ChemicalBook > CAS DataBase List > 4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE

4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE

Product Name
4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE
CAS No.
15646-46-5
Chemical Name
4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE
Synonyms
Oxazolone;AKOS BBS-00001130;Oxazolone, 10 mM in DMSO;OXAZOLONE SENSITIZING AGENT;4-ETHOXYMETHYLENE2-PHENYLOXAZOL-5-ONE;analytical standard, for drug analysis;4-EthoxyMethelene-2-phenyloxazolin-5-one;4-ETHOXYMETHYLENE-2-PHENYLOXAZOLIN-5-ONE;4-ETHOXYMETHYLEN-2-PHENYL-2-OXAZOLIN-5-O;4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN- &
CBNumber
CB0417644
Molecular Formula
C12H11NO3
Formula Weight
217.22
MOL File
15646-46-5.mol
More
Less

4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE Property

Melting point:
94-96 °C (dec.)(lit.)
Boiling point:
357.77°C (rough estimate)
Density 
1.2160 (rough estimate)
refractive index 
1.5560 (estimate)
storage temp. 
2-8°C
pka
-2.59±0.20(Predicted)
form 
Solid
color 
Gray to brown
Water Solubility 
Soluble in methanol (50 mg/ml), and water (partly).
BRN 
163055
InChI
InChI=1S/C12H11NO3/c1-2-15-8-10-12(14)16-11(13-10)9-6-4-3-5-7-9/h3-8H,2H2,1H3
InChIKey
SJHPCNCNNSSLPL-UHFFFAOYSA-N
SMILES
O1C(=O)C(=COCC)N=C1C1=CC=CC=C1
CAS DataBase Reference
15646-46-5(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
43
Safety Statements 
36
WGK Germany 
3
RTECS 
RQ5786250
HazardClass 
IRRITANT
HS Code 
29349990
Toxicity
mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#06780,
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
862207
Product name
4-Ethoxymethylene-2-phenyl-2-oxazolin-5-one
Purity
purified by recrystallization
Packaging
1g
Price
$49.1
Updated
2025/07/31
Sigma-Aldrich
Product number
862207
Product name
4-Ethoxymethylene-2-phenyl-2-oxazolin-5-one
Purity
purified by recrystallization
Packaging
10g
Price
$387.6
Updated
2025/07/31
Sigma-Aldrich
Product number
E0753
Product name
4-Ethoxymethylene-2-phenyl-2-oxazolin-5-one
Purity
analytical standard, for drug analysis
Packaging
1g
Price
$50.54
Updated
2025/07/31
Sigma-Aldrich
Product number
E0753
Product name
4-Ethoxymethylene-2-phenyl-2-oxazolin-5-one
Purity
analytical standard, for drug analysis
Packaging
5g
Price
$208
Updated
2025/07/31
Sigma-Aldrich
Product number
E0753
Product name
4-Ethoxymethylene-2-phenyl-2-oxazolin-5-one
Purity
analytical standard, for drug analysis
Packaging
10g
Price
$431
Updated
2025/07/31
More
Less

4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE Chemical Properties,Usage,Production

Chemical Properties

white to orange or pink powder

Uses

4-Ethoxymethylene-2-phenyloxazolin-5-one acts as sensitizing agent. It is also used as pharmaceutical intermediates.

Uses

4-Ethoxymethylene-2-phenyl-2-oxazolin-5-one has been used as a haptenizing agent, which can induce an inflammatory reaction in adult zebrafish intestinal tissues and this can be used as a model for gene expression studies of the two forms of inflammatory bowel disease like Crohn′s disease and ulcerative colitis.

Definition

ChEBI: A 1,3-oxazole compound having a phenyl substituent at the 2-position, an ethoxymethylene group at the 4-position, and an oxo group at the 5-position. It is a chemical allergen used for immunological experiments, particularly for experiments on delayed typ hypersensitivity.

