1-PHENYL-2-PROPYN-1-OL

Product Name: 1-PHENYL-2-PROPYN-1-OL
CAS No.: 4187-87-5
Chemical Name: 1-PHENYL-2-PROPYN-1-OL
Synonyms: PHENYLETHYNYLCARBINOL;ETHYNYLPHENYLCARBINOL;Phenylpropynol;Phenyl-2-propy;TIMTEC-BB SBB008986;1-PHENYL-2-PROPYN-1-OL;1-PHENYL-PROP-2-YN-1-OL;1-PHENYL-2-PROPYNE-1-OL;à-ethynylbenzyl alcohol;2-Propyn-1-ol, 1-phenyl-
CBNumber: CB0409973
Molecular Formula: C9H8O
Formula Weight: 132.16
MOL File: 4187-87-5.mol

More

Less

1-PHENYL-2-PROPYN-1-OL Property

Melting point:: 22-23 °C(lit.)
Boiling point:: 135-136 °C13 mm Hg(lit.)
alpha: 0°(neat)
Density: 1.087 g/mL at 25 °C(lit.)
refractive index: n20/D 1.549(lit.)
Flash point:: 211 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Methanol
pka: 12.40±0.20(Predicted)
form: Liquid
Specific Gravity: 1.087
color: Clear yellow
BRN: 742365
InChIKey: UIGLAZDLBZDVBL-UHFFFAOYSA-N
CAS DataBase Reference: 4187-87-5(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: Xn
Risk Statements: 22-36/37/38
Safety Statements: 26-36
RIDADR: UN2810
WGK Germany: 3
RTECS: DO5900000
HazardClass: 6.1
PackingGroup: III
HS Code: 29062990
Toxicity: mouse,LD50,intraperitoneal,240mg/kg (240mg/kg),Farmaco, Edizione Scientifica. Vol. 8, Pg. 406, 1953.

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 226610
Product name: 1-Phenyl-2-propyn-1-ol
Purity: 98%
Packaging: 1g
Price: $24.51
Updated: 2025/07/31

Sigma-Aldrich

Product number: 226610
Product name: 1-Phenyl-2-propyn-1-ol
Purity: 98%
Packaging: 10g
Price: $186
Updated: 2025/07/31

TCI Chemical

Product number: P0220
Product name: 1-Phenyl-2-propyn-1-ol
Purity: >98.0%(GC)
Packaging: 5g
Price: $70
Updated: 2025/07/31

TCI Chemical

Product number: P0220
Product name: 1-Phenyl-2-propyn-1-ol
Purity: >98.0%(GC)
Packaging: 25g
Price: $267
Updated: 2025/07/31

TCI Chemical

Product number: P0220
Product name: 1-Phenyl-2-propyn-1-ol
Packaging: 1G
Price: $32
Updated: 2025/07/31

More

Less

1-PHENYL-2-PROPYN-1-OL Chemical Properties,Usage,Production

Chemical Properties

Clear yellow liquid

Synthesis

100-52-7

74-86-2

4187-87-5

The general procedure for the synthesis of (±)-1-phenyl-2-propyn-1-ol from benzaldehyde and acetylene was as follows: magnesium (518 mg, 28.3 mmol) was placed in a pre-flame-dried, two-necked, round-bottomed flask fitted with a reflux condenser and cooled to room temperature under argon atmosphere. Subsequently, tetrahydrofuran (30 mL) and a small amount of iodine crystals were added. Next, a portion of the total volume of n-butyl chloride (2.23 mL, 28.3 mmol) was added dropwise and the mixture was refluxed until the Grignard reagent was generated. After removing the unreacted n-butyl chloride, the remaining n-butyl chloride was added. Stirring was continued at room temperature until all the magnesium was consumed. The reaction mixture was cooled to 0°C and acetylene gas was passed into it over a period of 15 minutes. Subsequently, benzaldehyde (1.0 g, 9.4 mmol) dissolved in tetrahydrofuran (20 mL) was added at 0°C and stirred for 6 hours. Upon completion of the reaction, the reaction was quenched with saturated ammonium chloride solution, diluted with water and extracted with ethyl acetate. The organic layers were combined, dried with anhydrous sodium sulfate, concentrated and purified by silica gel column chromatography (eluent 10% petroleum ether solution of ethyl acetate) to afford the target product (±)-1-phenyl-2-propyn-1-ol (1.08 g, 86% yield) as a pale yellow oil.

