ChemicalBook > CAS DataBase List > 3-Bromofuran

3-Bromofuran

Product Name
3-Bromofuran
CAS No.
22037-28-1
Chemical Name
3-Bromofuran
Synonyms
3-bromofurane;Furan, 3-bromo-;3-BROMOFURAN;b-Bromofuran;β-BroMofuran;BROMOFURANE-3;3-Bromofuran99%;BETA-BROMOFURAN;3-Furyl broMide;3-Bromofuran 97%
CBNumber
CB0329248
Molecular Formula
C4H3BrO
Formula Weight
146.97
MOL File
22037-28-1.mol
More
Less

3-Bromofuran Property

Melting point:
131.5-132 °C
Boiling point:
103 °C (lit.)
Density 
1.635 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.496(lit.)
Flash point:
38 °F
storage temp. 
-20°C
solubility 
Chloroform, Ethyl Acetate
form 
Liquid
color 
Clear yellow to orange to brown
Water Solubility 
Soluble in chloroform, ethyl acetate. Insoluble in water.
BRN 
105337
InChI
InChI=1S/C4H3BrO/c5-4-1-2-6-3-4/h1-3H
InChIKey
LXWLEQZDXOQZGW-UHFFFAOYSA-N
SMILES
O1C=CC(Br)=C1
CAS DataBase Reference
22037-28-1(CAS DataBase Reference)
NIST Chemistry Reference
Furan, 3-bromo-(22037-28-1)
More
Less

Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
16-23-24/25-37/39-26-33-29-7/9
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
F 
10
Hazard Note 
Highly Flammable/Irritant
HazardClass 
3
PackingGroup 
II
HS Code 
29321900
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
176524
Product name
3-Bromofuran
Purity
97%
Packaging
2.5g
Price
$251
Updated
2024/03/01
Sigma-Aldrich
Product number
176524
Product name
3-Bromofuran
Purity
97%
Packaging
10g
Price
$801
Updated
2024/03/01
TCI Chemical
Product number
B2157
Product name
3-Bromofuran
Purity
>98.0%(GC)
Packaging
1g
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
B2157
Product name
3-Bromofuran
Purity
>98.0%(GC)
Packaging
5g
Price
$139
Updated
2024/03/01
Alfa Aesar
Product number
B23543
Product name
3-Bromofuran, 97%, stab. with 0.5% calcium carbonate
Packaging
1g
Price
$54.65
Updated
2024/03/01
More
Less

3-Bromofuran Chemical Properties,Usage,Production

Chemical Properties

3-Bromofuran is a colorless to light yellow liquid having a boiling point similar to that of water (102.5-102.6 °C), but with density significantly higher (1.6606 g/cm3 at 20 °C).It is colorless when it is pure; however, the color can be light yellow when minor impurities are present. It is usaually stablized by calcium carbonate. It was used in the preparation of 2-substituted 3-furfurals. It was also used in the synthesis of 5,6-dehydronorcantharidins. 3-bromofuran is one of the volatile metabolites discussed in studies for detecting and discriminating diseases of onion.

Uses

3-Bromofuran is heterocyclic building block used in organic synthesis. 3-Bromofuran is one of the volatile metabolites discussed in studies for detecting and discriminating diseases of onion.

Synthesis

3-Bromofuran was obtained in minor amounts in 1887 as a byproduct in a reaction of 3-bromofuroic acid with calcium hydroxide. About four decades later this compound was prepared deliberately and in higher yield. 3-bromofuran has been prepared from 3,4-dibromofuran via ortho-metalation with butyl lithium in good yield. An elegant synthesis of 3-bromofuran is due to Fechtel who prepared this compound via a Diels Alder-bromination-reverse Diels Alder sequence.

Purification Methods

Purify 3-bromofuran by two steam distillations and dry it over fresh CaO. It can be dried over Na metal (no obvious reaction) and fractionated. It is not very soluble in H2O but is soluble in organic solvents. When freshly distilled, it is a clear oil, but darkens on standing and eventually resinifies. It can be stored for long periods by covering the oil with an alkaline solution of hydroquinone and is redistilled when required. It forms a characteristic maleic anhydride adduct, m 131.5-132o. [Shepard et al. J Am Chem Soc 52 2083 1930, Huhes & Johnson J Am Chem Soc 53 737 1931, adduct: van Campen & Johnson J Am Chem Soc 55 430 1933, Beilstein 17/1 V 295.]