Biological Activity

Oxazolone sensitizing agent

in vivo

Colitis induction[1]
1.Prepare procedure
Preparation of sensitization solution (I):
Mix acetone and olive oil in a 4:1 v/v ratio by vortexing. Dissolve a 60 mg oxazolone in 2 mL of this solution to obtain a 3 % (w/v) oxazolone sensitization solution. Mix the solution by carefully vortexing.
Preparation of challenge solution (II):
Dissolve 20 mg Oxazolone in 2 mL of 50 % ethanol to obtain a 1 % (w/v) solution. Mix the solution by careful vortexing. The oxazolone powder should be completely dissolved before use.

2. Experimental procedure
Sensitization pretreatment:
The electric scissors scraped an area of about 2 cmx2 cm on the skin of the mice's backs. Be careful to avoid open wounds.
Apply 150 μL of sensitizing solution (working solution 1) to the exposed skin of mice. Be careful to use an Oxazolone-free sensitizer as a control. Induction treatment:
Anesthetized mice: intraperitoneally injected ketamine/thiazide solution (80 μL/10 g), or inhaled with isoflurane anesthesia system.
The catheter was inserted into the colon of the mice (about 3-4 cm deep at the proximal end of the anus). The other end of the catheter is connected to a 1 mL syringe.
About 100 μL of oxazolone stimulation solution is injected into the colonic cavity through a catheter for 10 to 30 seconds. After dosing, hold the mouse in a vertical position (head down) for 60 seconds.

IC 50

IL-4; IL-13; TNFR1

4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE Suppliers

Bide Pharmatech Ltd.
Tel
400-6005915
Email
sales@picasso-e.com
Country
China
ProdList
39653
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15838
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai Meishui Chemical Technology Co., Ltd
Tel
021-60549325 18616193163
Fax
021-33250306
Country
China
ProdList
4526
Advantage
56
More
Less

View Lastest Price from 4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE 15646-46-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE 15646-46-5
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-02-20

15646-46-5, 4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONERelated Search:


  • 4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN-5-ONE
  • 4-Ethoxymethylene-2-phenyl-2-oxazolin-5-one,97%
  • 2-Oxazolin-5-one, 4-ethoxymethylene-2-phenyl-
  • (4E)-4-(Ethoxymethylene)-2-phenyl-1,3-oxazol-5(4H)-one
  • 4-EthoxyMethelene-2-phenyloxazolin-5-one
  • 4-EthoxyMethylene-2-phenyl-2-oxazolin-5-one purified by recrystallization
  • 4-ETHOXYMETHYLENE-2-PHENYLOXAZOLIN-5-ONE
  • 4-ETHOXYMETHYLENE-2-PHENYLOXAZOLINE-5-ONE
  • AKOS BBS-00001130
  • OXAZOLONE SENSITIZING AGENT
  • 4-(ethoxymethylene)-2-phenyl-5(4h)-oxazolon
  • 4-ethoxymethylene-2-phenyl-2-oxazolin-5-on
  • 4-ETHOXYMETHYLEN-2-PHENYL-2-OXAZOLIN-5-O
  • 4-ETHOXYMETHYLENE-2-PHENYL-2-OXAZOLIN- &
  • 4-Ethoxymethylene-2-phenyloxazolin-5-one, 98+%
  • Oxazolone
  • 4-ETHOXYMETHYLENE2-PHENYLOXAZOL-5-ONE
  • 2-Phenyl-4-(ethoxymethylene)-2-oxazoline-5-one
  • 4-(Ethoxymethylene)-2-phenyloxazol-5(4H)-one
  • 5(4H)-Oxazolone, 4-(ethoxymethylene)-2-phenyl-
  • (E)-4-(Ethoxymethylene)-2-phenyloxazol-5(4H)-one
  • analytical standard, for drug analysis
  • (4Z)-4-(ethoxymethylidene)-2-phenyl-1,3-oxazol-5-one
  • Oxazolone, 10 mM in DMSO
  • 15646-46-5
  • Heterocyclic Building Blocks
  • EQ - EZ
  • Oxazolines/Oxazolidines
  • Alphabetic
  • Analytical Chromatography Product Catalog
  • Building Blocks
  • Analytical Standards
  • Building Blocks
  • Heterocyclic Building Blocks
  • Oxazolines/Oxazolidines
  • API intermediates