ChemicalBook > CAS DataBase List > 4-Bromobenzoylacetonitrile

4-Bromobenzoylacetonitrile

Product Name
4-Bromobenzoylacetonitrile
CAS No.
4592-94-3
Chemical Name
4-Bromobenzoylacetonitrile
Synonyms
BUTTPARK 35\09-90;4-BROMOBENZOYLACETONITRILE;4-broMobenzoylacetonitirle;p-BroMobenzoylacetonitrile;(4-Bromobenzoyl)acetonitrile 97%;4-Bromo-β-oxobenzenepropanenitrile;3-(4-Bromphenyl)-3-oxopropanonitril;Benzenepropanenitrile, 4-bromo-b-oxo-;3-(4-BROMOPHENYL)-3-OXOPROPANENITRILE;Benzenepropanenitrile, 4-bromo-β-oxo-
CBNumber
CB0363415
Molecular Formula
C9H6BrNO
Formula Weight
224.05
MOL File
4592-94-3.mol
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4-Bromobenzoylacetonitrile Property

Melting point:
161-163
Boiling point:
370.0±27.0 °C(Predicted)
Density 
1.523±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
7.37±0.10(Predicted)
CAS DataBase Reference
4592-94-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
676330
Product name
(4-Bromobenzoyl)acetonitrile
Purity
97%
Packaging
5g
Price
$45.2
Updated
2024/03/01
TRC
Product number
B680688
Product name
4-Bromobenzoylacetonitrile
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
B680688
Product name
4-Bromobenzoylacetonitrile
Packaging
500mg
Price
$65
Updated
2021/12/16
TRC
Product number
B680688
Product name
4-Bromobenzoylacetonitrile
Packaging
1g
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
044680
Product name
3-(4-Bromophenyl)-3-oxopropanenitrile
Purity
>95%
Packaging
500mg
Price
$10
Updated
2021/12/16
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4-Bromobenzoylacetonitrile Chemical Properties,Usage,Production

Uses

4-Bromobenzoylacetonitrile is a useful research chemical used in the preparation of mechanistic studies, and fluorescence of naphtho[1,8-bc]pyrans via rhodium-catalyzed cascade oxidative annulation of benzoylacetonitriles with internal alkynes.

Purification Methods

The nitrile is purified by dissolving in slightly alkaline H2O (charcoal), filtering and acidifying with HCl to give colourless needles (m 162-163o). It recrystallises from EtOH. With Me2SO4/KOH at 130o it gives 4-bromo-methoxycinnamylnitrile m 58.5-59.5o (from high boiling pet ether) [Fuson & Wolf J Am Chem Soc 61 1940 1939, Grathaus & Dains J Am Chem Soc 58 1334 1936]. [Beilstein 10 III 2998.]

4-Bromobenzoylacetonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromobenzoylacetonitrile Suppliers

UkrOrgSynthesis Ltd.
Tel
--
Fax
--
Email
y.barysheva@ukrorgsynth.com
Country
Ukraine
ProdList
6230
Advantage
38
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View Lastest Price from 4-Bromobenzoylacetonitrile manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
4-Bromobenzoylacetonitrile 4592-94-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2022-11-17
Hebei Mojin Biotechnology Co., Ltd
Product
4-Bromobenzoylacetonitrile 4592-94-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-17
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Bromobenzoylacetonitrile 4592-94-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

4592-94-3, 4-BromobenzoylacetonitrileRelated Search:


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