ChemicalBook > CAS DataBase List > DI-1-ADAMANTYLPHOSPHINE

DI-1-ADAMANTYLPHOSPHINE

Appearance

Product Name: DI-1-ADAMANTYLPHOSPHINE
CAS No.: 131211-27-3
Chemical Name: DI-1-ADAMANTYLPHOSPHINE
Synonyms: Diadamantylphosphine;DI-1-ADAMANTYLPHOSPHINE;Bis(adamant-1-yl)phosphine;Di-1-adamantylphosphine>Di-1-adamantylphosphine,97%;Di(adamantan-1-yl)phosphine;Di-1-adamantylphosphine 97%;Bis(1-adamantyl)phosphine, 98%;Di-1-adamantylphosphine,min.97%;Di-1-adamantylphosphine, min. 97%
CBNumber: CB4371982
Molecular Formula: C20H31P
Formula Weight: 302.43
MOL File: 131211-27-3.mol

Less

DI-1-ADAMANTYLPHOSPHINE Property

Melting point:: 181-185 °C
Boiling point:: 407.8±12.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: white
Sensitive: air sensitive
InChI: InChI=1S/C20H31P/c1-13-2-15-3-14(1)8-19(7-13,9-15)21-20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18,21H,1-12H2
InChIKey: RRRZOLBZYZWQBZ-UHFFFAOYSA-N
SMILES: P(C12CC3CC(CC(C3)C1)C2)C12CC3CC(CC(C3)C1)C2

Less

Safety

Hazard Codes: T
Risk Statements: 23/24/25-36/37/38
Safety Statements: 36/37/39-45
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
HS Code: 2931.90.9051
HazardClass: 6.1
PackingGroup: Ⅲ

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 695823
Product name: Di-1-adamantylphosphine
Purity: 97%
Packaging: 500mg
Price: $134.32
Updated: 2025/07/31

Sigma-Aldrich

Product number: 695823
Product name: Di-1-adamantylphosphine
Purity: 97%
Packaging: 2g
Price: $517.04
Updated: 2025/07/31

TCI Chemical

Product number: D4781
Product name: Di-1-adamantylphosphine
Purity: >95.0%(GC)
Packaging: 200mg
Price: $43
Updated: 2025/07/31

TCI Chemical

Product number: D4781
Product name: Di-1-adamantylphosphine
Purity: >95.0%(GC)
Packaging: 1g
Price: $126
Updated: 2025/07/31

Strem Chemicals

Product number: 15-0954
Product name: Di-1-adamantylphosphine, min. 97%
Packaging: 250mg
Price: $69
Updated: 2024/03/01

Less

DI-1-ADAMANTYLPHOSPHINE Chemical Properties,Usage,Production

Appearance

White Powder

Uses

Di-1-adamantylphosphine is a useful research chemical.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Synthesis

126683-99-6

131211-27-3

The general procedure for the synthesis of di-1-adamantylphosphine using bis(1-adamantyl)phosphinic chloride as starting material was as follows: at -10 °C, LiAlH4 (2.54 g, 67.0 mmol) was slowly added to a cooled solution of bis(1-adamantyl)phosphinic chloride (10.00 g, 28.3 mmol) dissolved in dry THF (120 cm3) over 90 min. The reaction mixture was gradually warmed to room temperature and stirred continuously for 20 hours. Subsequently, the gray suspension was re-cooled to -10 °C and a mixed solution consisting of concentrated hydrochloric acid (5 cm3) and degassed water (50 cm3) was slowly added via syringe (due to the exothermic nature of the reaction, the initial rate of addition needed to be very slow), at which point a two-phase system was formed, with solids visible in the lower phase. To further improve the phase separation, concentrated hydrochloric acid (5 cm3) was added. The upper organic phase was removed using a flat cannula and the remaining organic phase was dried with MgSO4 and filtered through a cannula. Volatiles were removed under vacuum to give a white powdery product which was separated in a glove box. The final product yield was 6.00 g in 70% yield. The product showed a single peak (δ=17 ppm) by 31P NMR and was 100% pure. The molecular weight of the product was 302.44.

