Dibenzyl diselenide
- Product Name
- Dibenzyl diselenide
- CAS No.
- 1482-82-2
- Chemical Name
- Dibenzyl diselenide
- Synonyms
- BENZYL DISELENIDE;Dibenzyldiselenium;DIBENZYL DISELENIDE;1,2-Dibenzyldiselane;Dibenzyl perselenide;DibenzylDiselenide>Dibenzyl perdiselenide;Bis(benzyl) perselenide;Dibenzyldiselenide, 99+%;Diselenide,bis(phenylmethyl)
- CBNumber
- CB0309404
- Molecular Formula
- C14H14Se2
- Formula Weight
- 340.18
- MOL File
- 1482-82-2.mol
Dibenzyl diselenide Property
- Melting point:
- 91-93 °C(lit.)
- Boiling point:
- 427.3±48.0 °C(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- almost transparency in hot Toluene
- form
- solid
- color
- Light yellow to Yellow to Orange
- Water Solubility
- Soluble in water.
- Sensitive
- Air Sensitive
- BRN
- 1877745
- Exposure limits
- ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 - InChIKey
- HYAVEDMFTNAZQE-UHFFFAOYSA-N
- CAS DataBase Reference
- 1482-82-2(CAS DataBase Reference)
- NIST Chemistry Reference
- Diselenide, bis(phenylmethyl)(1482-82-2)
Safety
- Hazard Codes
- T,N
- Risk Statements
- 23/25-33-50/53
- Safety Statements
- 20/21-28-45-60-61
- RIDADR
- UN 3283 6.1/PG 2
- WGK Germany
- 3
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29310099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H331Toxic if inhaled
H373May cause damage to organs through prolonged or repeated exposure
H400Very toxic to aquatic life
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P314Get medical advice/attention if you feel unwell.
P391Collect spillage. Hazardous to the aquatic environment
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- D2717
- Product name
- Dibenzyl Diselenide
- Purity
- >95.0%(T)
- Packaging
- 5g
- Price
- $142
- Updated
- 2024/03/01
- Product number
- B21278
- Product name
- Dibenzyl diselenide, 95%
- Packaging
- 1g
- Price
- $19.65
- Updated
- 2024/03/01
- Product number
- B21278
- Product name
- Dibenzyl diselenide, 95%
- Packaging
- 5g
- Price
- $67.65
- Updated
- 2024/03/01
- Product number
- B21278
- Product name
- Dibenzyl diselenide, 95%
- Packaging
- 25g
- Price
- $260.65
- Updated
- 2024/03/01
- Product number
- D423085
- Product name
- Dibenzyl Diselenide
- Packaging
- 2.5g
- Price
- $75
- Updated
- 2021/12/16
Dibenzyl diselenide Chemical Properties,Usage,Production
Chemical Properties
Light yellow to Yellow to Orange powder to crystaline.
Uses
Dibenzyl diselenide is used as a source of the PhSe unit in organic synthesis. It is also used to introduce PhSe groups by reaction with a variety of nucleophilic, including enolates, enol silyl ethers, Grignard reagents, organolithium reagents, alkenes and amines.
Preparation
Dibenzyl diselenide was synthesized from bis(methoxymagnesium) diselenide reagent as reported by Gunther using benzyl chloride (6.3 g, 0.05 mole) and a methanolic solution of bis(methoxymagnesium) diselenide reagent (from 0.05 gatom of selenium). After 10 min stirring, water (100 mL) and concentrated hydrochloric acid (5 mL) were added, the solution was cooled, and the black solid was collected by filtration. This black solid was then extracted with ethanol to yield a bright yellow solution which, upon solvent removal, gave a yellow crystalline product. The 1H NMR of the yellow solid (in CDCl3) was identical to that of commercially available dibenzyl diselenide.
Dibenzyl diselenide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dibenzyl diselenide manufacturers
- Product
- Dibenzyldiselenide 1482-82-2
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 500kg
- Release date
- 2023-02-22
- Product
- Dibenzyl diselenide 1482-82-2
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- Dibenzyl Diselenide 1482-82-2
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27