1-(2-BROMOETHYL)-4-FLUOROBENZENE

Product Name: 1-(2-BROMOETHYL)-4-FLUOROBENZENE
CAS No.: 332-42-3
Chemical Name: 1-(2-BROMOETHYL)-4-FLUOROBENZENE
Synonyms: 4-FLUOROPHENETHYL BROMIDE;4-Fluorophenylethyl broMide;4-Fluorophenethyl bromide,97%;4-Fluorophenethyl bromide 97%;2-(4-FLUOROPHENYL)ETHYL BROMIDE;4-FLUORO-1-(2-BROMOETHYL)BENZENE;1-BROMO-2-(4-FLUOROPHENYL)ETHANE;1-FLUORO-4-(2-BROMOETHYL)BENZENE;4-(2-BroMoethyl)-1-fluorobenzene;1-(2-BROMOETHYL)-4-FLUOROBENZENE
CBNumber: CB0280259
Molecular Formula: C8H8BrF
Formula Weight: 203.05
MOL File: 332-42-3.mol

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1-(2-BROMOETHYL)-4-FLUOROBENZENE Property

Boiling point:: 100-104 °C15 mm Hg(lit.)
Density: 1.4498 g/mL at 25 °C(lit.)
refractive index: n20/D 1.534(lit.)
Flash point:: 200 °F
storage temp.: Sealed in dry,Room Temperature
form: Liquid or Low Melting Solid
color: Clear colorless to light yellow or white to pale yellow
CAS DataBase Reference: 332-42-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,N
Risk Statements: 22-51/53
Safety Statements: 61
RIDADR: UN 3082 9 / PGIII
WGK Germany: 2
HazardClass: 9
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 652008
Product name: 4-Fluorophenethyl bromide
Purity: 97%
Packaging: 5g
Price: $73.5
Updated: 2023/01/07

TCI Chemical

Product number: F0431
Product name: 2-(4-Fluorophenyl)ethyl Bromide
Purity: >95.0%(GC)
Packaging: 1g
Price: $35
Updated: 2025/07/31

TCI Chemical

Product number: F0431
Product name: 2-(4-Fluorophenyl)ethyl Bromide
Purity: >95.0%(GC)
Packaging: 5g
Price: $116
Updated: 2025/07/31

TRC

Product number: F595340
Product name: 4-Fluorophenethyl bromide
Packaging: 1g
Price: $130
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK333937
Product name: 1-(2-Bromoethyl)-4-fluorobenzene
Purity: 97%
Packaging: 1g
Price: $15
Updated: 2021/12/16

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1-(2-BROMOETHYL)-4-FLUOROBENZENE Chemical Properties,Usage,Production

Chemical Properties

Clear slightly yellow liquid

Uses

An intermediate in the production of protein A mimetics, serotonin antagonists, and other CNS agents

Synthesis

7589-27-7

332-42-3

Preparative Example 1 Synthesis of 4-fluorophenethyl bromide: Triphenylphosphine (222 g) and N-bromosuccinimide (151 g) were sequentially added to a solution of 4-fluorophenylethanol (100 g) in dichloromethane (1 L) under cooling conditions in an ice bath and the reaction was carried out with continuous stirring for 1 hour. Upon completion of the reaction, the resulting solution was concentrated under reduced pressure and the precipitated crystals were subsequently filtered. The filtrate was further concentrated to afford the target product 4-fluorobromoethylbenzene (133 g) as a colorless oil (yield: 92%). The product was characterized by 1H-NMR (400 MHz, CDCl3): δ (ppm) 3.14 (2H, t, J = 8 Hz), 3.54 (2H, t, J = 8 Hz), 6.98-7.03 (2H, m), 7.15-7.18 (2H, m).