3-Bromofuran Preparation Products And Raw materials

Raw materials

SODIUM DICHROMATE tert-Butyllithium 2-Butyne-1,4-diol Government regulation Dichloromethane Sulfuric acid

Preparation Products

3-Furaldehyde 3-Furanboronic acid
More
Less

3-Bromofuran Suppliers

Americas 1 Belgium 3 Canada 2 China 211 Czech Republic 1 Europe 5 France 3 Germany 8 India 64 Japan 3 Poland 1 Slovakia 3 Switzerland 4 United Kingdom 22 United States 32 Global 363
GLR Innovations
Tel
+91 9891111994
Email
info@glrgroup.in
Country
India
ProdList
4535
Advantage
58
TCI Chemicals (India) Pvt. Ltd.
Tel
--
Fax
--
Email
sales-in@tcichemicals.com
Country
India
ProdList
6768
Advantage
58
Triveni chemicals
Tel
--
Fax
--
Email
sales@trivenichemical.com
Country
India
ProdList
6088
Advantage
58
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
India
ProdList
6905
Advantage
58
Ashvarsha Fine Chemicals
Tel
--
Fax
--
Country
India
ProdList
147
Advantage
58
Sainor Laboratories Private Limited
Tel
--
Fax
--
Country
India
ProdList
66
Advantage
58
Basr Fine Chemicals Private Limited
Tel
--
Fax
--
Country
India
ProdList
632
Advantage
58
Denisco Chemicals Pvt Ltd
Tel
--
Fax
--
Country
India
ProdList
133
Advantage
58
Visa Chem Pvt. Ltd.
Tel
--
Fax
--
Email
info@visachemlabs.com
Country
India
ProdList
48
Advantage
58
Vyas Bio Life Sciences Pvt. Ltd
Tel
--
Fax
--
Country
India
ProdList
1213
Advantage
58
Vihasibio Sciences Private Limited
Tel
--
Fax
--
Country
India
ProdList
391
Advantage
58
Evans Fine Chem
Tel
--
Fax
--
Country
India
ProdList
289
Advantage
58
Chaturya Biotech (Tanuj Life Sciences)
Tel
--
Fax
--
Email
info@chaturyabiotech.com
Country
India
ProdList
398
Advantage
58
Almas Life Sciences
Tel
--
Fax
--
Country
India
ProdList
68
Advantage
58
VASIN BIO LIFE SCIENCES PVT LTD
Tel
--
Fax
--
Email
info@vasinbio.com
Country
India
ProdList
2092
Advantage
58
manikanta fine chem
Tel
--
Fax
--
Country
India
ProdList
133
Advantage
58
Dhanvi Exim Services
Tel
--
Fax
--
Email
info@dhanviexim.com
Country
India
ProdList
204
Advantage
58
Rivashaa Agrotech Biopharma Pvt. Ltd.
Tel
--
Fax
--
Email
source@rivashaa.com
Country
India
ProdList
986
Advantage
58
Chemipro Labs
Tel
--
Fax
--
Country
India
ProdList
73
Advantage
58
Reddy N Reddy Pharmaceuticals
Tel
--
Fax
--
Country
India
ProdList
473
Advantage
58
Bhuvar Technologies
Tel
--
Fax
--
Country
India
ProdList
47
Advantage
58
Basr Fine Chemicals Pvt., Ltd.
Tel
--
Fax
--
Email
basrtech@basrtech.com
Country
India
ProdList
134
Advantage
58
Vivera Labs
Tel
--
Fax
--
Email
info@viveralabs.com
Country
India
ProdList
24
Advantage
58
ASM Organics
Tel
--
Fax
--
Country
India
ProdList
1185
Advantage
58
Survival Technologies Private Limited
Tel
--
Fax
--
Country
India
ProdList
153
Advantage
58
Azole Rasayanas India Private Limited
Tel
--
Fax
--
Email
info@azolerasayanas.com
Country
India
ProdList
681
Advantage
58
Vihasifinechem Pvt Ltd
Tel
--
Fax
--
Country
India
ProdList
29
Advantage
58
Hypersynth Life Sciences
Tel
--
Fax
--
Country
India
ProdList
67
Advantage
58
Oceanic Pharmachem Pvt. Ltd.
Tel
--
Fax
--
Email
info@oceanicpharmachem.com
Country
India
ProdList
2005
Advantage
58
Siri Organics
Tel
--
Fax
--
Country
India
ProdList
54
Advantage
58
Anji Biosciences
Tel
--
Fax
--
Country
India
ProdList
201
Advantage
58
Symax Fine Chemicals
Tel
--
Fax
--
Country
India
ProdList
51
Advantage
58
Suchimin Life Sciences
Tel
--
Fax
--
Country
India
ProdList
25
Advantage
58
Reax Chemicals
Tel
--
Fax
--
Country
India
ProdList
4217
Advantage
58
Denisco Chemicals Pvt., Ltd.
Tel
--
Fax
--
Email
kat@denisco.com
Country
India
ProdList
174
Advantage
58
Spectrochem Private Limited
Tel
--
Fax
--
Country
India
ProdList
1055
Advantage
58
Anand Agencies
Tel
--
Fax
--
Email
en@gmail.com
Country
India
ProdList
2332
Advantage
58
Srinivasa Labs
Tel
--
Fax
--
Country
India
ProdList
113
Advantage
58
V Indaf Overseas Pvt., Ltd.
Tel
--
Fax
--
Email
info@vindaf.com
Country
India
ProdList
117
Advantage
58
Avra Synthesis Pvt Ltd
Tel
--
Fax
--
Email
info@avrasynthesis.com
Country
India
ProdList
1603
Advantage
30
Symax Life Sciences
Tel
--
Fax
--
Country
India
ProdList
12
Advantage
58
Quiver Technologies
Tel
--
Fax
--
Country
India
ProdList
169
Advantage
58
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
SRC Laboratories Pvt Ltd
Tel
--
Fax
--
Email
info@srclaboratories.com
Country
India
ProdList
243
Advantage
50
Survival Technologies Pvt Ltd
Tel
--
Fax
--
Email
swami@survivaltechnologies.in
Country
India
ProdList
290
Advantage
50
Reddy N Reddy Pharmaceuticals
Tel
--
Fax
--
Email
info@reddynreddypharma.com
Country
India
ProdList
254
Advantage
0
BASR Fine Chemicals
Tel
--
Fax
--
Email
info@basrtech.com
Country
India
ProdList
237
Advantage
56
OCEAN TRADING CORPORATION
Tel
--
Fax
--
Email
otcchem@otcchem.com
Country
India
ProdList
6202
Advantage
58
More
Less

