ChemicalBook > CAS DataBase List > Tetrabutylammonium hydrogen sulfate

Tetrabutylammonium hydrogen sulfate

Product Name
Tetrabutylammonium hydrogen sulfate
CAS No.
32503-27-8
Chemical Name
Tetrabutylammonium hydrogen sulfate
Synonyms
TBAHS;TETRABUTYLAMMONIUM BISULFATE;IPC-TBA-HS;TETRABUTYLAMMONIUM HYDROGEN SULPHATE;hydrogen sulfate,tetrabutylazanium;ammonium hydrog;TETRA-N-BUTYLAMMONIUM HYDROGEN SULPHATE;Tetrabutylammonium Hydrogen Sulfate [Reagent for Ion-Pair Chromatography];fate;en suL
CBNumber
CB0414623
Molecular Formula
C16H37NO4S
Formula Weight
339.53
MOL File
32503-27-8.mol
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Tetrabutylammonium hydrogen sulfate Property

Melting point:
171-174 °C
Boiling point:
213.3-593.92℃[at 101 325 Pa]
Density 
1.01
vapor pressure 
0Pa at 25℃
storage temp. 
Store below +30°C.
solubility 
H2O: soluble10% (w/v), clear, colorless
form 
Solution
color 
White to beige
Specific Gravity
1.01
PH
1-2 (100g/l, H2O, 20℃)
Odor
Amine like
PH Range
1 - 2
Water Solubility 
Soluble
Sensitive 
Hygroscopic
λmax
λ: 210 nm Amax: 0.06
λ: 220 nm Amax: 0.05
λ: 230 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02
BRN 
3599663
Stability:
Stable, but moisture sensitive. Incompatible with strong oxidizing agents.
InChIKey
SHFJWMWCIHQNCP-UHFFFAOYSA-M
LogP
0.96 at 25℃
CAS DataBase Reference
32503-27-8(CAS DataBase Reference)
NIST Chemistry Reference
Tetrabutylammonium hydrogen sulfate(32503-27-8)
EPA Substance Registry System
Tetrabutylammonium sulfate (1:1) (32503-27-8)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-22
Safety Statements 
26-36-37/39
WGK Germany 
3
F 
8-10
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29239000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
98479
Product name
Tetrabutylammonium bisulfate solution
Purity
suitable for ion pair chromatography, LiChropur?, concentrate, ampule
Packaging
6x1amp
Price
$597
Updated
2024/03/01
Sigma-Aldrich
Product number
86853
Product name
Tetrabutylammonium bisulfate
Purity
suitable for ion pair chromatography, LiChropur?, ≥99.0%
Packaging
10g
Price
$176
Updated
2024/03/01
Sigma-Aldrich
Product number
86853
Product name
Tetrabutylammonium bisulfate
Purity
suitable for ion pair chromatography, LiChropur?, ≥99.0%
Packaging
10x1g
Price
$572
Updated
2024/03/01
Sigma-Aldrich
Product number
86853
Product name
Tetrabutylammonium bisulfate
Purity
suitable for ion pair chromatography, LiChropur?, ≥99.0%
Packaging
50g
Price
$678
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18858
Product name
Tetra-n-butylammonium hydrogen sulfate
Purity
for synthesis
Packaging
100g
Price
$135
Updated
2024/03/01
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Tetrabutylammonium hydrogen sulfate Chemical Properties,Usage,Production

Chemical Properties

It is a stable, hygroscopic, white powder.

Uses

A compound that displays antibacterial properties due to the presence of the quaternary amine and the counter ion. Tetrabutylammonium hydrogen sulfate is an ion pairing reagent that is used in liquid chromatography. It is frequently utilized in the analysis of pharmaceutical compounds and metabolites.

