DI-1-ADAMANTYLPHOSPHINE

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Product Name: DI-1-ADAMANTYLPHOSPHINE
CAS No.: 131211-27-3
Chemical Name: DI-1-ADAMANTYLPHOSPHINE
Synonyms: Diadamantylphosphine;DI-1-ADAMANTYLPHOSPHINE;Bis(adamant-1-yl)phosphine;Di-1-adamantylphosphine>Di-1-adamantylphosphine,97%;Di(adamantan-1-yl)phosphine;Di-1-adamantylphosphine 97%;Bis(1-adamantyl)phosphine, 98%;Di-1-adamantylphosphine,min.97%;Di-1-adamantylphosphine, min. 97%
CBNumber: CB4371982
Molecular Formula: C20H31P
Formula Weight: 302.43
MOL File: 131211-27-3.mol

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DI-1-ADAMANTYLPHOSPHINE Property

Melting point:: 181-185 °C
Boiling point:: 407.8±12.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: white
Sensitive: air sensitive
InChI: InChI=1S/C20H31P/c1-13-2-15-3-14(1)8-19(7-13,9-15)21-20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18,21H,1-12H2
InChIKey: RRRZOLBZYZWQBZ-UHFFFAOYSA-N
SMILES: P(C12CC3CC(CC(C3)C1)C2)C12CC3CC(CC(C3)C1)C2

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Safety

Hazard Codes: T
Risk Statements: 23/24/25-36/37/38
Safety Statements: 36/37/39-45
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
HS Code: 2931.90.9051
HazardClass: 6.1
PackingGroup: Ⅲ

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 695823
Product name: Di-1-adamantylphosphine
Purity: 97%
Packaging: 500mg
Price: $134.32
Updated: 2025/07/31

Sigma-Aldrich

Product number: 695823
Product name: Di-1-adamantylphosphine
Purity: 97%
Packaging: 2g
Price: $517.04
Updated: 2025/07/31

TCI Chemical

Product number: D4781
Product name: Di-1-adamantylphosphine
Purity: >95.0%(GC)
Packaging: 200mg
Price: $43
Updated: 2025/07/31

TCI Chemical

Product number: D4781
Product name: Di-1-adamantylphosphine
Purity: >95.0%(GC)
Packaging: 1g
Price: $126
Updated: 2025/07/31

Strem Chemicals

Product number: 15-0954
Product name: Di-1-adamantylphosphine, min. 97%
Packaging: 250mg
Price: $69
Updated: 2024/03/01

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DI-1-ADAMANTYLPHOSPHINE Chemical Properties,Usage,Production

Appearance

White Powder

Uses

Di-1-adamantylphosphine is a useful research chemical.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Synthesis

126683-99-6

131211-27-3

The general procedure for the synthesis of di-1-adamantylphosphine using bis(1-adamantyl)phosphinic chloride as starting material was as follows: at -10 °C, LiAlH4 (2.54 g, 67.0 mmol) was slowly added to a cooled solution of bis(1-adamantyl)phosphinic chloride (10.00 g, 28.3 mmol) dissolved in dry THF (120 cm3) over 90 min. The reaction mixture was gradually warmed to room temperature and stirred continuously for 20 hours. Subsequently, the gray suspension was re-cooled to -10 °C and a mixed solution consisting of concentrated hydrochloric acid (5 cm3) and degassed water (50 cm3) was slowly added via syringe (due to the exothermic nature of the reaction, the initial rate of addition needed to be very slow), at which point a two-phase system was formed, with solids visible in the lower phase. To further improve the phase separation, concentrated hydrochloric acid (5 cm3) was added. The upper organic phase was removed using a flat cannula and the remaining organic phase was dried with MgSO4 and filtered through a cannula. Volatiles were removed under vacuum to give a white powdery product which was separated in a glove box. The final product yield was 6.00 g in 70% yield. The product showed a single peak (δ=17 ppm) by 31P NMR and was 100% pure. The molecular weight of the product was 302.44.

References

[1] Phosphorus, Sulfur and Silicon and the Related Elements, 1995, vol. 102, # 1-4, p. 211 - 216
[2] Phosphorus, Sulfur and Silicon and the Related Elements, 1993, vol. 81, # 1-4, p. 141 - 148
[3] Organometallics, 2018, vol. 37, # 19, p. 3243 - 3247
[4] Patent: US9802185, 2017, B2. Location in patent: Page/Page column 38; 39
[5] J. Gen. Chem. USSR (Engl. Transl.), 1990, vol. 60, # 8.1, p. 1603 - 1606

DI-1-ADAMANTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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DI-1-ADAMANTYLPHOSPHINE Suppliers

Americas 1 Belgium 1 China 145 Europe 1 France 1 Germany 3 India 2 Japan 2 Russia 1 Switzerland 1 Ukraine 1 United States 13 Global 172

Beijing VSciChem Technology Co., Ltd.

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Energy Chemical

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View Lastest Price from DI-1-ADAMANTYLPHOSPHINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: DI-1-ADAMANTYLPHOSPHINE 131211-27-3
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-17

XINXIANG RUNYU MATERIAL CO., LTD.

Product: DI-1-ADAMANTYLPHOSPHINE 131211-27-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 0.98
Supply Ability: 500kg
Release date: 2021-12-02

Shaanxi Dideu Medichem Co. Ltd

Product: Bis(1-adamantyl)phosphine 131211-27-3
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

131211-27-3, DI-1-ADAMANTYLPHOSPHINERelated Search:

4-tert-Butyltoluene N-Methylpropionamide 2-Bromoethanol DI-I-PROPYLPHOSPHINE Diphenyl-2-pyridylphosphine Di(1-adaMantyl)chlorophosphine DI-1-ADAMANTYLPHOSPHINIC CHLORIDE Di(1-adamantyl)-n-butylphosphine hydriodide BENZYLDI-1-ADAMANTYLPHOSPHINE Butyldi-1-adamantylphosphine DI-1-ADAMANTYLPHOSPHINE CYCLOHEXYLDI(1-ADAMANTYL)PHOSPHINE DI-1-ADAMANTYLPHOSPHINE OXIDE,Di-1-adamantylphosphine oxide, min. 90%

DI-1-ADAMANTYLPHOSPHINE

Bis(adamant-1-yl)phosphine, Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine

Di-1-adamantylphosphine, min. 97%

Bis(1-adamantyl)phosphine, 98%

Di-1-adamantylphosphine 97%

Di-1-adamantylphosphine,min.97%

Bis(adamant-1-yl)phosphine

Diadamantylphosphine

Di(adamantan-1-yl)phosphine

Di-1-adamantylphosphine,97%

Di-1-adamantylphosphine&gt

Phosphine, bis(tricyclo[3.3.1.13,7]dec-1-yl)-

131211-27-3

133211-27-3

C10H152PH

C20H31P

P-H

Achiral Phosphine

Alkyl Phosphine

organophosphine ligand