4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER
- Product Name
- 4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER
- CAS No.
- 56893-25-5
- Chemical Name
- 4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER
- Synonyms
- Fs005025;Methyl p-(BroMoacetyl)benzoate;Methyl 4-(BroMoacetyl)benzoate;Methyl 4-(2-bromoacetyl)benzoate;α-BroMo-4-(carboMethoxy)acetophenone;4-(2-Bromoacetyl)benzoic acid methyl este;4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER;Benzoic acid, 4-(2-broMoacetyl)-, Methyl ester;ω-BroMoacetophenone-4-carboxylic Αcid Methyl Ester;4-(Methoxycarbonyl)phenacyl bromide, 2-Bromo-4'-(methoxycarbonyl)acetophenone
- CBNumber
- CB0354040
- Molecular Formula
- C10H9BrO3
- Formula Weight
- 257.08
- MOL File
- 56893-25-5.mol
4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER Property
- Boiling point:
- 342.8±22.0 °C(Predicted)
- Density
- 1.494±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- solid
- color
- Beige
Safety
- HS Code
- 2917399590
N-Bromosuccinimide Price
- Product number
- B679260
- Product name
- 4-(2-Bromoacetyl)benzoicAcidMethylEster
- Packaging
- 1g
- Price
- $875
- Updated
- 2021/12/16
- Product number
- FB19187
- Product name
- 4-(2-Bromoacetyl)benzoic acid methyl ester
- Packaging
- 100mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- OR46535
- Product name
- Methyl4-(bromoacetyl)benzoate
- Packaging
- 250mg
- Price
- $79
- Updated
- 2021/12/16
- Product number
- 2629-9-03
- Product name
- 4-(2-Bromoacetyl)benzoic acid methyl ester
- Packaging
- 250mg
- Price
- $93
- Updated
- 2021/12/16
- Product number
- FB19187
- Product name
- 4-(2-Bromoacetyl)benzoic acid methyl ester
- Packaging
- 250mg
- Price
- $100
- Updated
- 2021/12/16
4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production
Uses
A phenacyl bromide
Synthesis
3609-53-8
56893-25-5
General procedure for the synthesis of methyl 4-(2-bromoacetyl)benzoate from methyl 4-acetylbenzoate: Bromine (2.71 mL, 52.5 mmol) was added dropwise to a solution of methyl 4-acetylbenzoate (8.91 g, 50.0 mmol) in acetic acid (80 mL). The reaction mixture was stirred at room temperature for 2 hours. Upon completion of the reaction, the mixture was cooled to 0 °C and filtered to collect the solid. The resulting precipitate was washed with a 1:1 mixed methanol-water solution and subsequently dried to afford methyl 4-(2-bromoacetyl)benzoate (10.6 g, 82% yield) as a brown solid. The product was characterized by 1H NMR (400 MHz, CDCl3) with chemical shifts of δ 8.19-8.12 (m, 2H), 8.04 (d, J = 8.5 Hz, 2H), 4.47 (s, 2H), 3.96 (s, 3H).
References
[1] Journal of the American Chemical Society, 2000, vol. 122, # 39, p. 9361 - 9366
[2] Patent: WO2006/78698, 2006, A1. Location in patent: Page/Page column 64
[3] Patent: US2012/196869, 2012, A1. Location in patent: Paragraph 0467; 0468; 0469
[4] Inorganic Chemistry, 2018, vol. 57, # 1, p. 120 - 128
[5] Patent: WO2008/33745, 2008, A2. Location in patent: Page/Page column 70-71
4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER Suppliers
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View Lastest Price from 4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER manufacturers
- Product
- methyl 4-(2-bromoacetyl)benzoate 56893-25-5
- Price
- US $0.00/kg
- Min. Order
- 20kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2025-03-27
- Product
- 4-(2-BROMO-ACETYL)-BENZOIC ACID METHYL ESTER 56893-25-5
- Price
- US $6.60/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg-1000kg
- Release date
- 2019-12-26