ChemicalBook > CAS DataBase List > 4-PYRROLIDIN-1-YLANILINE

4-PYRROLIDIN-1-YLANILINE

Product Name
4-PYRROLIDIN-1-YLANILINE
CAS No.
2632-65-7
Chemical Name
4-PYRROLIDIN-1-YLANILINE
Synonyms
AKOS BB-8560;AKOS B021942;ART-CHEM-BB B021942;TIMTEC-BB SBB009578;4-pyrrolidinoaniline;4-PYRROLIDIN-1-YLANILINE;4-(1-PYRROLIDINYL)ANILINE;1-(4-Aminophenyl)pyrrolidine;4-(1-pyrrolidinyl)phenylamine;4-PYRROLIDIN-1-YL-PHENYLAMINE
CBNumber
CB0674997
Molecular Formula
C10H14N2
Formula Weight
162.23
MOL File
2632-65-7.mol
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4-PYRROLIDIN-1-YLANILINE Property

Melting point:
51 °C
Boiling point:
180-185 °C(Press: 16 Torr)
Density 
1.109±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
7.20±0.40(Predicted)
Appearance
Brown to black Solid
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Safety

HazardClass 
IRRITANT
HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B525040
Product name
4-Pyrrolidin-1-ylaniline
Packaging
100mg
Price
$75
Updated
2021/12/16
SynQuest Laboratories
Product number
3H30-1-F9
Product name
4-(Pyrrolidin-1-yl)aniline
Packaging
1g
Price
$135
Updated
2021/12/16
Matrix Scientific
Product number
033452
Product name
4-(1-Pyrrolidinyl)aniline
Packaging
500mg
Price
$155
Updated
2021/12/16
SynQuest Laboratories
Product number
3H30-1-F9
Product name
4-(Pyrrolidin-1-yl)aniline
Packaging
250mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
2324AB
Product name
4-(Pyrrolidin-1-yl)aniline
Packaging
5g
Price
$251
Updated
2021/12/16
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4-PYRROLIDIN-1-YLANILINE Chemical Properties,Usage,Production

Synthesis

10220-22-1

2632-65-7

GENERAL PROCEDURE: The general method for the synthesis of 4-(pyrrolidin-1-yl)aniline from 1-(4-nitrophenyl)pyrrolidine is as follows: 1-(substituted)4-nitrophenyl derivatives IVa, b, e, f (0.01 mol) were dissolved in NH4OH (20 mL, 30%) and an aqueous solution of sodium conidiosulfite (7 g, 0.04 mol) was quickly added (30 mL). The reaction mixture was refluxed for 15 min. After completion of the reaction, the mixture was cooled and the crude product was obtained by filtration. The crude product was washed and crystallized from dichloromethane to give the target compounds Va, b, e, f. Among them, 4-(pyrrolidin-1-yl)aniline Vb was obtained in 80% yield as a yellow oily substance (in agreement with the literature report) [66].

References

[1] Bulletin of the Korean Chemical Society, 2015, vol. 36, # 7, p. 1863 - 1873
[2] Bioorganic Chemistry, 2014, vol. 57, p. 65 - 82
[3] Advanced Synthesis and Catalysis, 2018, vol. 360, # 11, p. 2131 - 2137
[4] Patent: US2005/49286, 2005, A1
[5] Justus Liebigs Annalen der Chemie, 1955, vol. 596, p. 1,151

4-PYRROLIDIN-1-YLANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-PYRROLIDIN-1-YLANILINE manufacturers

Career Henan Chemical Co
Product
4-PYRROLIDIN-1-YLANILINE 2632-65-7
Price
US $1.00/KG
Min. Order
1G
Purity
99%
Supply Ability
100KG
Release date
2018-08-13