ACETOBROMO-ALPHA-D-XYLOSE

Product Name: ACETOBROMO-ALPHA-D-XYLOSE
CAS No.: 3068-31-3
Chemical Name: ACETOBROMO-ALPHA-D-XYLOSE
Synonyms: Acetobromoxylose;Acetobromo-α-D-xylose;alpha-Acetobromoxylose;-D-xylopyranosyl bromide;ALPHA-ACETOBROMO-D-XYLOSE;ACETOBROMO-ALPHA-D-XYLOSE;α-D-Xylopyranosyl bromide;2,3,4-Tri-O-acetyl-ùD-alpha-bromo-triacetoxylose;2,3,4-O-triacetyl-A-D-bromo xylose
CBNumber: CB0339746
Molecular Formula: C11H15BrO7
Formula Weight: 339.14
MOL File: 3068-31-3.mol

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ACETOBROMO-ALPHA-D-XYLOSE Property

Melting point:: 88-90°C
Boiling point:: 337.2±42.0 °C(Predicted)
Density: 1.51±0.1 g/cm3(Predicted)
storage temp.: Hygroscopic, -20°C Freezer, Under Inert Atmosphere
solubility: Chloroform (Sparingly, Heated), Dichloromethane (Slightly), Ethyl Acetate
form: Solid
color: White to Pale Beige
Stability:: Hygroscopic, Moisture Sensitive

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Safety

HS Code: 2938909090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC

Product number: B688345
Product name: Bromo2,3,4-Tri-O-acetyl-α-D-xylopyranoside(Stabilizedwith2.5%CaCO3)
Packaging: 250mg
Price: $130
Updated: 2021/12/16

Usbiological

Product number: 294727
Product name: 2,3,4-Tri-O-acetyl-a-D-xylopyranosyl bromide
Packaging: 50mg
Price: $340
Updated: 2021/12/16

Biosynth Carbosynth

Product number: MT04675
Product name: 2,3,4-Tri-O-acetyl-a-D-xylopyranosyl bromide - Stabilised with 2.5% CaCO3
Packaging: 50mg
Price: $50
Updated: 2021/12/16

Biosynth Carbosynth

Product number: MT04675
Product name: 2,3,4-Tri-O-acetyl-a-D-xylopyranosyl bromide - Stabilised with 2.5% CaCO3
Packaging: 100mg
Price: $90
Updated: 2021/12/16

Biosynth Carbosynth

Product number: MT04675
Product name: 2,3,4-Tri-O-acetyl-a-D-xylopyranosyl bromide - Stabilised with 2.5% CaCO3
Packaging: 250mg
Price: $120
Updated: 2021/12/16

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ACETOBROMO-ALPHA-D-XYLOSE Chemical Properties,Usage,Production

Chemical Properties

Off-White Solid

Uses

α-Acetobromo-D-xylose, 95% is a biochemical reagent.

Synthesis

62446-93-9

3068-31-3

II. General procedure for the synthesis of 2,3,4-tri-O-acetyl-α-D-bromopyranose (formula XII): In a 1 L round-bottomed flask equipped with a protective tube was added tetra-O-acetyl-D-xylulose (formula XI; 25.0 g, 78.54 mmol) and dichloromethane (500 mL), and the mixture was cooled to 0°C in an ice bath. An acetic acid solution (56 mL) of 33% hydrogen bromide was slowly added to the cooled solution over a period of 1 h under constant stirring. After addition, the reaction mixture was continued stirring at room temperature for 1 hour. After the completion of the reaction was monitored by thin layer chromatography (TLC, unfolding reagent ratio of 4:6 ethyl acetate:hexane), the reaction mixture was washed sequentially with ice water (1 x 500mL), 1% sodium bicarbonate solution (1 x 500mL), 10% sodium bicarbonate solution (2 x 500mL) and saturated saline (1 x 500mL). The organic layer was separated, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford a white solid 2,3,4-tri-O-acetyl-α-D-bromopyranose (formula XII), which could be used in the next reaction without further purification. The yield and nuclear magnetic resonance (NMR) data of the compound of formula XII were as follows: yield: 24.0 g (90%); 1H NMR (300 MHz, CDCl3): δ=6.59 (d, 1H, J=3.9 Hz), 5.60 (t, 1H, J=9.9 Hz), 5.05-5.03 (m, 1H), 4.77 (dd, 1H, J= 3.9,9.6Hz), 4.07 (dd, 1H, J=6.3,11.4Hz), 3.88 (t, 1H, J=11.1Hz), 2.10 (s, 3H), 2.06 (s, 6H).