View Lastest Price from 3-Bromofuran manufacturers

PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD
Product
3-Bromofuran 22037-28-1
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
500 kgs
Release date
2024-05-15
Hebei Weibang Biotechnology Co., Ltd
Product
3-Bromofuran 22037-28-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2022-09-29
Zhuozhou Wenxi import and Export Co., Ltd
Product
3-Bromofuran 22037-28-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

22037-28-1, 3-BromofuranRelated Search:

Nitrofurantoin Furan Tetrahydrofuran FURFURYL ALCOHOL RESIN Furazolidone 3-Furanboronic acid 3-(2-Furyl)acrylic acid Carbofuran Zolasartan 3-BROMO-1-BENZOFURAN 2,3-DIBROMOFURAN Saprisartan 4-BROMOFURAN-2-CARBOXYLICACID 2-BROMOFURAN METHYL 5-BROMO-2-FUROATE 2-Bromo-3-methylfuran 4-Bromo-2-furaldehyde 4,5-Dibromo-2-furaldehyde

  • 3-BroMofuran, stabilized with Cu(0.1%), Furan (0.5%) & NaHCO3 (0.4%), 95%
  • 3-Bromofuran 97%
  • 3-BROMOFURAN
  • BUTTPARK 98\57-04
  • BETA-BROMOFURAN
  • 3-Bromofuran, GC 97%
  • 3-BROMOFURAN , STABILIZED WITH 0.5% CALCIUM CARBONATE
  • 3-BROMOFURAN, 97%, STAB. WITH 0.5% CALCIUM CARBONATE
  • TIMTEC-BB SBB004098
  • 3-bromofurane
  • 3-Bromofuran99%
  • Furan, 3-bromo- (6CI,8CI,9CI)
  • BROMOFURANE-3
  • 3-Bromofuran, stabilized, 98%
  • Furan, 3-bromo-
  • b-Bromofuran
  • 3-Bromofuran,98%,stabilized
  • 3-Bromofuran, Stab. With 0.5% Calcium Carbonate
  • 3-BroMofuran, stabilized, 98% 2.5ML
  • 3-Furyl broMide
  • β-BroMofuran
  • 3-Bromofuran &gt
  • 22037-28-1
  • Br1C4H3O1
  • HALOGEN
  • Furans
  • Heterocyclic Building Blocks
  • Building Blocks
  • Furans, Benzofurans & Dihydrobenzofurans
  • Heterocycles
  • Building Blocks
  • FuransHeterocyclic Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Furans
  • Furans, Benzofurans & Dihydrobenzofurans
  • Halides
  • Furan&Benzofuran
  • Heterocyclic Compounds
  • HALIDE