3-DroMo-9,9'-spirobifluorene

Product Name: 3-DroMo-9,9'-spirobifluorene
CAS No.: 1361227-58-8
Chemical Name: 3-DroMo-9,9'-spirobifluorene
Synonyms: 3-bromo-9,9'-spirobi[fluorene];3-BSF;3-bromo-SBF;3-DroMo-9,9'-spirobifluorene;3-Bromo-9,9'-Spiro[9H-Fluorene];3-Bromo-9,9'-spirobi[9H-fluorene;3-bromo-9,9'-spirobi(9h-fluorene);9,9'-Spirobi[9H-fluorene], 3-bromo-;(S)-1-(dicyclohexylphosphino)-2-[(r)-1-(dimethylamino)
CBNumber: CB02735395
Molecular Formula: C25H15Br
Formula Weight: 395.29
MOL File: 1361227-58-8.mol

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3-DroMo-9,9'-spirobifluorene Property

Boiling point:: 508.6±29.0 °C(Predicted)
Density: 1.52±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Appearance: White to off-white Solid
InChI: InChI=1S/C25H15Br/c26-16-13-14-24-20(15-16)19-9-3-6-12-23(19)25(24)21-10-4-1-7-17(21)18-8-2-5-11-22(18)25/h1-15H
InChIKey: UIUSRIQSFHZPSQ-UHFFFAOYSA-N
SMILES: C12(C3=C(C=CC=C3)C3=C1C=CC=C3)C1=C(C=CC=C1)C1=C2C=CC(Br)=C1

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: D678988
Product name: 3-Bromo-9,9-Spirobifluorene
Packaging: 50mg
Price: $45
Updated: 2021/12/16

AK Scientific

Product number: 9540AL
Product name: 3-DroMo-9,9'-spirobifluorene
Packaging: 1g
Price: $145
Updated: 2021/12/16

Ambeed

Product number: A188263
Product name: 3-Bromo-9,9'-spirobi[fluorene]
Purity: 98%
Packaging: 100mg
Price: $18
Updated: 2021/12/16

Arctom

Product number: AS016107
Product name: 3-Bromo-9,9'-spirobi[fluorene]
Purity: 98%
Packaging: 100mg
Price: $18
Updated: 2021/12/16

Ambeed

Product number: A188263
Product name: 3-Bromo-9,9'-spirobi[fluorene]
Purity: 98%
Packaging: 250mg
Price: $25
Updated: 2021/12/16

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3-DroMo-9,9'-spirobifluorene Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Synthesis

2052-07-5

2041-19-2

1361227-58-8

The synthesis of the compound was carried out in two steps. Step 1: 2-Bromobiphenyl (1.05 eq., 4.0 g, 16.5 mmol) was dissolved in anhydrous ether (102 mL), and after the solution was cooled to -60 °C, n-butyllithium (n-BuLi, 1.16 eq.) was added slowly and dropwise. After maintaining this temperature for 10 minutes, a white precipitate was observed to be generated and the reaction mixture was subsequently warmed to room temperature to dissolve the precipitate. Next, 3-bromo-9H-fluoren-9-one was added and the reaction mixture was stirred at 45 °C overnight. After completion of the reaction, the reaction was quenched by adding 5% aqueous ammonium chloride solution (260 mL) and the organic phase was extracted with ether to give the alcohol intermediate (7.0 g). Step 2: The above alcohol intermediate was dissolved in acetic acid (141 mL) and hydrolyzed by adding 10% HCl/dioxane solution (78 mL, 10 mol%, 20 eq.). After evaporation to remove the solvent, the residual solid was purified by normal-phase fast chromatography to finally obtain 3-bromo-9,9'-spirobifluorene (5.86 g, 94% yield).

References

[1] Patent: EP2574608, 2013, A1. Location in patent: Paragraph 0088; 0089; 0090; 0091
[2] Patent: US9076971, 2015, B2. Location in patent: Page/Page column 9-10

3-DroMo-9,9'-spirobifluorene Preparation Products And Raw materials

Raw materials

Preparation Products

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3-DroMo-9,9'-spirobifluorene Suppliers

China 110 India 1 United States 3 Global 114

Puyang Huicheng Electronic Material Co. Ltd.

Tel: 0393-0393-0393-8910800 15039333257
Fax: 0393-8912775
Email: info@huichengchem.com
Country: China
ProdList: 569
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Henan Chuangan Optoelectronics Technology Co., Ltd.

Tel: 0371-61280670 15638139892
Fax: 0371-61280670
Email: dongguinan@chuanganchem.com
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Country: China
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Shanghai Hanhong Scientific Co.,Ltd.

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Email: info@hanhongsci.com
Country: China
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Hunan Hui Bai Shi Biotechnology Co., Ltd.

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Zhengzhou HQ Material Co., Ltd.

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Bide Pharmatech Ltd.

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NINGBO INNO PHARMCHEM CO.,LTD.

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Quzhou Rundong Chemical (Technology) Co.

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Anhui CONO Fine Chemical Co., Ltd.

Tel: 0550-0550-7097550 15051613561
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View Lastest Price from 3-DroMo-9,9'-spirobifluorene manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: 9,9'-Spirobi[9H-fluorene], 3-bromo- 1361227-58-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.00%
Supply Ability: 150KG /month
Release date: 2021-11-18

Henan Fengda Chemical Co., Ltd

Product: 3-DroMo-9,9'-spirobifluorene 1361227-58-8
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-02

Puyang Huicheng Electronic Materials Co., Ltd.

Product: 3-DroMo-9,9'-spirobifluorene 1361227-58-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%+HPLC
Supply Ability: 20
Release date: 2023-04-05

1361227-58-8, 3-DroMo-9,9'-spirobifluoreneRelated Search:

3-BROMO-4-CHLOROBENZONITRILE (2,7-BIS(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-9,9-DIOCTYLFLUORENE) 3-BroMo-9,9-diphenyl-9H-fluorene 2,7-Dibromo-9,9'-spiro-bifluorene 1,3,2-DIOXABOROLANE, 2,2'-(9,9-DIMETHYL-9H-FLUORENE-2,7-DIYL)BIS[4,4,5,5-TETRAMETHYL] 4-BroMo-9,9-diphenyl fluorene 2-Bromo-9,9'-spirobi[9H-fluorene] 4-bromo-9,9'-Spirobi[9H-fluorene 3-Bromo-9,9-dimethylfluorene

3-DroMo-9,9'-spirobifluorene

3-bromo-9,9'-spirobi(9h-fluorene)

3-bromo-9,9'-spirobi[fluorene]

9,9'-Spirobi[9H-fluorene], 3-bromo-

3-Bromo-9,9'-Spiro[9H-Fluorene]

3-BSF

3-bromo-SBF

3-Bromo-9,9'-spirobi[9H-fluorene

(S)-1-(dicyclohexylphosphino)-2-[(r)-1-(dimethylamino)

1361227-58-8

oled intermediates