References

[1] Journal of Organic Chemistry, 2001, vol. 66, # 7, p. 2327 - 2342
[2] Organic Letters, 2007, vol. 9, # 20, p. 3897 - 3900
[3] Bulletin of the Korean Chemical Society, 2010, vol. 31, # 3, p. 653 - 663
[4] Patent: US2012/29179, 2012, A1. Location in patent: Page/Page column 7
[5] Tetrahedron, 2005, vol. 61, # 35, p. 8405 - 8409

ACETOBROMO-ALPHA-D-XYLOSE Preparation Products And Raw materials

Raw materials

Preparation Products

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ACETOBROMO-ALPHA-D-XYLOSE Suppliers

Canada 1 China 48 India 2 Italy 1 Switzerland 1 United Kingdom 5 United States 9 Global 67

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
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3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
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Country: China
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Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
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China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
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Shanghai Huikai Chemical Technology Co., Ltd.

Tel: 021-61995394 18916691159
Email: chemicalsea@163.com
Country: China
ProdList: 1972
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Wuhan Chemduro Pharm Tech Co. Ltd.

Tel: 18040571231/1402788087
Fax: sales@chemduro.com
Country: China
ProdList: 1973
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Beijing Qinling Mountains Pharmaceutical Co., Ltd.

Tel: 010-61241352 18901327973
Email: 834537306@qq.com
Country: China
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Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939
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Email: shenlinxing@macklin.cn
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Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
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Nanjing Klender Bio-Technology Co., Ltd.

Tel: 025-52343882 18112933882
Fax: 025-52343882
Email: sales@kldbio.com
Country: China
ProdList: 2019
Advantage: 55

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View Lastest Price from ACETOBROMO-ALPHA-D-XYLOSE manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 2,3,4-Tri-O-acetyl-α-D-xylopyranosyl bromide 3068-31-3
Price: US $0.00/G
Min. Order: 1G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-17

Career Henan Chemical Co

Product: ACETOBROMO-ALPHA-D-XYLOSE 3068-31-3
Price: US $8.80/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 100kg
Release date: 2019-07-09

3068-31-3, ACETOBROMO-ALPHA-D-XYLOSERelated Search:

2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE 2,3,4-TRI-O-ACETYL-1-BROMO-1-DEOXY-BETA-D-XYLOPYRANOSYL CYANIDE ACETOBROMO-ALPHA-D-GLUCURONIC ACID METHYL ESTER 1,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranose 2,3,4,6-TETRA-O-BENZOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE C-(2,3,4,6-TETRA-O-BENZOYL-1-BROMO-1-DEOXY-BETA-D-GLUCOPYRANOSYL) FORMAMIDE 2,3,4,6-TETRA-O-BENZOYL-1-BROMO-1-DEOXY-BETA-D-GLUCOPYRANOSYL CYANIDE ACETOBROMO-ALPHA-D-XYLOSE

2,3,4-tri-o-acetyl-ù-d-xylopyranosylbromide

2,3,4-Tri-o-acetyl-α-D-xylopyranosylbromide

2,3,4-Tri-O-acetyl-&ugrave

-D-xylopyranosyl bromide

2,3,4-TRI-O-ACETYL-ALPHA-D-GLUCOPYRANURONIC ACID METHYL ESTER, TRICHLOROACETIMIDATE

ALPHA-ACETOBROMO-D-XYLOSE

2,3,4-Tri-O-acetyl-a-D-xylopyranosylbromide

Bromo2,3,4-tri-O-acetyl-α-D-xylopyranoside

Acetobromo-α-D-xylose

2,3,4-TRI-O-ACETYL-ALPHA-D-XYLOPYRANOSYL BROMIDE

D-alpha-bromo-triacetoxylose

1-Bromo-2-O,3-O,4-O-triacetyl-1-deoxy-α-D-xylopyranose

2-O,3-O,4-O-Triacetyl-α-D-xylopyranosyl bromide

Acetobromoxylose

alpha-Acetobromoxylose

alpha-D-Xylopyranosyl bromide triacetate

AcetobroMo-α-D-xylose, α-D-Xylopyranosyl BroMide 2,3,4-Triacetate

(2R,3R,4S,5R)-2-Bromotetrahydro-2H-pyran-3,4,5-triyl triacetate

Bromo 2,3,4-Tri-O-acetyl-α-D-xylopyranoside (Stabilized with 2.5% CaCO3)

a-D-Xylopyranosyl broMide,2,3,4-triacetate

2,3,4-Tri-O-acetyl-a-D-xylopyranosyl bromide - Stabilised with 2.5% CaCO3

BROMO 2,3,4-TRI-O-ACETYL-ALPHA-D-XYLOPYRANOSIDE

ACETOBROMO-ALPHA-D-XYLOSE

2,3,4-O-triacetyl-A-D-bromo xylose

2,3,4-O-triacetyl-alfa-D-bromo xylose

Bromo 2,3,4-Tri-O-acetyl-α-D-xylopyranoside

2,3,4-Tri-O-acetyl-α-D-xylopyranosyl bromide

Α-D-XYLOPYRANOSYL BROMIDE, 2,3,4-TRIACETATE

α-D-Xylopyranosyl bromide

(2R,3R,4S,5R)-3,5-bis(acetyloxy)-2-bromooxan-4-yl acetate

3068-31-3

Carbohydrates & Derivatives

13C & 2H Sugars