ChemicalBook > CAS DataBase List > 4-Chlorophenylboronic acid

4-Chlorophenylboronic acid

Product Name
4-Chlorophenylboronic acid
CAS No.
1679-18-1
Chemical Name
4-Chlorophenylboronic acid
Synonyms
4-CHLOROBENZENEBORONIC ACID;AC 34441;NSC 25408;WLN: QBQR DG;AKOS BRN-0011;RARECHEM AH PB 0178;orobenzeneboronic Acid;p-chlorophenylboronic aci;4-Chlorophenylbronic Acid;The effects of boric acid
CBNumber
CB0307561
Molecular Formula
C6H6BClO2
Formula Weight
156.37
MOL File
1679-18-1.mol
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4-Chlorophenylboronic acid Property

Melting point:
284-289 °C(lit.)
Boiling point:
295.4±42.0 °C(Predicted)
Density 
1.32±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO
pka
8.39±0.10(Predicted)
form 
Crystalline Powder
color 
Off-white to beige
Water Solubility 
2.5 g/100 mL
BRN 
2936346
InChI
InChI=1S/C6H6BClO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChIKey
CAYQIZIAYYNFCS-UHFFFAOYSA-N
SMILES
B(C1=CC=C(Cl)C=C1)(O)O
CAS DataBase Reference
1679-18-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
36-37/39-26
WGK Germany 
3
RTECS 
CY8950000
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
417548
Product name
4-Chlorophenylboronic acid
Purity
95%
Packaging
1g
Price
$21.84
Updated
2024/03/01
Sigma-Aldrich
Product number
417548
Product name
4-Chlorophenylboronic acid
Purity
95%
Packaging
10g
Price
$119
Updated
2024/03/01
TCI Chemical
Product number
C1473
Product name
4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
C1473
Product name
4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
25g
Price
$141
Updated
2024/03/01
Alfa Aesar
Product number
A15657
Product name
4-Chlorobenzeneboronic acid, 98+%
Packaging
1g
Price
$19.65
Updated
2024/03/01
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4-Chlorophenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

off-white to beige crystalline powder

Chemical Properties

4-Chlorophenylboronic acid is white or off-white crystalline powder. It has certain solubility in water and is soluble in strong polar organic solvents such as dimethyl sulfoxide, but insoluble in ether solvents. It has similar chemical properties to phenylboronic acid.

Uses

4-Chlorobenzeneboronic Acid is used as a catalyst for the preparation of 4-hydroxycoumarin derivatives which display antitrypanosomal and antioxidant properties. It is also used as a catalyst for the asymmetric borane reduction of electron-deficient ketones.

Uses

4-Chlorophenylboronic acid can be used as a reactant in:

  • Palladium-catalyzed direct arylation.
  • Cyclopalladation.
  • Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation.
  • Copper-mediated ligandless aerobic fluoroalkylation.
  • Pd-catalyzed arylative cyclization.
  • Ruthenium catalyzed direct arylation.
  • Ligand-free copper-catalyzed coupling reactions.
  • Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.

It can also be used to prepare:
  • Substituted diarylmethylidenefluorenes via Suzuki coupling reaction.
  • Baclofen lactam by Suzuki coupling of a pyrrolinyl tosylate, followed by hydrogenation reaction.
  • Palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts.
  • Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.

4-Chlorophenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

6-(4-CHLOROPHENYL)PYRIDINE-2-CARBALDEHYDE
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4-Chlorophenylboronic acid Suppliers

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View Lastest Price from 4-Chlorophenylboronic acid manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
4-Chlorophenylboronic acid 1679-18-1
Price
US $999.00-666.00/ton
Min. Order
1ton
Purity
99%
Supply Ability
5000
Release date
2024-08-20
Hebei Zhuanglai Chemical Trading Co Ltd
Product
4-Chlorophenylboronic acid 1679-18-1
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-11-26
Baoji Guokang Bio-Technology Co., Ltd.
Product
4-Chlorophenylboronic acid 1679-18-1
Price
US $171.80/KG
Min. Order
1g
Purity
99%
Supply Ability
10Tons
Release date
2021-06-07

