, p. 8024 - 8034
[4] Patent: KR2015/53913, 2015, A. Location in patent: Paragraph 0533-0535
[5] Patent: KR2015/127023, 2015, A. Location in patent: Paragraph 0409; 0560; 0561; 0562; 0563; 0564
3,5-DibroMo-biphenyl Preparation Products And Raw materials
Raw materials
Preparation Products
3,5-DibroMo-biphenyl Suppliers
- Tel
- --
- Fax
- --
- ardan@micro.lt
- Country
- Lithuania
- ProdList
- 206
- Advantage
- 30
View Lastest Price from 3,5-DibroMo-biphenyl manufacturers
- Product
- 3,5-DibroMo-biphenyl 16372-96-6
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-11-07
- Product
- 3,5-DibroMo-biphenyl 16372-96-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1ton
- Release date
- 2018-08-06