4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE
- Product Name
- 4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE
- CAS No.
- 13104-56-8
- Chemical Name
- 4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE
- Synonyms
- 4'-(4-Methoxyphenyl)-2,2':6',2;4'-(4-methoxyphenyl)-2.2:6,2"-Terpyridine;4'-(4-METHOXYPHENYL)-2,2':6',2'-TERPYRIDINE;4'-(4-Methoxyphenyl)-2,2':6',2"-terpyridine;4'-(4-Methoxyphenyl)-2,2':6',2''-terpyridine;4'-(p-Methoxyphenyl)-2,2':6',2''-terpyridine;2,6-Di[2-pyridyl-4-(p-methoxyphenyl)pyridine;4-(4-methoxyphenyl)-2,6-dipyridin-2-ylpyridine;2,2':6',2''-Terpyridine, 4'-(4-methoxyphenyl)-;2,6-bis(2'-pyridyl)-4-(p-methoxyphenyl)pyridine
- CBNumber
- CB0446792
- Molecular Formula
- C22H17N3O
- Formula Weight
- 339.39
- MOL File
- 13104-56-8.mol
4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE Property
- Melting point:
- 167-168℃
- Boiling point:
- 504.5±50.0 °C(Predicted)
- Density
- 1.174±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 4.62±0.22(Predicted)
- Appearance
- White to off-white Solid
- Water Solubility
- Insoluble in water.
- CAS DataBase Reference
- 13104-56-8
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- M2951
- Product name
- 4'-(4-Methoxyphenyl)-2,2':6',2''-terpyridine
- Packaging
- 200MG
- Price
- $69
- Updated
- 2025/07/31
- Product number
- M2951
- Product name
- 4'-(4-Methoxyphenyl)-2,2':6',2''-terpyridine
- Packaging
- 1G
- Price
- $208
- Updated
- 2025/07/31
- Product number
- CHM0012878
- Product name
- 4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $503.33
- Updated
- 2021/12/16
- Product number
- AS574753
- Product name
- 4'-(4-Methoxyphenyl)-2,2':6',2''-terpyridine
- Purity
- 97%
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- AS574753
- Product name
- 4'-(4-Methoxyphenyl)-2,2':6',2''-terpyridine
- Purity
- 97%
- Packaging
- 1g
- Price
- $148
- Updated
- 2021/12/16
4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE Chemical Properties,Usage,Production
Uses
4'-(4-Methoxyphenyl)-2,2':6',2''-terpyridine is used as an organic chemical synthesis intermediate.
Synthesis
1122-62-9
123-11-5
13104-56-8
Generic method: 4'-(3-methoxyphenyl)-2,2':6',2"-terpyridine (3-MeO-Phtpy), 4'-(2-methoxyphenyl)-2,2':6',2"-terpyridine (2-MeO-Phtpy) and 4'-(4-methoxyphenyl)-2,2':6',2"-terpyridine (4-MeO-Phtpy) The synthesis was carried out with reference to the method described in the literature [27-33]. The steps were as follows: 2-acetylpyridine (2.813 g, 23.2 mmol, 2 eq.) was added to a 50 mL ethanol solution dissolved in 2-methoxybenzaldehyde, 3-methoxybenzaldehyde or 4-methoxybenzaldehyde (11.6 mmol, 1 eq.). Subsequently, KOH pellets (46.5 mmol, 4 eq.) were added to this solution. The reaction mixture was stirred at room temperature for 10 minutes. NH3 (40 mL, 25% aqueous solution) was slowly added to the reaction mixture. After incubation at 37 °C for 24 h, 5 mL of 25% aqueous NH3 was added. The reaction mixture was cooled to -20 °C and the resulting white precipitate was separated by filtration and washed with cold ethanol. For further purification of each product, recrystallization was carried out using ethanol-H2O mixed solvent. After recrystallization, each product was recovered by filtration, washed sequentially with cold ethanol and petroleum ether, and finally dried under high vacuum for 24 h (Scheme 1).
References
[1] Applied Organometallic Chemistry, 2017, vol. 31, # 10,
[2] Applied Organometallic Chemistry, 2017, vol. 31, # 6,
[3] Chemistry - An Asian Journal, 2018, vol. 13, # 21, p. 3169 - 3172
[4] Chemistry Letters, 2005, vol. 34, # 5, p. 732 - 733
[5] Synthesis, 2005, # 18, p. 3045 - 3050
4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE manufacturers
- Product
- 4'-(4-METHOXYPHENYL)-2,2':6',2''-TERPYRIDINE 13104-56-8
- Price
- US $64.00-206.00/g
- Min. Order
- 5g
- Purity
- 0.98
- Supply Ability
- 25kg
- Release date
- 2025-07-08