Di(1-adaMantyl)chlorophosphine
- Product Name
- Di(1-adaMantyl)chlorophosphine
- CAS No.
- 157282-19-4
- Chemical Name
- Di(1-adaMantyl)chlorophosphine
- Synonyms
- Bis(tric;Mifepristone Impurity 15;Diadamantylchlorophosphine;Di(1-adaMantyl)chlorophosphine;Bis(1-AdaMantyl)Chlorophosphine;Di(adamantan-1-yl)chlorophosphine;Di-1-adamantylchlorophosphine,97%;Bis(1-adamantyl)phosphinous chloride;Diadamantan-1-ylphosphinous chloride;DI-1-ADAMANTYLCHLOROPHOSPHINE,MIN.97%
- CBNumber
- CB02594929
- Molecular Formula
- C20H30ClP
- Formula Weight
- 336.88
- MOL File
- 157282-19-4.mol
Di(1-adaMantyl)chlorophosphine Property
- Melting point:
- 168-173°C
- Boiling point:
- 413.3±12.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- solid
- color
- white
- Sensitive
- moisture sensitive
- InChI
- InChI=1S/C20H30ClP/c21-22(19-7-13-1-14(8-19)3-15(2-13)9-19)20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18H,1-12H2
- InChIKey
- BVOJCPQWSXCCKU-UHFFFAOYSA-N
- SMILES
- P(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)Cl
Safety
- Hazard Codes
- T,N
- Risk Statements
- 14-23/24/25-34-40-48/23-59
- Safety Statements
- 26-36/37/39-45-59
- RIDADR
- UN 3096 4.3(8) / PGII
- WGK Germany
- 3
- HS Code
- 2932190090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H261In contact with water releases flammable gas
H314Causes severe skin burns and eye damage
H317May cause an allergic skin reaction
H351Suspected of causing cancer
H372Causes damage to organs through prolonged or repeated exposure
H373May cause damage to organs through prolonged or repeated exposure
H420Harms public health and the environment by destroying ozone in the upper atmosphere
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P502Refer to manufacturer/supplier for information on recovery/recycling
N-Bromosuccinimide Price
- Product number
- 737267
- Product name
- Di(1-adamantyl)chlorophosphine
- Purity
- 97%
- Packaging
- 1g
- Price
- $303
- Updated
- 2025/07/31
- Product number
- 737267
- Product name
- Di(1-adamantyl)chlorophosphine
- Purity
- 97%
- Packaging
- 250mg
- Price
- $139
- Updated
- 2023/06/20
- Product number
- 15-1095
- Product name
- Di-1-adamantylchlorophosphine, min. 97%
- Packaging
- 250mg
- Price
- $100
- Updated
- 2024/03/01
- Product number
- 15-1095
- Product name
- Di-1-adamantylchlorophosphine, min. 97%
- Packaging
- 1g
- Price
- $296
- Updated
- 2024/03/01
- Product number
- 7878AA
- Product name
- Di(adamantan-1-yl)chlorophosphine
- Packaging
- 250mg
- Price
- $179
- Updated
- 2021/12/16
Di(1-adaMantyl)chlorophosphine Chemical Properties,Usage,Production
Synthesis
131211-27-3
157282-19-4
General procedure for the synthesis of bis(1-adamantyl)phosphonium chloride from di-1-adamantylphosphine: a solution of Ad2PH (10.5 g, 34.7 mmol) and 1,5-diazabicyclo[5.4.0]undec-5-ene (DBU, 6.12 cm3, 40.9 mmol) in toluene (250 cm3) was cooled to -10 °C. The phosgene solution (30.0 cm3, 56.7 mmol) was added slowly through a cannula and transferred through a measuring cylinder. The reaction produced a highly viscous light yellow suspension. To reduce the viscosity and to facilitate stirring, additional toluene (100 cm3) was added through the cannula. The reaction mixture was filtered through a cannula to give a yellow filtrate. The residue was washed with toluene (2 x 100 cm3), the washings were combined with the original filtrate and the volatiles were removed under vacuum to give a light yellow solid. The solid was washed with pentane (2 x 30 cm3, the wash solution was almost colorless), dried under vacuum and separated in a glove box to give a lemon yellow powdery product in 7.84 g yield, 67%.31P NMR chemical shift: δ= 139 ppm, purity 99%, molecular weight (FW) = 336.88.
References
[1] Chemistry - A European Journal, 2003, vol. 9, # 6, p. 1416 - 1425
[2] Organometallics, 2018, vol. 37, # 19, p. 3243 - 3247
[3] Phosphorus, Sulfur and Silicon and the Related Elements, 1995, vol. 102, # 1-4, p. 211 - 216
[4] Patent: US9802185, 2017, B2. Location in patent: Page/Page column 39
[5] Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 88, # 1-4, p. 241 - 244
Di(1-adaMantyl)chlorophosphine Preparation Products And Raw materials
Raw materials
Preparation Products
Di(1-adaMantyl)chlorophosphine Suppliers
- Tel
- 44-20819178-90 02081917890
- Fax
- (0)2080432064
- info@novachemistry.com
- Country
- United Kingdom
- ProdList
- 4381
- Advantage
- 58
- Tel
- --
- Fax
- --
- enquiries@fluorochem.co.uk
- Country
- United Kingdom
- ProdList
- 6401
- Advantage
- 74
View Lastest Price from Di(1-adaMantyl)chlorophosphine manufacturers
- Product
- Di(1-adaMantyl)chlorophosphine 157282-19-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2025-02-22
- Product
- Di(1-adaMantyl)chlorophosphine 157282-19-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2025-03-01
- Product
- Di(1-adaMantyl)chlorophosphine 157282-19-4
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- g/kg/T
- Release date
- 2019-12-18