2,2',7,7'-Tetrabromo-9,9'-spirobifluorene
- Product Name
- 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene
- CAS No.
- 128055-74-3
- Chemical Name
- 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene
- Synonyms
- SBF-4Br;7,7'CAS:128055-74-3;2,2',7,7'-Tetrabromo;TetrabroMo-9,9'-spirobifl;2,2',7,7'-Tetrabromo-9,9'-spirobiflurene;2,2',7,7'-Tetrabromo-9,9'-spirobifluorene;2,2',7,7'-Tetrabromo-9,9'-spirobifluorene;2,2',7,7'- four-9,9'- screwtwobroMinefluorene;2,2'',7,7''-TETRABROMO-9,9''-SPIRO-BIFLUOROENE
- CBNumber
- CB7843327
- Molecular Formula
- C25H12Br4
- Formula Weight
- 631.98
- MOL File
- 128055-74-3.mol
2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Property
- Melting point:
- 395-400°C
- Boiling point:
- 633.7±55.0 °C(Predicted)
- Density
- 2.12±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform
- form
- Solid
- color
- White to Off-White
- InChI
- InChI=1S/C25H12Br4/c26-13-1-5-17-18-6-2-14(27)10-22(18)25(21(17)9-13)23-11-15(28)3-7-19(23)20-8-4-16(29)12-24(20)25/h1-12H
- InChIKey
- MASXXNUEJVMYML-UHFFFAOYSA-N
- SMILES
- C12(C3=C(C=CC(Br)=C3)C3=C1C=C(Br)C=C3)C1=C(C=CC(Br)=C1)C1=C2C=C(Br)C=C1
- CAS DataBase Reference
- 128055-74-3(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 763888
- Product name
- 2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene
- Purity
- 95% (HPLC)
- Packaging
- 1g
- Price
- $193
- Updated
- 2023/06/20
- Product number
- 763888
- Product name
- 2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene
- Purity
- 95% (HPLC)
- Packaging
- 5g
- Price
- $669
- Updated
- 2023/01/07
- Product number
- T2597
- Product name
- 2,2',7,7'-Tetrabromo-9,9'-spirobi[9H-fluorene]
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $61
- Updated
- 2025/07/31
- Product number
- T2597
- Product name
- 2,2',7,7'-Tetrabromo-9,9'-spirobi[9H-fluorene]
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $205
- Updated
- 2025/07/31
- Product number
- T291200
- Product name
- 2,2'',7,7''-Tetrabromo-9,9''-spirobifluorene
- Packaging
- 5g
- Price
- $150
- Updated
- 2021/12/16
2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Chemical Properties,Usage,Production
Description
2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene is a spirobifluorene (SBF) derivative and is used as a blue-emitting material in electroluminescent devices. The spirobifluorene linkage in the molecule helps in decreasing the crystallization tendency and also increases the colour stability by preventing the formation of aggregates or excimers. They possess high photoluminescence efficiency and good chemical stability.
Chemical Properties
White to light yellow powder
Uses
2,2',7,7'-Tetrabromo-9,9'-spirobifluorene is used in the preparation of OLEDs using amorphous compounds with spiro-bifluorene core.
Uses
2,2'',7,7''-Tetrabromo-9,9''-spirobifluorene is used in the preparation of OLEDs using amorphous compounds with spiro-bifluorene core.
Application
Blue light emitting material in Organic Light Emitting Diodes (OLEDs).
General Description
2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene is a spirobifluorene (SBF) derivative and is used as a blue-emitting material in electroluminescent devices. The spirobifluorene linkage in the molecule helps in decreasing the crystallization tendency and also increases the colour stability by preventing the formation of aggregates or excimers. They possess high photoluminescence efficiency and good chemical stability.
Synthesis
159-66-0
128055-74-3
General procedure for the synthesis of 2,2',7,7'-tetrabromo-9,9'-spirobifluorene from 9,9'-spirobifluorene: 80 mg (0.5 mmol) of anhydrous FeCl3 was added to 30 ml of dichloromethane solution containing 3.16 g (10.0 mmol) of 9,9'-spirobifluorene. A solution of 2.1 ml (41 mmol) of bromine dissolved in 5 ml of dichloromethane was added slowly and dropwise over 10 min. The reaction mixture was refluxed for 6 hours. After completion of the reaction, it was cooled to room temperature and the product precipitated as a precipitate. The precipitate was collected by diafiltration and washed with a small amount of cold dichloromethane. Drying gave 6.0 g (95% yield) of the target product 2,2',7,7'-tetrabromo-9,9'-spirobifluorene as a white solid.
References
[1] Journal of the American Chemical Society, 1990, vol. 112, # 14, p. 5662 - 5663
[2] Journal of Organic Chemistry, 1996, vol. 61, # 20, p. 6906 - 6921
[3] Inorganic Chemistry, 2018, vol. 57, # 11, p. 6210 - 6213
[4] Journal of Materials Chemistry A, 2016, vol. 4, # 22, p. 8750 - 8754
[5] Chemistry - An Asian Journal, 2017, vol. 12, # 2, p. 181 - 189
2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Preparation Products And Raw materials
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View Lastest Price from 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene manufacturers
- Product
- 2,2,7,7-Tetrabromo-9,9-Spirobifluorene 128055-74-3
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-18
- Product
- 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene 128055-74-3
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-30
- Product
- 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene 128055-74-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1ton
- Release date
- 2018-08-06