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5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER

Product Name
5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER
CAS No.
51677-09-9
Chemical Name
5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER
Synonyms
AKOS B024670;AKOS BBS-00002559;ART-CHEM-BB B024670;TIMTEC-BB SBB009684;5-phenylisoxazole-3-carboxylate;3-(Methoxycarbonyl)-5-phenylisoxazole;METHYL 5-PHENYL-3-ISOXAZOLECARBOXYLATE;METHYL 5-PHENYLISOXAZOLE-3-CARBOXYLATE;Methyl 5-phenyl-1,2-oxazole-3-carboxylate;5-Phenyl-3-isoxazolecarboxylic acid methyl ester
CBNumber
CB0350037
Molecular Formula
C11H9NO3
Formula Weight
203.19
MOL File
51677-09-9.mol
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5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER Property

Melting point:
81°C
Boiling point:
370.2±30.0 °C(Predicted)
Density 
1.204±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
-6.43±0.28(Predicted)
form 
solid
Appearance
White to off-white Solid
InChIKey
XMPLCJOQBDGMKT-UHFFFAOYSA-N
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Safety

Hazard Codes 
Xi
HazardClass 
IRRITANT
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
JRD0175
Product name
Methyl 5-phenylisoxazole-3-carboxylate
Purity
Aldrich
Packaging
1g
Price
$185
Updated
2025/07/31
TRC
Product number
B399913
Product name
Methyl 5-phenylisoxazole-3-carboxylate
Packaging
250mg
Price
$90
Updated
2021/12/16
AK Scientific
Product number
W6653
Product name
Methyl 5-phenylisoxazole-3-carboxylate
Packaging
1g
Price
$105
Updated
2021/12/16
SynQuest Laboratories
Product number
4H23-1-Q1
Product name
Methyl 5-phenylisoxazole-3-carboxylate
Packaging
1g
Price
$157
Updated
2021/12/16
Matrix Scientific
Product number
043176
Product name
Methyl 5-phenyl-3-isoxazolecarboxylate
Purity
>95%
Packaging
500mg
Price
$181
Updated
2021/12/16
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5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER Chemical Properties,Usage,Production

Uses

Methyl 5-Phenylisoxazole-3-carboxylate is a useful reagent for reactions with isoxazoles.

Synthesis

1313396-20-1

51677-09-9

GENERAL METHODS: Alkyne oxime ether 1 (0.15 mmol) was dissolved in THF (5 mL) and phenol (28 mg, 0.3 mmol) and AgBF4 (5.8 mg, 0.03 mmol) were added sequentially. The reaction system was equipped with a drying tube (filled with silica gel) and heated to reflux at 50 °C in an oil bath. The reaction process was monitored by TLC with continuous stirring for 1-12 hours. After completion of the reaction, the reaction mixture was concentrated under reduced pressure. The residue was purified by preparative thin layer chromatography (unfolding reagent: hexane/ethyl acetate = 3-10:1) to afford the target product methyl 5-phenylisoxazole-3-carboxylate (3a and 3j). The physical properties and spectral data of the obtained compounds were in agreement with those reported in the literature.

References

[1] Tetrahedron, 2011, vol. 67, # 25, p. 4612 - 4615

5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER Suppliers

China 64 Germany 2 India 2 Russia 2 United Kingdom 2 United States 16 Global 88
A.J Chemicals
Tel
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Fax
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Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
Dr. Jagath Reddy's Heterocyclics
Tel
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Fax
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Email
jagathreddy@usa.net
Country
India
ProdList
3886
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View Lastest Price from 5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER manufacturers

Career Henan Chemical Co
Product
5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER 51677-09-9
Price
US $0.01/KG
Min. Order
1KG
Purity
98%; 99%
Supply Ability
500g； 1kg; 25kg
Release date
2020-01-10
Career Henan Chemical Co
Product
5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER 51677-09-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-03

51677-09-9, 5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTERRelated Search:

ETHYL 5-PHENYL-3-ISOXAZOLECARBOXYLATE methyl 5-nitro-1h-indazole-6-carboxylate methyl 5-methoxy-1-methyl-1H-indole-6-carboxylate methyl 5-oxo-5{H}-[1,3]thiazolo[3,2-{a}]pyrimidine-7-carboxylate 5-PHENYLISOXAZOLE-3-CARBOXYLIC ACID 3-Isoxazolecarboxylic acid ETHYL 5-PHENYL-3-ISOXAZOLECARBOXYLATE METHYL 5-(4-METHYLPHENYL)ISOXAZOLE-3-CARBOXYLATE 3-(4-NITRO-PHENYL)-ISOXAZOLE-5-CARBOXYLIC ACID ETHYL ESTER METHYL 5-(3-IODOPHENYL)ISOXAZOLE-3-CARBOXYLATE ETHYL 5-P-TOLYLISOXAZOLE-3-CARBOXYLATE METHYL 5-(4-FLUOROPHENYL)ISOXAZOLE-3-CARBOXYLATE ETHYL-5(3-FLUOROPHENYL)-ISOXAZOLE-3-CARBOXYLATE METHYL 5-(4-BROMOPHENYL)ISOXAZOLE-3-CARBOXYLATE 5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER METHYL 5-(4-METHOXYPHENYL)ISOXAZOLE-3-CARBOXYLATE 3-METHYL-5-PHENYL-ISOXAZOLE-4-CARBOXYLIC ACID METHYL ESTER 3-(4-NITRO-PHENYL)-ISOXAZOLE-5-CARBOXYLIC ACID METHYL ESTER

  • AKOS B024670
  • AKOS BBS-00002559
  • ART-CHEM-BB B024670
  • METHYL 5-PHENYLISOXAZOLE-3-CARBOXYLATE
  • METHYL 5-PHENYL-3-ISOXAZOLECARBOXYLATE
  • JR-7047, Methyl 5-phenylisoxazole-3-carboxylate, 97%
  • Methyl 5-phenyl-1,2-oxazole-3-carboxylate
  • 3-Isoxazolecarboxylic acid, 5-phenyl-, Methyl ester
  • 3-(Methoxycarbonyl)-5-phenylisoxazole
  • 5-PHENYL-ISOXAZOLE-3-CARBOXYLIC ACID METHYL ESTER
  • TIMTEC-BB SBB009684
  • 5-Phenyl-3-isoxazolecarboxylic acid methyl ester
  • 5-phenylisoxazole-3-carboxylate
  • 51677-09-9