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4-Chlorophenylboronic acid

Product Name
4-Chlorophenylboronic acid
CAS No.
1679-18-1
Chemical Name
4-Chlorophenylboronic acid
Synonyms
4-CHLOROBENZENEBORONIC ACID;AC 34441;NSC 25408;WLN: QBQR DG;AKOS BRN-0011;RARECHEM AH PB 0178;orobenzeneboronic Acid;p-chlorophenylboronic aci;4-Chlorophenylbronic Acid;The effects of boric acid
CBNumber
CB0307561
Molecular Formula
C6H6BClO2
Formula Weight
156.37
MOL File
1679-18-1.mol
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4-Chlorophenylboronic acid Property

Melting point:
284-289 °C(lit.)
Boiling point:
295.4±42.0 °C(Predicted)
Density 
1.32±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO
pka
8.39±0.10(Predicted)
form 
Crystalline Powder
color 
Off-white to beige
Water Solubility 
2.5 g/100 mL
BRN 
2936346
InChI
InChI=1S/C6H6BClO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChIKey
CAYQIZIAYYNFCS-UHFFFAOYSA-N
SMILES
B(C1=CC=C(Cl)C=C1)(O)O
CAS DataBase Reference
1679-18-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
36-37/39-26
WGK Germany 
3
RTECS 
CY8950000
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
417548
Product name
4-Chlorophenylboronic acid
Purity
95%
Packaging
1g
Price
$21.84
Updated
2024/03/01
Sigma-Aldrich
Product number
417548
Product name
4-Chlorophenylboronic acid
Purity
95%
Packaging
10g
Price
$119
Updated
2024/03/01
TCI Chemical
Product number
C1473
Product name
4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
C1473
Product name
4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
25g
Price
$141
Updated
2024/03/01
Alfa Aesar
Product number
A15657
Product name
4-Chlorobenzeneboronic acid, 98+%
Packaging
1g
Price
$19.65
Updated
2024/03/01
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4-Chlorophenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

off-white to beige crystalline powder

Chemical Properties

4-Chlorophenylboronic acid is white or off-white crystalline powder. It has certain solubility in water and is soluble in strong polar organic solvents such as dimethyl sulfoxide, but insoluble in ether solvents. It has similar chemical properties to phenylboronic acid.

Uses

4-Chlorobenzeneboronic Acid is used as a catalyst for the preparation of 4-hydroxycoumarin derivatives which display antitrypanosomal and antioxidant properties. It is also used as a catalyst for the asymmetric borane reduction of electron-deficient ketones.

Uses

4-Chlorophenylboronic acid can be used as a reactant in:

  • Palladium-catalyzed direct arylation.
  • Cyclopalladation.
  • Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation.
  • Copper-mediated ligandless aerobic fluoroalkylation.
  • Pd-catalyzed arylative cyclization.
  • Ruthenium catalyzed direct arylation.
  • Ligand-free copper-catalyzed coupling reactions.
  • Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.

It can also be used to prepare:
  • Substituted diarylmethylidenefluorenes via Suzuki coupling reaction.
  • Baclofen lactam by Suzuki coupling of a pyrrolinyl tosylate, followed by hydrogenation reaction.
  • Palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts.
  • Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.

4-Chlorophenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Chlorophenylboronic acid Suppliers

Jinan Daen Pharmaceutical Technology Co., Ltd
Tel
0531-68657833 15553112864
Fax
-
Email
2098511197@qq.com
Country
China
ProdList
219
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19918
Advantage
55
Tianjin Englon Technology Co., LTD
Tel
010-1234567 17526513758
Email
2062435649@qq.com
Country
China
ProdList
97
Advantage
49
Jiangsu Jingping New Material Technology Co., Ltd.
Tel
18852320356
Email
3437818551@qq.com
Country
China
ProdList
39
Advantage
58
Anhui Tokind Advanced Material Co., Ltd.
Tel
0554-2114112 18118134211
Email
tokind@tokinchem.com
Country
China
ProdList
62
Advantage
58
Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-8910800 03938917690
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
549
Advantage
64
Henan Ouber Technology Co., Ltd.
Tel
18860389453
Email
wade@oubertec.com
Country
China
ProdList
378
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
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View Lastest Price from 4-Chlorophenylboronic acid manufacturers

Henan Fengda Chemical Co., Ltd
Product
4-Chlorophenylboronic acid 1679-18-1
Price
US $34.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08
Hebei Xinsheng New Material Technology Co., LTD.
Product
4-Chlorophenylboronic acid 1679-18-1
Price
US $35.00-25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 Ton
Release date
2023-10-31
Hebei Xinsheng New Material Technology Co., LTD.
Product
4-Chlorobenzeneboronic acid 1679-18-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
30000 Kg
Release date
2023-12-01

1679-18-1, 4-Chlorophenylboronic acidRelated Search:


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  • B (Classes of Boron Compounds)
  • Boronic Acids
  • Organometallic Reagents
  • Boronic Acids and Derivatives
  • Aryl
  • blocks
  • BoronicAcids
  • Boronic Acid series
  • Fluorin-contained phenyl boronic acid series
  • Heterocyclic Compounds
  • Boronic Acid
  • Aryl
  • Organoborons
  • Boric acid