1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
- Product Name
- 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
- CAS No.
- 1078153-58-8
- Chemical Name
- 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
- Synonyms
- DK7571;DK7240;H4TCPB;1,2,4,5-Tetrakis(4-carboxyphenyl);1,2,4,5-Tetrakis(4-carboxyphenyl)benzene;4,4',4'',4'''-benzene-1,2,4,5-tetrayl-tetrabenzoic acid;4',5'-Bis(4-carboxyphenyl)-[1,1':2',1''-terphenyl]-4,4''-dicarboxylic acid;1,2,4,5-Tetrakis(4-carboxyphenyl)benzene contains up to 6 wt. % water, >=98%;[1,1':2',1''-Terphenyl]-4,4''-dicarboxylic acid, 4',5'-bis(4-carboxyphenyl)-;1,2,4,5-Tetrakis(4-carboxyphenyl)benzene (This product is unavailable in the U.S.)
- CBNumber
- CB02662642
- Molecular Formula
- C34H22O8
- Formula Weight
- 558.53
- MOL File
- 1078153-58-8.mol
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene Property
- Boiling point:
- 792.8±60.0 °C(Predicted)
- Density
- 1.393±0.06 g/cm3(Predicted)
- Flash point:
- 85 °C
- pka
- 3.24±0.10(Predicted)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- SIK2110-10
- Product name
- 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene-H4TCPB
- Purity
- ≥97%
- Packaging
- 250MG
- Price
- $245
- Updated
- 2024/03/01
- Product number
- SIK2110-10
- Product name
- 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene-H4TCPB
- Purity
- ≥97%
- Packaging
- 1G
- Price
- $698
- Updated
- 2024/03/01
- Product number
- 715298
- Product name
- 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
- Purity
- contains up to 6 wt. % water, ≥98%
- Packaging
- 1G
- Price
- $246
- Updated
- 2023/06/20
- Product number
- CHM0114927
- Product name
- 1,2,4,5-TETRAKIS(4-CARBOXYPHENYL)BENZENE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $767.07
- Updated
- 2021/12/16
- Product number
- A1154801
- Product name
- 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
- Purity
- 98%
- Packaging
- 5g
- Price
- $327
- Updated
- 2021/12/16
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene Chemical Properties,Usage,Production
Uses
Selected Applications of MOFs in Sustainable Energy Technologies
General Description
This product has been enhanced for energy efficiency.
Synthesis
a) 100 ml of p-tolylmagnesium bromide (1M in THF, 100 mmol) was added under nitrogen to a flask containing 5g of (9.07 mmol). The mixture was stirred at nitrogen to a flask containing 5g of (9.07 mmol). The mixture was stirred at room temperature for 15 hours (gray suspension). The reaction was poured on ice then 50 ml of 6M HCl was added. The mixture was extracted with THF (3X 200ml). The organics were combined and the solvent was removed via rotary evaporation. The solid was then washed with hexanes and cold acetone. Isolated yield: 2.75g, 70% based on hexabromobenzene. yield: 2.75g, 70% 1H NMR (CDCl3): δ 2.32 (s, 12H), 7.04 (d, 8H), 7.12 (d, 8H), 7.45 (s, 2H). 13C NMR (CDCl3): δ 128.9, 130.0, 133.3, 136.4, 138.4, 139.5 ppm.(b) An amount of 2g from (a) was placed in a 100 ml teflon lined vessel. An amount of 24 ml of water and 6 ml of HNO3 were then added. The vessel was sealed and heated at 180 °C for 24 hrs. The resulting solid was collected by filtration and washed with THF/CHCl3 (7:3). Isolated yield: 1.85g, 75%. yield: 1.85g, 75%
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene manufacturers
- Product
- 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene 1078153-58-8
- Price
- US $8.66/KG
- Min. Order
- 1KG
- Purity
- 95.0%-99.0%
- Supply Ability
- 1kg-100kg
- Release date
- 2020-03-11
- Product
- 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene 1078153-58-8
- Price
- US $2.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- ask
- Release date
- 2020-01-08