References

[1] Liebigs Annalen der Chemie, 1982, # 9, p. 1750 - 1752
[2] Organic and Biomolecular Chemistry, 2013, vol. 11, # 35, p. 5954 - 5962
[3] Patent: WO2015/193915, 2015, A1. Location in patent: Page/Page column 11
[4] Liebigs Annalen, 1995, # 7, p. 1353 - 1360
[5] Synthesis, 2004, # 9, p. 1381 - 1390

1-PHENYL-2-PROPYN-1-OL Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

1-PHENYL-2-PROPYN-1-OL Suppliers

Americas 1 Belgium 1 China 140 Europe 1 France 1 Germany 5 India 3 Japan 3 South Korea 1 Switzerland 1 The Netherlands 1 United Kingdom 4 United States 31 Global 193

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12984
Advantage: 57

Sichuan Kulinan Technology Co., Ltd

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11705
Advantage: 57

More

Less

View Lastest Price from 1-PHENYL-2-PROPYN-1-OL manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 1-PHENYL-2-PROPYN-1-OL 4187-87-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-11

Shaanxi Dideu Medichem Co. Ltd

Product: 1-PHENYL-2-PROPYN-1-OL 4187-87-5
Price: US $1.00-35.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200000KG
Release date: 2024-07-30

Shanghai Rlavie Technology Co ltd

Product: 1-Phenyl-2-propyn-1-ol 4187-87-5
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 98%min
Supply Ability: 100kgs/month
Release date: 2021-11-27

4187-87-5, 1-PHENYL-2-PROPYN-1-OLRelated Search:

2-PHENYL-3-BUTYN-2-OL Enpromate 1,1,3-Triphenylpropargyl alcohol 1,1,4,4-TETRAPHENYL-2-BUTYN-1,4-DIOL 1,1-DIPHENYL-2-PROPYN-1-OL 9-ETHYNYL-9-FLUORENOL (-)-1,6-BIS(2-CHLOROPHENYL)-1,6-DIPHENYL-2,4-HEXADIYNE-1,6-DIOL 1-PHENYL-2-PROPYN-1-OL (R)-1-PHENYL-2-PROPYN-1-OL 1-PHENYL-1-PROPYN-3-OL,3-PHENYL-2-PROPYN-1-OL,3-PHENYL-2-PROPYN-1-OL 98+%,2-phenyl-2-propyn-1-ol Propyne Propargyl alcohol 3-PHENYL-1-PROPYNE Butinoline (S)-1-PHENYL-2-PROPYN-1-OL (+)-1,6-BIS(2-CHLOROPHENYL)-1,6-DIPHENYL-2,4-HEXADIYNE-1,6-DIOL 1,1,1-TRIFLUORO-2-PHENYL-3-BUTYN-2-OL 2,4-DIPHENYL-3-BUTYN-2-OL

TIMTEC-BB SBB008986

PHENYLETHYNYLCARBINOL

(+/-)-3-HYDROXY-3-PHENYL-1-PROPYNE

(+/-)-ALPHA-ETHYNYLBENZYL ALCOHOL

1-PHENYL-2-PROPYN-1-OL

1-PHENYL-2-PROPYNE-1-OL

1-PHENYL-PROP-2-YN-1-OL

1-PHENYLPROPARGYL ALCOHOL

(±)-α-ethynylbenzyl alcohol

à-ethynylbenzyl alcohol

1-PHENYL-2-PROPYN-1-OL: TECH., 85%

1-PHENYL-2-PROPYN-1-OL 98%

2-Propyn-1-ol, 1-phenyl-

alpha-ethynyl-benzenemethano

alpha-ethynylbenzenemethanol

alpha-ethynyl-benzylalcoho

alpha-Phenylpropargyl alcohol

alpha-phenylpropargylalcohol

Benzyl alcohol, alpha-ethynyl-

ETHYNYLPHENYLCARBINOL

A-PHENYLPROPARGYL ALCOHOL

Phenylpropynol

(±)-α-Ethynylbenzyl alcohol, (±)-1-Phenyl-2-propyn-1-ol, (±)-3-Hydroxy-3-phenyl-1-propyne, 1-Phenylpropargyl alcohol

(+/-)-1-PHENYL-2-PROPYN-1-OL, 98+%

α-Ethynylbenzenemethanol

(§1)-1-Phenyl-2-propyn-1-ol, 98+%

Ethynylphenylcarbinol 1-Phenylpropargyl Alcohol

Phenyl-2-propy

(±)-α-Ethynylbenzyl alcohol, (±)-3-Hydroxy-3-phenyl-1-propyne, 1-Phenylpropargyl alcohol

1-PHENYL-2-PROPYN-1-OL, 98%1-PHENYL-2-PROPYN-1-OL, 98%1-PHENYL-2-PROPYN-1-OL, 98%

1-Phenyl-2-propyn-1-ol&gt

Benzenemethanol, α-ethynyl-

1-PHENYL-2-PROPYN-1-OL ISO 9001：2015 REACH

(+/-)-1-phenyl-2-propyn-1-ol

α-Ethynylbenzenemethanol

4187-87-5

CH8801CCHOHC6H5

HCCCHOHC6H5

Acetylenic Alcohols & Their Derivatives

Acetylenes

Building Blocks

Alkynes

Organic Building Blocks

Terminal

Acetylenes

Acetylenic Alcohols & Their Derivatives