Uses

Phase transfer catalyst Tetra-n-butylammonium hydrogen sulfate shows antibacterial properties due to the presence of the quaternary amine and the counter ion. It serves as a phase-transfer catalyst, surface-active agent, solvent, intermediate, active ingredient for conditioners, antistatic agent, detergent sanitizers, softener for textiles and paper products, emulsifying agents and pigment dispersers. Tetrabutylammonium hydrogensulfate is used as a cocatalyst in the synthesis of propionic acid and the ketones by hydrocarboxylation of ethylene. It is also used as an efficient catalyst in the N-alkylation reactions of benzanilides, cyclization of beta-amino acids to beta-lactams, conversion of nitriles to amides, dehydrohalogenation of aryl 2-haloethyl ethers to give vinyl ethers and in the oxidation of alcohols.

Preparation

Tetrabutylammonium hydrogen sulfate can be prepared from tetrabutylammonium azide by treating it with potassium hydrogen sulfate and 10% aqueous sulfuric acid in aqueous medium or from tetrabutylammonium thiocyanate by treating it with relatively concentrated sulfuric acid (70%) at 75 °C.

General Description

Tetrabutylammonium hydrogensulfate, a quaternary ammonium salt, is a phase-transfer reagent. It It serves as solvent for the dissolution of ruthenium(II) complex fac-[Ru(CO)2(H2O)3(C(O)C2H5)][CF3SO3]. It participates as a cocatalyst in the reaction medium for the preparation of alternating polyketones and propionic acid.

Purification Methods

The sulfate crystallises from acetone. It has been used as a phase transfer catalyst.

References

[1] H. N. KARADE M. P K M Sathe. An efficient synthesis of 1, 8-dioxo-octahydroxanthenes using tetrabutylammonium hydrogen sulfate[J]. Arkivoc, 2007, 2007 1. DOI:10.3998/ARK.5550190.0008.D28.
[2] A. J. PARDEY. New media in homogeneous catalysis: wet sodium or tetrabutylammonium hydrogensulfate salts for reppe syntheses catalyzed by a ru(ii) carbonyl complex[J]. Journal of Coordination Chemistry, 2004, 57 1: 871-882. DOI:10.1080/00928970410001721998.
[3] A. J. PARDEY. Hydrocarboxylation and stepwise alternating oligomerization of carbon monoxide and ethylene catalyzed by cis-[Rh(CO)2(amine)2](PF6) complexes in a wet liquid tetrabutylammonium hydrogensulfate[J]. Polyhedron, 2004, 23 1: 1677-1683. DOI:10.1016/J.POLY.2004.03.023.
[4] NEETU TEWARI Rama P T Namrata Dwivedi. Tetrabutylammonium hydrogen sulfate catalyzed eco-friendly and efficient synthesis of glycosyl 1,4-dihydropyridines[J]. Tetrahedron Letters, 2004, 45 49: Pages 9011-9014. DOI:10.1016/j.tetlet.2004.10.057.

Tetrabutylammonium hydrogen sulfate Preparation Products And Raw materials

Raw materials

Tributylamine 1-Iodobutane Tetra-n-butylammonium hydrogen sulfate Dilute hydrochloric acid

Preparation Products

ETHYLENE TRITHIOCARBONATE 1-(3-(4-AMINO-2,6-DICHLOROPHENOXY)PROPYL)PYRROLIDIN-2-ONE 3-AMINO-2,2-DIMETHYL-4-OXO-AZETIDINE-1-SULFONIC ACID 4,6-DIMETHYL-PYRIMIDINE-2-SULFONYL FLUORIDE Butyl glycidyl ether 4-METHYL-PYRIMIDINE-2-SULFONYL FLUORIDE 1-Bromo-4-methoxybutane Hydroxytyrosol 4-(2-(PIPERIDIN-1-YL)ETHOXY)-3,5-DICHLOROBENZENAMINE 1-(4-AMINO-2,6-DICHLOROPHENOXY)-3-(PYRROLIDIN-1-YL)PROPAN-2-OL 5-METHYL-PYRIMIDINE-2-SULFONYL FLUORIDE
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View Lastest Price from Tetrabutylammonium hydrogen sulfate manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Tetrabutylammonium hydrogen sulfate 32503-27-8
Price
US $110.00-70.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-14
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Tetrabutylammonium hydrogen sulfate 32503-27-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-14
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tetrabutylammonium hydrogen sulfate 32503-27-8
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-09

