2-Bromofluorobenzene

Product Name: 2-Bromofluorobenzene
CAS No.: 1072-85-1
Chemical Name: 2-Bromofluorobenzene
Synonyms: 1-BROMO-2-FLUOROBENZENE;Benzene, 1-bromo-2-fluoro-;O-FLUOROBROMOBENZENE;2-Bromofluorobenzene99%;1-Bromo-2-fL;2-Bromfluorbenzen;2-Flurobromobenzene;-Bromofluorobenzene;1-BROMOFLUOROBENZENE;2-FLUOROBROMOBENZENE
CBNumber: CB2414900
Molecular Formula: C6H4BrF
Formula Weight: 175
MOL File: 1072-85-1.mol

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2-Bromofluorobenzene Property

Melting point:: -8°C
Boiling point:: 78-82 °C50 mm Hg
Density: 1.601 g/mL at 25 °C(lit.)
refractive index: n20/D 1.534(lit.)
Flash point:: 110 °F
storage temp.: Sealed in dry,Room Temperature
solubility: 0.35g/l
form: Liquid
color: Clear colorless to light yellow
Specific Gravity: 1.601
Water Solubility: insoluble
BRN: 1071819
InChI: 1S/C6H4BrF/c7-5-3-1-2-4-6(5)8/h1-4H
InChIKey: IPWBFGUBXWMIPR-UHFFFAOYSA-N
SMILES: Fc1ccccc1Br
CAS DataBase Reference: 1072-85-1(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-bromo-2-fluoro-(1072-85-1)
EPA Substance Registry System: Benzene, 1-bromo-2-fluoro- (1072-85-1)

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Safety

Hazard Codes: Xi,F,Xn
Risk Statements: 10-36/37/38-22-20/21/22
Safety Statements: 26-36-37/39-16
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
RTECS: DA1050000
Hazard Note: Flammable/Irritant
TSCA: TSCA listed
HazardClass: 3
PackingGroup: III
HS Code: 29036990
Storage Class: 3 - Flammable liquids
Hazard Classifications: Flam. Liq. 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P370+P378In case of fire: Use … for extinction.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: B66809
Product name: 1-Bromo-2-fluorobenzene
Purity: 99%
Packaging: 25g
Price: $64.2
Updated: 2025/07/31

Sigma-Aldrich

Product number: B66809
Product name: 1-Bromo-2-fluorobenzene
Purity: 99%
Packaging: 100g
Price: $147
Updated: 2025/07/31

TCI Chemical

Product number: B0883
Product name: 2-Bromofluorobenzene
Purity: >99.0%(GC)
Packaging: 25g
Price: $48
Updated: 2025/07/31

TCI Chemical

Product number: B0883
Product name: 2-Bromofluorobenzene
Purity: >99.0%(GC)
Packaging: 100g
Price: $128
Updated: 2025/07/31

TCI Chemical

Product number: B0883
Product name: 2-Bromofluorobenzene
Purity: >99.0%(GC)
Packaging: 500g
Price: $378
Updated: 2025/07/31

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2-Bromofluorobenzene Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID

Uses

1-Bromo-2-fluorobenzene is used as a reactant with cyclopenta-1,3-diene to produce 1,4-dihydro-1,4-methano-naphthalene. This reaction will need reagent Mg, and solvent diethyl ether. The reaction time is 3 hours with the temperature of 20°C,

Application

2-Bromofluorobenzene is a starting material for coupling reactions; a useful benzyne precursor.

Synthesis Reference(s)

The Journal of Organic Chemistry, 26, p. 5149, 1961 DOI: 10.1021/jo01070a089

Synthesis

NaOMe (0.5 mmol; 25 wt% MeOH solution) was added to a slurry of arylboronic acid (10 mmol) in acetonitrile (10 mL/g vs. boric acid). One portion of 1,3-dibromo-5,5-dimethylglycolide (11 mmol) was added to the reaction and the mixture was heated to 40 C. The reaction was aged under N2 atmosphere at 40 C for 4 h. The reaction was cooled to room temperature and burst with 10% Na2SO3 (10 mL/g vs. boric acid). The mixture was diluted with MTBE (10mL/g vs. boric acid) and the stirred organic layer was washed with 1N NaOH (10mL/g vs. boric acid) to remove any unreacted starting material. The organic solution was analyzed by HPLC and the yield of the reaction was obtained by comparison with authentic samples obtained from commercial sources.GC/MS and NMR analyses confirmed the identity of the product. The final product, o-bromofluorobenzene, was obtained in 98% yield

2-Bromofluorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

1,4-EPOXY-1,4-DIHYDRONAPHTHALENE

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2-Bromofluorobenzene Suppliers

Americas 1 Belgium 2 Canada 4 China 411 Europe 4 France 1 Germany 7 India 30 Italy 1 Japan 5 Norway 1 Slovakia 1 South Korea 1 Switzerland 4 The Netherlands 1 Ukraine 1 United Kingdom 20 United States 59 Global 554

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View Lastest Price from 2-Bromofluorobenzene manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd

Product: 1-Bromo-2-fluorobenzene 1072-85-1
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: Customise
Release date: 2025-11-25

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2-Bromofluorobenzene 1072-85-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-12-04

Hebei Chuanghai Biotechnology Co,.LTD

Product: 2-Bromofluorobenzene 1072-85-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99.%
Supply Ability: 10 ton
Release date: 2024-08-21

1072-85-1, 2-BromofluorobenzeneRelated Search:

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1-Bromo-2-fluorobenzene,98% [2-Bromofluorobenzene]

o-Bromofluorobenzene,99%

Benzene, 1-bromo-2-fluoro-

2-Bromofluorobenzene 99%

2-Bromofluorobenzene99%

2-BROMO-1-FLUORO-BENZENE

O-BROMO-2-FLUOROBENZENE

2-BROMOFLUOROBENZENE

2-FLUOROBROMOBENZENE

1-BROMOFLUOROBENZENE

1-BROMO-2-FLUOROBENZENE

O-FLUOROBROMOBENZENE

O-BROMOFLUOROBENZENE

1,2-Fluorobromobenzene

1-bromo-2-fluoro-benzen

1-fluoro-2-bromo-benzen

1-Fluoro-2-bromobenzene

2-Bromfluorbenzen

Benzene, 1-fluoro-2-bromo-

2-Fluorobromobenzene 99%

2-BroMofluorobenzene, 99% 50ML

2-Bromophenyl fluoride

Adjacent fluorine broMobenzene

2-Flurobromobenzene

1-Bromo-2-fluorobenzene≥ 99% (HPLC)

1-Bromo-2-fL

2-Bromofluorobenzene &gt

1-Brom-2-fluorbenzol

2 - bromine fluorobenzene

2-Bromofluorobenzene ISO 9001：2015 REACH

-Bromofluorobenzene

Bifeprunox Impurity 13

1-Bromo-2-fluorobenzene, 98%

Ortho bromofluorobenzene

2-BromofChemicalbookluorobenzene99%

1072-85-1

Aryl

Organic Building Blocks

Halogenated Hydrocarbons

ARYL HALIDE

Building Blocks

C6

Aryl Fluorinated Building Blocks

Building Blocks

Chemical Synthesis

Fluorinated Building Blocks

Halogenated Hydrocarbons

Organic Building Blocks

Organic Fluorinated Building Blocks

Other Fluorinated Organic Building Blocks

Aromatic Hydrocarbons (substituted) & Derivatives

Fluorobenzene

alkyl Fluorine| alkyl bromide

alkyl bromide| alkyl Fluorine

Bromine Compounds

Fluorine Compounds

Aryl

Halogenated Hydrocarbons