References

[1] Journal of Organic Chemistry, 2006, vol. 71, # 18, p. 7035 - 7044
[2] Tetrahedron Asymmetry, 2001, vol. 12, # 4, p. 585 - 596
[3] Patent: US2002/19531, 2002, A1
[4] Bioorganic and Medicinal Chemistry, 2009, vol. 17, # 8, p. 2989 - 3002
[5] Patent: EP2508526, 2012, A1. Location in patent: Page/Page column 48

1-(2-BROMOETHYL)-4-FLUOROBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(2-BROMOETHYL)-4-FLUOROBENZENE Suppliers

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View Lastest Price from 1-(2-BROMOETHYL)-4-FLUOROBENZENE manufacturers

Henan Fengda Chemical Co., Ltd

Product: 1-(2-BROMOETHYL)-4-FLUOROBENZENE 332-42-3
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-(2-BROMOETHYL)-4-FLUOROBENZENE 332-42-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2-(4-Fluorophenyl)ethyl Bromide 332-42-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

332-42-3, 1-(2-BROMOETHYL)-4-FLUOROBENZENERelated Search:

4-FLUORO-3-(TRIFLUOROMETHYL)PHENACYL BROMID PENTAFLUOROPHENACYL BROMIDE 2-Bromo-4'-fluoroacetophenone 1-(2-BROMOETHYL)-4-FLUOROBENZENE 2-Bromo-2',4'-difluoroacetophenone 2-Bromo-1-(3,4-difluorophenyl)ethan-1-one ALPHA,ALPHA-DIBROMO-4-FLUOROACETOPHENONE 1-(2-BROMOETHYL)-3-FLUOROBENZENE (2-Bromoethyl)benzene 4-FLUORO-2-(TRIFLUOROMETHYL)PHENACYL BROMIDE 2-BROMO-1-(4-FLUOROPHENYL)-1-ETHANONE OXIME 2-BROMO-2-PHENYL-1-(γ-FLUOROPHENYL)-ETHANONE 2-BROMO-3-(3-CHLORO-4-FLUOROPHENYL)-1-PROPENE 2-BROMO-3-(3,4-DIFLUOROPHENYL)-1-PROPENE 3,4,5-TRIFLUOROPHENACYL BROMIDE 2-BROMO-3'-CHLORO-4'-FLUOROACETOPHENONE, 96% 1-(P-FLUOROPHENYL)-1,2-DIBROMOETHANE 2-Bromo-3-(4-fluoro-3-methylphenyl)prop-1-ene

1-FLUORO-4-(2-BROMOETHYL)BENZENE

1-BROMO-2-(4-FLUOROPHENYL)ETHANE

2-(4-FLUOROPHENYL)ETHYL BROMIDE

4-FLUORO-1-(2-BROMOETHYL)BENZENE

4-FLUOROPHENETHYL BROMIDE

1-(2-Bromoethyl)-4-fluoroBenzene,4-FluorophenethylBromide

1-Bromo-2-(4-fluorophenyl)ethane 97%

1-Bromo-2-(4-fluorophenyl)ethane97%

1-Fluoro-4-(2-bromoethyl)benzene, 4-Fluoro-1-(2-bromoethyl)benzene

4-Fluorophenethyl bromide 97%

4-Fluorophenethyl bromide,97%

1-(2-Bromoethyl)-4-fluorobenzene, 1-Bromo-2-(4-fluorophenyl)ethane

4-(2-BroMoethyl)-1-fluorobenzene

1-(2-Bromoethyl)-4-fluorobenzene 1-Bromo-2-(4-fluorophenyl)ethane 4-Fluorophenethyl Bromide

4-Fluorophenylethyl broMide

2-(4-Fluorophenyl)ethylBromide&gt

Benzene, 1-(2-bromoethyl)-4-fluoro-

1-(2-BROMOETHYL)-4-FLUOROBENZENE

1-(2-BROMOETHYL)-4-FLUOROBENZENE ISO 9001：2015 REACH

332-42-3

FC6H4CH2CH2Br

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