4-BROMOFURAN-2-CARBOXYLICACID

Product Name: 4-BROMOFURAN-2-CARBOXYLICACID
CAS No.: 3439-02-9
Chemical Name: 4-BROMOFURAN-2-CARBOXYLICACID
Synonyms: 4-Bromo-2-furoic acid;2-Furoic acid, 4-bromo-;4-BROMOFURAN-2-CARBOXYLICACID;4-Bromo-2-furancarboxylic acid;2-Furancarboxylic acid, 4-broMo-
CBNumber: CB81511394
Molecular Formula: C5H3BrO3
Formula Weight: 190.98
MOL File: 3439-02-9.mol

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4-BROMOFURAN-2-CARBOXYLICACID Property

Melting point:: 115-127 ºC
Boiling point:: 284 ºC
Density: 1.891
Flash point:: 125 ºC
storage temp.: 2-8°C
pka: 2.91±0.15(Predicted)
Appearance: Off-white to yellow Solid
InChI: InChI=1S/C5H3BrO3/c6-3-1-4(5(7)8)9-2-3/h1-2H,(H,7,8)
InChIKey: QALYBHRYGIXHOF-UHFFFAOYSA-N
SMILES: O1C=C(Br)C=C1C(O)=O

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Safety

HS Code: 2932190090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Biosynth Carbosynth

Product number: FB142309
Product name: 4-Bromofuran-2-carboxylic acid
Packaging: 250mg
Price: $72.5
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB142309
Product name: 4-Bromofuran-2-carboxylic acid
Packaging: 500mg
Price: $125
Updated: 2021/12/16

Matrix Scientific

Product number: 119203
Product name: 4-Bromo-2-furoic acid
Purity: 95+%
Packaging: 250mg
Price: $180
Updated: 2021/12/16

Apolloscientific

Product number: OR917328
Product name: 4-Bromo-2-furoicacid
Purity: 95%
Packaging: 250mg
Price: $190
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0342138
Product name: 4-BROMO-2-FUROIC ACID
Purity: 95.00%
Packaging: 250MG
Price: $203.7
Updated: 2021/12/16

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4-BROMOFURAN-2-CARBOXYLICACID Chemical Properties,Usage,Production

Synthesis

2434-03-9

3439-02-9

General procedure for the synthesis of 4-bromo-2-furancarboxylic acid from 4,5-dibromo-2-furoic acid: 10.0 g (37.1 mmol) of 4,5-dibromofuran-2-carboxylic acid was dissolved in a 7.3% aqueous ammonia solution and the reaction system was cooled down to 0°C. The reaction was carried out by adding 2.54 g (38.9 mmol) of zinc powder. Under vigorous stirring conditions, 2.54 g (38.9 mmol) of zinc powder was added in batches and the reaction temperature was controlled not to exceed 7 °C. The reaction mixture was continued to be stirred at 0 °C for 10 min. Subsequently, the pH was adjusted to acidic by dropwise addition of aqueous hydrochloric acid. The resulting suspension was extracted with ethyl acetate, the organic phases were combined and dried over anhydrous sodium sulfate. After filtration, the organic phase was concentrated under reduced pressure to afford 7.27 g (99% yield) of 4-bromo-2-furancarboxylic acid. The structure of the product was confirmed by 1H-NMR (400 MHz, DMSO-d6): δ = 13.5 (s, 1H, COOH), 8.17 (s, 1H, furan cyclic H), 7.40 (s, 1H, furan cyclic H). LC-MS analysis (Method 1): retention time Rt = 1.52 min; mass spectrum (ESI positive ion mode): m/z = 191 [M+ H]+.

References

[1] Patent: US2012/22059, 2012, A1. Location in patent: Page/Page column 10-11
[2] Journal of Medicinal Chemistry, 2008, vol. 51, # 3, p. 407 - 416
[3] Patent: EP2236500, 2010, A1. Location in patent: Page/Page column 49
[4] Patent: EP2441457, 2012, A1. Location in patent: Page/Page column 31
[5] Patent: TWI530497, 2016, B. Location in patent: Page/Page column 61

4-BROMOFURAN-2-CARBOXYLICACID Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMOFURAN-2-CARBOXYLICACID Suppliers

China 52 Germany 1 India 1 United Kingdom 2 United States 6 Global 62

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View Lastest Price from 4-BROMOFURAN-2-CARBOXYLICACID manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 4-Bromo-2-furoic acid 3439-02-9
Price: US $1.60-6.60/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-19

Shaanxi Dideu Medichem Co. Ltd

Product: 4-BROMOFURAN-2-CARBOXYLICACID 3439-02-9
Price: US $1.00/Kg
Min. Order: 1Kg
Purity: 98%
Supply Ability: 20T
Release date: 2024-07-25

Career Henan Chemical Co

Product: 4-BROMOFURAN-2-CARBOXYLICACID 3439-02-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-12-31

3439-02-9, 4-BROMOFURAN-2-CARBOXYLICACIDRelated Search:

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4-BROMOFURAN-2-CARBOXYLICACID

4-Bromo-2-furancarboxylic acid

4-Bromo-2-furoic acid

2-Furancarboxylic acid, 4-broMo-

2-Furoic acid, 4-bromo-

3439-02-9

3439/2/9

3439-2-9