2-Bromo-9,9'-spirobi[9H-fluorene]

Product Name: 2-Bromo-9,9'-spirobi[9H-fluorene]
CAS No.: 171408-76-7
Chemical Name: 2-Bromo-9,9'-spirobi[9H-fluorene]
Synonyms: 2-BSF;K0001;DK912;2-Bromo-9,9'-spirobi;2- broMospirofluorene;2-Bromospirobifluorene;2-BroMo-9,9'-spirobiflu;2-BroMo-9,9'-spirobiflu;2-broMo-9,9'-Spirobi[9H]-;2-BroMo-9,9'-spirobifluoren
CBNumber: CB6846376
Molecular Formula: C25H15Br
Formula Weight: 395.29
MOL File: 171408-76-7.mol

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2-Bromo-9,9'-spirobi[9H-fluorene] Property

Melting point:: 182.0 to 186.0 °C
Boiling point:: 517.2±29.0 °C(Predicted)
Density: 1.52±0.1 g/cm3(Predicted)
vapor pressure: 0-0.001Pa at 20-50℃
storage temp.: Sealed in dry,Room Temperature
form: Solid
color: White to Orange to Green
InChI: InChI=1S/C25H15Br/c26-16-13-14-20-19-9-3-6-12-23(19)25(24(20)15-16)21-10-4-1-7-17(21)18-8-2-5-11-22(18)25/h1-15H
InChIKey: ONCCVJKFWKAZAE-UHFFFAOYSA-N
SMILES: C12(C3=C(C=CC=C3)C3=C1C=CC=C3)C1=C(C=CC=C1)C1=C2C=C(Br)C=C1
LogP: 6.5 at 25℃ and pH6

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Safety

Safety Statements: 24/25
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TCI Chemical

Product number: B3560
Product name: 2-Bromo-9,9'-spirobi[9H-fluorene]
Purity: >98.0%(GC)
Packaging: 1g
Price: $16
Updated: 2024/03/01

TCI Chemical

Product number: B3560
Product name: 2-Bromo-9,9'-spirobi[9H-fluorene]
Purity: >98.0%(GC)
Packaging: 5g
Price: $44
Updated: 2024/03/01

TRC

Product number: B997230
Product name: 2-Bromo-9,9''-spirobi[fluorene]
Packaging: 50mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB62368
Product name: 2-Bromo-9,9'-spirobi[9H-fluorene]
Packaging: 2g
Price: $72
Updated: 2021/12/16

AK Scientific

Product number: X4125
Product name: 2-Bromo-9,9'-spirobifluorene
Packaging: 10g
Price: $90
Updated: 2021/12/16

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2-Bromo-9,9'-spirobi[9H-fluorene] Chemical Properties,Usage,Production

Description

2-Bromo-9, 9’-spirobifluorene is a derivative of 9,9'-spirobifluorene. It is a quite useful blue light emitting material used in the organic light emitting diodes (OLEDs). It possesses high photoluminescence efficiency and good chemical stability. Moreover, It has high glass-transition temperature, excellent thermal stability and easy color tenability through introducing low band gap co-monomers.

Chemical Properties

Off-white to light yellow crystal or powder

Synthesis

Synthesis of 2-bromo-spirofluorene
2-bromo-9-hydroxy-9-(2-biphenyl)fluorene (2g) dissolved in 25 mL acetic acid (15 mol/L) containing hydrochloric acid (12 mol/L) was refluxed for about 2 h to separate out a white solid, which was recrystallized with ethanol to produce white crystals of 2-bromo-spirofluorene (1.2 g, yield 63%).
GC-MS (m/z +): 394. 1HNMR (400 MHz, CDCl3, ppm):δ7.80～7.86 (m, 3H), δ7. 70 (d, 1H),δ7.48 (m, 1H), δ7.36 ～ 7.40 (m, 3H), δ7.13 (m, 3H), δ6.84 (d, 1H), δ6.72 (m, 3H)

References

http://www.sigmaaldrich.com/catalog/product/aldrich/767735?lang=en&region=US
Tang, S., et al. "A Molecular Glass for Deep-Blue Organic Light-Emitting Diodes Comprising a 9,9′-Spirobifluorene Core and Peripheral Carbazole Groups." Advanced Functional Materials 17.15(2010):2869-2877.
Nakanotani, H., et al. "Extremely Low-Threshold Amplified Spontaneous Emission of 9,9′-Spirobifluorene Derivatives and Electroluminescence from Field-Effect Transistor Structure." Advanced Functional Materials17.14(2010):2328-2335.

2-Bromo-9,9'-spirobi[9H-fluorene] Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromo-9,9'-spirobi[9H-fluorene] Suppliers

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View Lastest Price from 2-Bromo-9,9'-spirobi[9H-fluorene] manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 2-Bromo-9,9'-spirobi[9H-fluorene] 171408-76-7
Price: US $0.00-0.00/Kg/Drum
Min. Order: 1KG
Purity: 99%min
Supply Ability: 100kg
Release date: 2021-11-02

Shaanxi Franta Biotechnology Co., Ltd

Product: Triptorelin Acetate/GnRH 57773-63-4
Price: US $20.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 1000kg
Release date: 2024-12-10

Shanghai Daken Advanced Materials Co.,Ltd

Product: 9,9'-Spirobi[9H-fluorene], 2-bromo- 171408-76-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.00%
Supply Ability: 150KG /month
Release date: 2021-11-18

171408-76-7, 2-Bromo-9,9'-spirobi[9H-fluorene]Related Search:

Pentabromodiphenyl ether 2-Bromo-9,9-diphenylfluorene Decabromodiphenyl Ethane Bromoacetaldehyde diethyl acetal Ethyl bromodifluoroacetate Dibromomethane 2-Amino-9,9-dimethylfluorene 2-Bromodibenzofuran 4-BROMODIBENZOFURAN 4-BROMODIBENZOTHIOPHENE 9,9'-Spirobi[9H-fluorene] 2,2'-DIBROMO-9,9'-SPIROBIFLUORENE 2-Bromofluorene 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene 2,7-Dibromo-9,9'-spiro-bifluorene 2-Bromo-9,9-dimethylfluorene Bromine 2-Bromo-9,9'-spirobi[9H-fluorene]

9,9′-Spirobi[9H-fluorene],2′-bromo

2-BROMO-9,9''-SPIROBIFLUOROENE

2-Bromo-9,9'-spirobi[9H-fluorene]

2-Bromo-9,9'-spirobi

2-BroMo-9,9'-spirobiflu

2-BSF

2-BroMo-9,9'-spirobifluoren

2- broMospirofluorene

2-DibroMo-9,9'-spirobifluorene

2-(9,9'-spirobi[fluoren]-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-broMo-9,9'-Spirobi[9H]-fluorene (BSBF)

2-BROMO-9,9'-SPIROBIFLUORENE

2-Bromospirobifluorene

2-broMo-9,9'-Spirobi[9H]-

2-Bromo-9,9'-spirobi[9H-fluorene] &gt

K0001

2-Bromo-9,9'-spirobi[9H-fluorene] ISO 9001：2015 REACH

DK912

TIANFU-CHEM 2-Bromo-9,9'-spirobifluorene---

2-Bromo-9,9'-spirobi[9H-fluorene

2-BroMo-9,9'-spirobiflu

2-Bromo-9,9'-spirobi[fluorene

9,9'-Spirobi[9H-fluorene],2-bromo-

171408-76-7

C25H15Br

Pyridines

OLED materials,pharm chemical,electronic

Fluorene Series

Fluorene Derivatives

171408-76-7

OLED