References

[1] Phosphorus, Sulfur and Silicon and the Related Elements, 1995, vol. 102, # 1-4, p. 211 - 216
[2] Phosphorus, Sulfur and Silicon and the Related Elements, 1993, vol. 81, # 1-4, p. 141 - 148
[3] Organometallics, 2018, vol. 37, # 19, p. 3243 - 3247
[4] Patent: US9802185, 2017, B2. Location in patent: Page/Page column 38; 39
[5] J. Gen. Chem. USSR (Engl. Transl.), 1990, vol. 60, # 8.1, p. 1603 - 1606

DI-1-ADAMANTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

Less

DI-1-ADAMANTYLPHOSPHINE Suppliers

Americas 1 Belgium 1 China 146 Europe 1 France 1 Germany 3 India 2 Japan 2 Russia 1 Switzerland 1 Ukraine 1 United States 13 Global 173

Beijing VSciChem Technology Co., Ltd.

Tel: 13811761079
Email: vscichem@163.com
Country: China
ProdList: 263
Advantage: 64

Xinxiang Runyu Material Co., Ltd.

Tel: 166-166-37336996 15690792173
Fax: 0373-7759608
Email: chenxi.song@runvmat.com
Country: China
ProdList: 285
Advantage: 55

BeiJing Greenchem Technology Co.,Ltd.

Tel: 131-21959385 18804271668
Fax: 010-62925455
Email: chemrocking@bjgreenchem.com
Country: China
ProdList: 273
Advantage: 58

Jiaxing Carry Chemical Co.,Ltd.

Tel: 18258318278
Fax: 0573-82758956
Email: info@carrybiotech.com
Country: China
ProdList: 38
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Beijing HwrkChemical Technology Co., Ltd

Tel: 18515581800 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 9400
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9309
Advantage: 66

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18729
Advantage: 57

Tangshan Moneide Trading Co., Ltd.

Tel: 0315-8309571 15633399667
Fax: +86-315-7726572
Email: sales@moneidechem.com
Country: China
ProdList: 704
Advantage: 57

Nanjin Cynthia chemicals Technology Co.,Ltd

Tel: 0550-5618439 15951861180
Fax: 0550-5610690
Email: cynthiachem@163.com
Country: China
ProdList: 291
Advantage: 62

ZhengZhou HuaWen Chemical Co.Ltd

Tel: 0370-2785118 17550508557
Fax: QQ：3470079902
Email: 675141927@qq.com
Country: China
ProdList: 3199
Advantage: 55

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9895
Advantage: 58

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 150-2103-5486 18017383231
Fax: qq：2817624287
Email: 983544897@qq.com
Country: China
ProdList: 9342
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 13167063860
Fax: 021-50323701
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Huainan Kedi Chemical Factory

Tel: 0554-2106669
Fax: 0554-2666215
Email: sales1@kedichem.com
Country: China
ProdList: 4924
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Chengdu HuaXia Chemical Reagent Co. Ltd

Tel: 400-1166-196 13458535857
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 13350
Advantage: 58

Finetech Industry Limited

Tel: 027-87465837 19945049750
Fax: 027-8777-2287
Email: sales@finetechnology-ind.com
Country: China
ProdList: 9637
Advantage: 58

Credit Asia Chemical Co., Ltd.

Tel: +86 (21) 61124340
Fax: +86 (21) 6129-4103
Country: China
ProdList: 9756
Advantage: 58

Cool Pharm, Ltd

Tel: 021-60455363 18019463053
Fax: 50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12346
Advantage: 58

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51395
Advantage: 80

Watson Biotechnology Co.,Ltd

Tel: 027-59207879 1972026995 18140587686
Fax: QQ：1972026995
Email: sales@3600chem.com
Country: China
ProdList: 4446
Advantage: 55

Struchem Co., Ltd.

Tel: 0512-63009836 18994340901
Fax: 0512-63006936
Email: helen@struchem.com
Country: China
ProdList: 3981
Advantage: 60

Shanghai Uchem Inc.

Tel: 15618758386; 15618758386
Fax: QQ:3004479444
Email: sales3@myuchem.com
Country: China
ProdList: 1988
Advantage: 55

Zhengzhou Alfachem Co., Ltd.

Tel: 0371-53765687 18937137882
Fax: QQ:2885373884
Email: 2853979813@qq.com
Country: China
ProdList: 7991
Advantage: 55

Chengdu RunZeBenTu Chemical Co., Ltd

Tel: 028-88469284 18000562381
Email: rzbtsj@163.com
Country: China
ProdList: 9951
Advantage: 56

Codow Chemical Co.,Ltd.

