ChemicalBook > CAS DataBase List > 1-BENZOTHIEN-4-YLAMINE

1-BENZOTHIEN-4-YLAMINE

Product Name
1-BENZOTHIEN-4-YLAMINE
CAS No.
17402-83-4
Chemical Name
1-BENZOTHIEN-4-YLAMINE
Synonyms
4-Aminobenzothiophene;1-BENZOTHIEN-4-YLAMINE;4-AMinobenzo[b]thiophen;4-Aminobenzo[b]thiophene;Benzo[b]thiophen-4-aMine;4-Aminobenzo[B]Thiophenee;BENZO[B]THIOPHEN-4-YLAMINE;4-Aminobenzo[b]thiophene, CAS 17402-83-4;3-aMino-1-benzyl-1H-1$l^{4}-thiophen-1-yl;1-BENZOTHIEN-4-YLAMINE ISO 9001:2015 REACH
CBNumber
CB0301620
Molecular Formula
C8H7NS
Formula Weight
149.21
MOL File
17402-83-4.mol
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1-BENZOTHIEN-4-YLAMINE Property

Melting point:
139-140 °C
Boiling point:
135-140 °C(Press: 4 Torr)
Density 
1.294±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
3.96±0.10(Predicted)
Appearance
Light brown to brown Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B411720
Product name
Benzo[b]thiophen-4-amine
Packaging
50mg
Price
$110
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM1024196
Product name
4-AMINOBENZO[B]THIOPHENE
Purity
95.00%
Packaging
5MG
Price
$502.93
Updated
2021/12/16
AK Scientific
Product number
8994AA
Product name
Benzo[b]thiophen-4-amine
Packaging
250mg
Price
$246
Updated
2021/12/16
Matrix Scientific
Product number
145286
Product name
Benzo[b]thiophen-4-amine
Purity
95%
Packaging
1g
Price
$850
Updated
2021/12/16
Matrix Scientific
Product number
145286
Product name
Benzo[b]thiophen-4-amine
Purity
95%
Packaging
5g
Price
$2220
Updated
2021/12/16
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1-BENZOTHIEN-4-YLAMINE Chemical Properties,Usage,Production

Synthesis

10133-34-3

17402-83-4

(a) To a 500 mL autoclave was added 80 g (0.446 mol) of 4-nitrobenzo[b]thiophene, 4 g (0.05 g/g) of 5% palladium-carbon catalyst, and 320 mL of methanol. After the dosing was completed, the air in the kettle was replaced three times with nitrogen and then three times with hydrogen. Subsequently, hydrogen was charged into the kettle until the pressure reached 0.3 MPa, stirring was initiated, and the reaction mixture was heated to 50 °C and kept at this temperature for 6 h until the kettle no longer absorbed hydrogen. After the reaction was completed, stirring was continued for 30 minutes. After the reaction mixture was cooled to room temperature, the reaction solution was removed and filtered under nitrogen protection. The filtrate was concentrated under reduced pressure to a remaining volume of about 150 mL to give 60 g of compound (II) in 90% yield.

References

[1] Patent: CN106831739, 2017, A. Location in patent: Paragraph 0066-0067; 0073-0081; 0087- 0095
[2] Justus Liebigs Annalen der Chemie, 1937, vol. 527, p. 83,101
[3] Journal of the American Chemical Society, 1955, vol. 77, p. 5939,5943

1-BENZOTHIEN-4-YLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BENZOTHIEN-4-YLAMINE Suppliers

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View Lastest Price from 1-BENZOTHIEN-4-YLAMINE manufacturers

R&D Scientific Inc.
Product
1-benzothiophen-4-amine 17402-83-4
Price
US $3500.00/g
Min. Order
1g
Purity
99 %
Supply Ability
500 Kg
Release date
2024-11-12