Di(1-adaMantyl)chlorophosphine

Product Name: Di(1-adaMantyl)chlorophosphine
CAS No.: 157282-19-4
Chemical Name: Di(1-adaMantyl)chlorophosphine
Synonyms: Bis(tric;Mifepristone Impurity 15;Diadamantylchlorophosphine;Di(1-adaMantyl)chlorophosphine;Bis(1-AdaMantyl)Chlorophosphine;Di(adamantan-1-yl)chlorophosphine;Di-1-adamantylchlorophosphine,97%;Bis(1-adamantyl)phosphinous chloride;Diadamantan-1-ylphosphinous chloride;DI-1-ADAMANTYLCHLOROPHOSPHINE,MIN.97%
CBNumber: CB02594929
Molecular Formula: C20H30ClP
Formula Weight: 336.88
MOL File: 157282-19-4.mol

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Di(1-adaMantyl)chlorophosphine Property

Melting point:: 168-173°C
Boiling point:: 413.3±12.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
color: white
Sensitive: moisture sensitive
InChI: InChI=1S/C20H30ClP/c21-22(19-7-13-1-14(8-19)3-15(2-13)9-19)20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18H,1-12H2
InChIKey: BVOJCPQWSXCCKU-UHFFFAOYSA-N
SMILES: P(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)Cl

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Safety

Hazard Codes: T,N
Risk Statements: 14-23/24/25-34-40-48/23-59
Safety Statements: 26-36/37/39-45-59
RIDADR: UN 3096 4.3(8) / PGII
WGK Germany: 3
HS Code: 2932190090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H261In contact with water releases flammable gas

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H351Suspected of causing cancer

H372Causes damage to organs through prolonged or repeated exposure

H373May cause damage to organs through prolonged or repeated exposure

H420Harms public health and the environment by destroying ozone in the upper atmosphere

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P502Refer to manufacturer/supplier for information on recovery/recycling

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 737267
Product name: Di(1-adamantyl)chlorophosphine
Purity: 97%
Packaging: 1g
Price: $303
Updated: 2025/07/31

Sigma-Aldrich

Product number: 737267
Product name: Di(1-adamantyl)chlorophosphine
Purity: 97%
Packaging: 250mg
Price: $139
Updated: 2023/06/20

Strem Chemicals

Product number: 15-1095
Product name: Di-1-adamantylchlorophosphine, min. 97%
Packaging: 250mg
Price: $100
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1095
Product name: Di-1-adamantylchlorophosphine, min. 97%
Packaging: 1g
Price: $296
Updated: 2024/03/01

AK Scientific

Product number: 7878AA
Product name: Di(adamantan-1-yl)chlorophosphine
Packaging: 250mg
Price: $179
Updated: 2021/12/16

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Di(1-adaMantyl)chlorophosphine Chemical Properties,Usage,Production

Synthesis

131211-27-3

157282-19-4

General procedure for the synthesis of bis(1-adamantyl)phosphonium chloride from di-1-adamantylphosphine: a solution of Ad2PH (10.5 g, 34.7 mmol) and 1,5-diazabicyclo[5.4.0]undec-5-ene (DBU, 6.12 cm3, 40.9 mmol) in toluene (250 cm3) was cooled to -10 °C. The phosgene solution (30.0 cm3, 56.7 mmol) was added slowly through a cannula and transferred through a measuring cylinder. The reaction produced a highly viscous light yellow suspension. To reduce the viscosity and to facilitate stirring, additional toluene (100 cm3) was added through the cannula. The reaction mixture was filtered through a cannula to give a yellow filtrate. The residue was washed with toluene (2 x 100 cm3), the washings were combined with the original filtrate and the volatiles were removed under vacuum to give a light yellow solid. The solid was washed with pentane (2 x 30 cm3, the wash solution was almost colorless), dried under vacuum and separated in a glove box to give a lemon yellow powdery product in 7.84 g yield, 67%.31P NMR chemical shift: δ= 139 ppm, purity 99%, molecular weight (FW) = 336.88.

References

[1] Chemistry - A European Journal, 2003, vol. 9, # 6, p. 1416 - 1425
[2] Organometallics, 2018, vol. 37, # 19, p. 3243 - 3247
[3] Phosphorus, Sulfur and Silicon and the Related Elements, 1995, vol. 102, # 1-4, p. 211 - 216
[4] Patent: US9802185, 2017, B2. Location in patent: Page/Page column 39
[5] Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 88, # 1-4, p. 241 - 244

Di(1-adaMantyl)chlorophosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Di(1-adaMantyl)chlorophosphine Suppliers

China 74 United Kingdom 2 United States 5 Global 81

BeiJing Greenchem Technology Co.,Ltd.

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View Lastest Price from Di(1-adaMantyl)chlorophosphine manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: Di(1-adaMantyl)chlorophosphine 157282-19-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-02-22

Shaanxi Dideu New Materials Co. Ltd

Product: Di(1-adaMantyl)chlorophosphine 157282-19-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-03-01

Career Henan Chemical Co

Product: Di(1-adaMantyl)chlorophosphine 157282-19-4
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: g/kg/T
Release date: 2019-12-18

157282-19-4, Di(1-adaMantyl)chlorophosphineRelated Search:

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Di(1-adaMantyl)chlorophosphine

Di(adamantan-1-yl)chlorophosphine

Bis(1-AdaMantyl)Chlorophosphine

Di-1-adaMantylchlorophosphine, Min. 97%

Bis(1-adamantyl)phosphinous chloride

Diadamantylchlorophosphine

Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphinous chloride

DI-1-ADAMANTYLCHLOROPHOSPHINE,MIN.97%

Bis(tric

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Mifepristone Impurity 15

Diadamantan-1-ylphosphinous chloride

Di-1-adamantylchlorophosphine,97%

157282-19-4

C20H30ClP

Achiral Phosphine

Alkyl Phosphine

P-Cl