Tel: 18620099427
Fax: +86-20-62619665
Email: amy@howeipharm.com
Country: China
ProdList: 6687
Advantage: 55

Shanghai Qiao Chemical Science Co., Ltd

Tel: 021-58892003
Email: info@qiaochem.com
Country: China
ProdList: 6059
Advantage: 65

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.

Tel: 0371-65511006 18625597674
Email: sales@kingorgchem.com
Country: China
ProdList: 976
Advantage: 55

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71826
Advantage: 60

Panjin Infinity Scientific CO. LTD

Tel: 400-1062016 18612996721
Fax: QQ25788917
Email: hao@infsci.com
Country: China
ProdList: 327
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2886750 13927877953
Fax: 0751-2886750
Email: 3005811397@qq.com
Country: China
ProdList: 13305
Advantage: 58

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2280
Advantage: 58

Taian Jiaye Biotechnology Co.Ltd

Tel: 13127280945
Email: 285424065@qq.com
Country: China
ProdList: 9976
Advantage: 55

Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
Country: China
ProdList: 9998
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 021-021-52271985 17721149837
Fax: +86 (21) 52271987
Email: sales@9dingchem.com
Country: China
ProdList: 19800
Advantage: 60

Jiaxing Deyi Chemical Co., Ltd.

Tel: 86-0573-85866609 13325730825
Fax: 0573-85866609
Email: 945717149@qq.com
Country: China
ProdList: 8595
Advantage: 58

Shanghai Zhen Li Biological Technology Co., Ltd

Tel: 021-16621358918; 18516310516
Fax: 13045646768
Email: zhenlipharma888@163.com
Country: China
ProdList: 19035
Advantage: 58

Aikon International Limited

Tel: 025-58859352 18068836627
Fax: (5)02557626880
Email: dt3@aikonchem.com
Country: China
ProdList: 15493
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 400821072
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 25000
Advantage: 58

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400-6387771-6039 18920764717
Email: sales@heowns.com
Country: China
ProdList: 23771
Advantage: 60

Less

View Lastest Price from DI-1-ADAMANTYLPHOSPHINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: DI-1-ADAMANTYLPHOSPHINE 131211-27-3
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-17

XINXIANG RUNYU MATERIAL CO., LTD.

Product: DI-1-ADAMANTYLPHOSPHINE 131211-27-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 0.98
Supply Ability: 500kg
Release date: 2021-12-02

Shaanxi Dideu Medichem Co. Ltd

Product: Bis(1-adamantyl)phosphine 131211-27-3
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

131211-27-3, DI-1-ADAMANTYLPHOSPHINERelated Search:

4-tert-Butyltoluene N-Methylpropionamide 2-Bromoethanol DI-I-PROPYLPHOSPHINE Diphenyl-2-pyridylphosphine Di(1-adaMantyl)chlorophosphine DI-1-ADAMANTYLPHOSPHINIC CHLORIDE Di(1-adamantyl)-n-butylphosphine hydriodide BENZYLDI-1-ADAMANTYLPHOSPHINE Butyldi-1-adamantylphosphine DI-1-ADAMANTYLPHOSPHINE CYCLOHEXYLDI(1-ADAMANTYL)PHOSPHINE DI-1-ADAMANTYLPHOSPHINE OXIDE,Di-1-adamantylphosphine oxide, min. 90%

DI-1-ADAMANTYLPHOSPHINE

Bis(adamant-1-yl)phosphine, Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine

Di-1-adamantylphosphine, min. 97%

Bis(1-adamantyl)phosphine, 98%

Di-1-adamantylphosphine 97%

Di-1-adamantylphosphine,min.97%

Bis(adamant-1-yl)phosphine

Diadamantylphosphine

Di(adamantan-1-yl)phosphine

Di-1-adamantylphosphine,97%

Di-1-adamantylphosphine&gt

Phosphine, bis(tricyclo[3.3.1.13,7]dec-1-yl)-

131211-27-3

133211-27-3

C10H152PH

C20H31P

P-H

Achiral Phosphine

Alkyl Phosphine

organophosphine ligand