(3-CHLORO-5-NITROPHENYL)METHANOL
- Product Name
- (3-CHLORO-5-NITROPHENYL)METHANOL
- CAS No.
- 79944-62-0
- Chemical Name
- (3-CHLORO-5-NITROPHENYL)METHANOL
- Synonyms
- Benzenamine,2-bromo-7-methyl-;3-Chloro-5-nitrobenzyl alcohol;3-chloro-5-nitroBenzenemethanol;(3-CHLORO-5-NITROPHENYL)METHANOL;Benzenemethanol, 3-chloro-5-nitro-;(3-Chloro-5-nitrophenyl)methanol, 96%
- CBNumber
- CB0429186
- Molecular Formula
- C7H6ClNO3
- Formula Weight
- 187.58
- MOL File
- 79944-62-0.mol
(3-CHLORO-5-NITROPHENYL)METHANOL Property
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- White to off-white Solid
Safety
- HS Code
- 2906290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- C611660
- Product name
- (3-Chloro-5-nitrophenyl)methanol
- Packaging
- 500mg
- Price
- $240
- Updated
- 2021/12/16
- Product number
- 4654-5-1N
- Product name
- 3-Chloro-5-nitrobenzyl alcohol
- Packaging
- 250mg
- Price
- $88
- Updated
- 2021/12/16
- Product number
- 2488AC
- Product name
- (3-Chloro-5-nitrophenyl)methanol
- Packaging
- 250mg
- Price
- $151
- Updated
- 2021/12/16
- Product number
- 4654-5-1N
- Product name
- 3-Chloro-5-nitrobenzyl alcohol
- Packaging
- 1g
- Price
- $216
- Updated
- 2021/12/16
- Product number
- 2488AC
- Product name
- (3-Chloro-5-nitrophenyl)methanol
- Packaging
- 1g
- Price
- $304
- Updated
- 2021/12/16
(3-CHLORO-5-NITROPHENYL)METHANOL Chemical Properties,Usage,Production
Synthesis
34662-36-7
79944-62-0
1. 3-Chloro-5-nitrobenzoic acid (5.00 g, 24.8 mmol, ABCR GmbH & CO.KG) was dissolved in THF (48 mL) at 0 °C and stirred until homogeneous. 2. To the above solution, a THF solution of 1 M borane-THF complex (99.2 mL, 99.2 mmol) was slowly added, keeping the temperature at 0 °C. 3. The reaction mixture was gradually warmed to room temperature and the reaction was stirred overnight. 4. Upon completion of the reaction, MeOH was slowly added to the stirred mixture under ice bath cooling to quench the reaction. 5. The reaction mixture was diluted with ethyl acetate and washed sequentially with 1N aqueous sodium hydroxide and saturated aqueous sodium chloride. 6. The organic phase was separated, dried over anhydrous sodium sulfate, filtered and concentrated. 7. The residue was purified by column chromatography (eluent: hexane/ethyl acetate, gradient from 50% to 100%) to give pure 3-chloro-5-nitrobenzyl alcohol (4.22 g, 22.5 mmol). 8. The structure of the product was determined by NMR. 8. The structure of the product was confirmed by NMR (400 MHz, CDCl3, 300 K): δ = 8.13 (m, 2H), 7.71 (s, 1H), 4.81 (m, 2H), 2.00 (br, 1H).
References
[1] Patent: WO2014/76028, 2014, A1. Location in patent: Page/Page column 97
(3-CHLORO-5-NITROPHENYL)METHANOL Preparation Products And Raw materials
Raw materials
Preparation Products
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