32503-27-8, Tetrabutylammonium hydrogen sulfateRelated Search:

Ammonium bisulfate Colistin sulfate calcium sulfate Sodium sulfate Neomycin sulfate Bis(tetrabutylammonium) sulphate Ferrous sulfate monohydrate Ammonium bisulfite TETRABUTYL AMMONIUM BROMIDE Tetrabutylammonium hydroxide Tetrabutylammonium perchlorate Tetrabutylammonium bromide Tetrabutylammonium phosphate Ammonium sulfate Hydrogen Potassium sulfate Tetrabutyl ammonium chloride Tetrabutylammonium fluoride Tetrabutylammonium Hydrogen Sulphate

  • ammonium hydrog
  • en suL
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  • Tetrabutylammonium Hydrogen Sulfate [Reagent for Ion-Pair Chromatography]
  • TETRA-N-BUTYLAMMONIUM HYDROGENSULFATE
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  • TETRABUTYLAMMONIUM HYDROGEN SULFATE
  • TETRABUTYLAMMONIUM HYDROGEN SULPHATE
  • TETRABUTYLAMMONIUM BISULFATE
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  • N4,4,4,4HSO4
  • Tetrabutylammonium hydrogensulfate,anhydrous, free-flowing
  • Tetrabutylammonium hydrogensulphate≥ 99% (Assay)
  • Tetra butyl ammonium hydrogen sulphate Solid
  • Tetra-n-butylammonium hydrogensulfate Msynthplus
  • Tetra-n-butylammonium hydrogen sulfate for ion pair chromatography LiChropur
  • hydrogen sulfate,tetrabutylazanium
  • Tetrabutylammonium hydrogensulfate, 99%, for ion-pair chromatography
  • TETRA BUTYL AMMONIUM HYDROGEN SULPHATE TBAHSO4
  • 1-Butanaminium,N,N,N-tributyl-,sulfate(1:1)
  • n,n,n-tributyl-1-butanaminiusulfate(1:1)
  • TETRABUTYLAMM.HYDROGENSULPHATE
  • TetrabutylAmmoniumHydrogenSulfateForSynthesis
  • TetrabutylAmmoniumHydrogenSulfateForHplc
  • Tetra-n-butylammoniumhydrogensulfate,98%
  • TETRABUTYLAMMONIUM HYDROGEN SULFATE 98+%
  • Tetrabutylammonium bisulfate solution
  • TETRABUTYLAMMONIUM HYDROGENSULFATE 97%
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  • tetrabutylammonium hydrogen sulfate solution
  • Tetrabutylammonium hydrogen sulphate 97%
  • 1-BUTANAMINIUM,N,N,N-TRIBUTYL-,SULFATE
  • TETRABUTYLAMMONIUM HYDROGEN SULFATE (TBAHS)
  • TETRABUTYLAMMONIUM HYDROGEN SULPHATE 30% SOLUTION
  • TETRA-N-BUTYLAMMONIUM.HYDROGENSULFATE ANALYTICAL GRADE
  • Tetrabutylammonium bisulfate solution,Tetrabutylammonium hydrogen sulfate solution
  • Tetrabutylammonium bisulfate,Tetrabutylammonium hydrogen sulfate
  • Tetrakis(but-1-yl)ammonium hydrogen sulphate 97%
  • Tetrabutylammonium bisulfate puriss., >=99.0% (T)
  • TetrabutylaMMo
  • TetrabutylaMMoniuM hydrogen sulfate, 98% 100GR
  • TetrabutylaMMoniuM hydrogen sulfate, 98% 1KG
  • TetrabutylaMMoniuM hydrogen sulfate, 98% 250GR
  • TetrabutylaMMoniuM hydrogen sulfate, 98% 25GR
  • TetrabutylaMMoniuM hydrogen sulfate, for HPLC, 99% 10GR
  • N,N,N-Tributyl-1-butanaMiniuM Sulfate
  • TBAHS-MB