1679-18-1, 4-Chlorophenylboronic acidRelated Search:

4-Chlorobenzoic acid ​4-Chlorophenoxyacetic acid sodium salt HexanitrodiphenylaMine Chlorphenamine maleate 1,2,4-Trichlorobenzene 4-Fluorobenzeneboronic acid Phenylboronic acid 4-Chlorobenzaldehyde Zinc borate 4-Chloronitrobenzene 4-Chloro-3-fluorobenzeneboronic acid (4-CHLORO-2-ETHOXYPHENYL)BORONIC ACID 2,4-Dichlorophenylboronic acid (3-AMINO-4-CHLOROPHENYL)BORONIC ACID HYDROCHLORIDE 4-Chloro-2-methoxyphenylboronic acid 4-CHLORO-2-METHYLPHENYLBORONIC ACID 4-Chloro-3-(trifluoromethyl)phenylboronic acid 2,4,6-Trichlorophenylboronic acid

  • 4-Chlorophenylboronic acid,97%
  • 4-Chlorophenylboronic acid, May contain varying amounts of anhydride, 97%
  • 4-Chlorophenylboronic acid,4-Chlorobenzeneboronic acid
  • p-chlorophenylboronic aci
  • (4-chlorophenyl)boronic acid(SALTDATA: 0.7H2O)
  • 4-Chlorophenylboronic acid, 97% 5GR
  • NSC 25408
  • BORONIC ACID, (4-CHLOROPHENYL)-;P-CHLOROBENZENEBORONIC ACID;
  • p-chloro-benzeneboronicaci
  • (p-chlorophenyl)metaboric acid
  • 4-Chlorophenylboronicacid,min.97%
  • 4-CHLOROBENZENEBORONIC ACID / 4-CHLOROPHENYLBORONIC ACID
  • PARACHLOROPHENYLBORONIC ACID
  • 4-Chlorophenylboronic acid ,98%
  • 4-Chlorophenylboronic acid, min. 97%
  • (4-Chlorophenyl)boranic acid
  • 4-Chlorophenylboranic acid
  • 4-Chlorophenylboron dihydoxide
  • 4-Chlorobenzeneboronic acid, 98+%
  • 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
  • orobenzeneboronic Acid
  • 4-Chlorophenylbronic Acid
  • The effects of boric acid
  • 4-Chlorophenylboronic acid 95%
  • AC 34441
  • Benzeneboronic acid, p-chloro-
  • WLN: QBQR DG
  • B-(4-Chlorophenyl)boronic acid
  • BORONIC ACID, (4-CHLOROPHENYL)-
  • AKOS BRN-0011
  • 4-CHLOROPHENYLBORNIC ACID
  • 4-CHLOROPHENYLBORONIC ACID
  • 4-CHLOROBENZENEBORONIC ACID
  • P-CHLOROPHENYLBORONIC ACID
  • P-CHLORO BENZENE BORONIC ACID
  • RARECHEM AH PB 0178
  • boronicacid,p-chlorophenyl
  • 4-Chlorophenylboronic acid,99%
  • Boronic acid, B-(4-chlorophenyl)-
  • 4-Chlorophenylboronic Acid extrapure, 97%
  • 4-Chlorophenylboornic acid
  • 4-Chlorophenylboronic acid supplier in China CAS NO.1679-18-1 CAS NO.1679-18-1
  • 1679-18-1
  • 1679-81-1
  • B (Classes of Boron Compounds)
  • Boronic Acids
  • Organometallic Reagents
  • Boronic Acids and Derivatives
  • Aryl
  • blocks
  • BoronicAcids
  • Boronic Acid series
  • Fluorin-contained phenyl boronic acid series
  • Heterocyclic Compounds
  • Boronic Acid
  • Aryl
  • Organoborons
  • Boric acid