4-Fluoro-3-nitroaniline
- Product Name
- 4-Fluoro-3-nitroaniline
- CAS No.
- 364-76-1
- Chemical Name
- 4-Fluoro-3-nitroaniline
- Synonyms
- 3-NITRO-4-FLUOROANILINE;4-Fluoro-3-nitrobenzenamine;4-F-3NA;uoro-3-nitroaniL;4-Fluoro-3-nitroanil;4-Fluor-3-nitroanilin;4-FLUORO-3-NITROANILINE;4-fluoro-3-nitro-anilin;4-Fluoro-3-phenylnitramine;4-Fluoro-3-nitroaniline98%
- CBNumber
- CB0430717
- Molecular Formula
- C6H5FN2O2
- Formula Weight
- 156.11
- MOL File
- 364-76-1.mol
4-Fluoro-3-nitroaniline Property
- Melting point:
- 94-96 °C (lit.)
- Boiling point:
- 331.3±22.0 °C(Predicted)
- Density
- 0.43 g/cm3 (20℃)
- Flash point:
- 196 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- Powder
- pka
- 2.36±0.10(Predicted)
- color
- Ochre
- Water Solubility
- Insoluble
- BRN
- 2210199
- InChI
- InChI=1S/C6H5FN2O2/c7-5-2-1-4(8)3-6(5)9(10)11/h1-3H,8H2
- InChIKey
- LLIOADBCFIXIEU-UHFFFAOYSA-N
- SMILES
- C1(N)=CC=C(F)C([N+]([O-])=O)=C1
- CAS DataBase Reference
- 364-76-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenamine, 4-fluoro-3-nitro-(364-76-1)
- EPA Substance Registry System
- 4-Fluoro-3-nitroaniline (364-76-1)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 20/21/22-36/37/38-22
- Safety Statements
- 36/37-37/39-26
- RIDADR
- UN 1325 4.1/PG 2
- WGK Germany
- 2
- RTECS
- BY1700000
- Hazard Note
- Irritant
- TSCA
- T
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29214210
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H301Toxic if swalloed
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 155861
- Product name
- 4-Fluoro-3-nitroaniline
- Purity
- 97%
- Packaging
- 25g
- Price
- $26.11
- Updated
- 2025/07/31
- Product number
- 155861
- Product name
- 4-Fluoro-3-nitroaniline
- Purity
- 97%
- Packaging
- 100g
- Price
- $142
- Updated
- 2025/07/31
- Product number
- F0168
- Product name
- 4-Fluoro-3-nitroaniline
- Purity
- >98.0%(GC)
- Packaging
- 10g
- Price
- $23
- Updated
- 2021/12/16
- Product number
- F0168
- Product name
- 4-Fluoro-3-nitroaniline
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $34
- Updated
- 2025/07/31
- Product number
- F621950
- Product name
- 4-Fluoro-3-nitroaniline
- Packaging
- 5g
- Price
- $45
- Updated
- 2021/12/16
4-Fluoro-3-nitroaniline Chemical Properties,Usage,Production
Chemical Properties
whitetolightyellowcrystalpowde
Uses
4-Fluoro-3-nitroaniline is used in the preparation of commercial hair dyes. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals.
Uses
4-Fluoro-3-nitroaniline was used in the preparation of commercial hair dyes.
Definition
ChEBI: 4-fluoro-3-nitroaniline is a nitroaniline and an organofluorine compound.
Synthesis
70-34-8
364-76-1
369-36-8
Example 43: General procedure for the synthesis of 4-fluoro-3-nitroaniline and 2-fluoro-5-nitroaniline from 2,4-dinitrofluorobenzene. A hydrogenation reaction was carried out according to the method described in Example 25 using 5% rhodium/alumina as a catalyst. This was done as follows: 18.61 g (0.10 mol) of 2,4-dinitrofluorobenzene was dissolved in a solvent mixture of 100 ml of glacial acetic acid and 100 ml of anhydrous ethanol in the presence of an alumina hydrogenation catalyst containing 0.50 g of rhodium. The hydrogen pressure was maintained at 370 psi during the reaction and the reaction time was 2 hours. Upon completion of the reaction, the product was separated by column chromatography to afford 2.79 g of 2-fluoro-5-nitroaniline in 17.6% yield. In addition, 0.85 g of 4-fluoro-3-nitroaniline was recovered as a second fraction.
References
[1] Tetrahedron Letters, 1990, vol. 31, # 43, p. 6141 - 6144
[2] Tetrahedron Letters, 1990, vol. 31, # 43, p. 6141 - 6144
[3] Patent: US5105012, 1992, A
[4] Recueil des Travaux Chimiques des Pays-Bas, 1946, vol. 65, p. 329,330
[5] Russian Journal of General Chemistry, 2006, vol. 76, # 1, p. 76 - 81
4-Fluoro-3-nitroaniline Preparation Products And Raw materials
Raw materials
Preparation Products
4-Fluoro-3-nitroaniline Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from 4-Fluoro-3-nitroaniline manufacturers
- Product
- 4-Fluoro-3-nitroaniline 364-76-1
- Price
- US $2.20-8.80/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 1000kg
- Release date
- 2025-09-09
- Product
- 4-Fluoro-3-nitroaniline 364-76-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-24
- Product
- 4-Fluoro-3-nitroaniline 364-76-1
- Price
- US $25.00/KG
- Min. Order
- 100KG
- Purity
- 99.5%
- Supply Ability
- 100 mt
- Release date
- 2025-03-10