4-(2-THIAZOLYL)PHENOL

Product Name: 4-(2-THIAZOLYL)PHENOL
CAS No.: 81015-49-8
Chemical Name: 4-(2-THIAZOLYL)PHENOL
Synonyms: 4-(2-Thiazolyl);4-(2-THIAZOLYL)PHENOL;4-(2-Thiazolyl)phenol8;Phenol, 4-(2-thiazolyl)-;4-(2-Thiazolyl)phenol95%;4-(2-THIAZOLYL)PHENOL 95%;4-(1,3-Thiazol-2-yl)phenol;2-(4-chlorophenyl)thiazole;4-(3H-1,3-thiazol-2-ylidene)cyclohexa-2,5-dien-1-one
CBNumber: CB0466905
Molecular Formula: C9H7NOS
Formula Weight: 177.22
MOL File: 81015-49-8.mol

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4-(2-THIAZOLYL)PHENOL Property

Melting point:: 162-165℃
storage temp.: Store at room temperature
Appearance: Light yellow to yellow Solid
CAS DataBase Reference: 81015-49-8

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Safety

HS Code: 2934100090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: T430125
Product name: 4-(2-Thiazolyl)phenol
Packaging: 25mg
Price: $45
Updated: 2021/12/16

AK Scientific

Product number: W8566
Product name: 4-(2-Thiazolyl)phenol
Packaging: 100mg
Price: $95
Updated: 2021/12/16

Apolloscientific

Product number: OR913227
Product name: 4-(2-Thiazolyl)phenol
Purity: 95%
Packaging: 1g
Price: $115
Updated: 2021/12/16

Matrix Scientific

Product number: 071922
Product name: 4-(2-Thiazolyl)phenol
Purity: 95+%
Packaging: 1g
Price: $347
Updated: 2021/12/16

Apolloscientific

Product number: OR913227
Product name: 4-(2-Thiazolyl)phenol
Purity: 95%
Packaging: 5g
Price: $395
Updated: 2021/12/16

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4-(2-THIAZOLYL)PHENOL Chemical Properties,Usage,Production

Synthesis

27088-84-2

81015-49-8

Step 2: Synthesis of 4-thiazol-2-yl-phenol; Boron tribromide (2.00 ml, 15.7 mmol) was added slowly and dropwise to a solution of dichloromethane (25 ml) of the product obtained in step 1 (1.0 g, 5.23 mmol) at -78 °C, keeping the temperature at -78 °C and stirring the reaction for 1 hour. Subsequently, the reaction mixture was warmed to room temperature and stirring was continued for 16 hours. After completion of the reaction, the reaction was quenched by slowly pouring the mixture into ice water. The solid product was collected by filtration and washed with ether to give the final target product 4-thiazol-2-yl-phenol (0.84 g, 84% yield); 1H NMR (400 MHz, CDCl3) δ 7.85 (d, J = 3.2Hz, 1H), 7.79 (d, J = 8.8Hz, 2H), 7.67 (d, J = 3.2Hz, 1H), 7.67 (d, J = 3.2Hz, 1H), 7.67 (d, J = 3.2Hz, 1H), and 6.88 (d, J = 8.8 Hz, 2H); MS (ESI-) m/z 176 ([M-H]-, 100).

References

[1] European Journal of Medicinal Chemistry, 2010, vol. 45, # 6, p. 2299 - 2306
[2] Patent: US2007/66820, 2007, A1. Location in patent: Page/Page column 78
[3] Patent: US2008/33024, 2008, A1. Location in patent: Page/Page column 7; 16
[4] Journal of Medicinal Chemistry, 1986, vol. 29, # 6, p. 1065 - 1080
[5] Journal of the American Chemical Society, 1930, vol. 52, p. 1585

4-(2-THIAZOLYL)PHENOL Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(2-THIAZOLYL)PHENOL Suppliers

China 55 Germany 1 India 2 United Kingdom 2 United States 7 Global 67

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81015-49-8, 4-(2-THIAZOLYL)PHENOLRelated Search:

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4-(2-Thiazolyl)phenol95%

2-(4-chlorophenyl)thiazole

4-(2-THIAZOLYL)PHENOL 95%

4-(2-THIAZOLYL)PHENOL

4-(1,3-Thiazol-2-yl)phenol

4-(2-Thiazolyl)

Phenol, 4-(2-thiazolyl)-

4-(2-Thiazolyl)phenol8

4-(3H-1,3-thiazol-2-ylidene)cyclohexa-2,5-dien-1-one

81015-49-8