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ChemicalBook > CAS DataBase List > (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

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Product Name
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
CAS No.
129648-07-3
Chemical Name
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
Synonyms
ano)ethane;(R,R)-ME-BPE;Bisdimethylphospholanoethane;(+)-1,2-Bis((2R,5R)-2,5-dimethyL;(+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane;1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane;1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane;(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE;(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane;(+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95%
CBNumber
CB0683443
Molecular Formula
C14H28P2
Formula Weight
258.32
MOL File
129648-07-3.mol
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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Property

Boiling point:
64-67 °C 0.06 mm Hg
alpha 
+263° ±3° (c 1, hexane)
Density 
0.940 g/mL at 25 °C
refractive index 
n20/D 1.534
form 
liquid
color 
colorless to pale-yellow
Sensitive 
Air Sensitive
CAS DataBase Reference
129648-07-3
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Safety

Hazard Codes 
F
Risk Statements 
11-17
Safety Statements 
24/25
RIDADR 
UN 2845 4.2/PG 1
WGK Germany 
3
HazardClass 
4.2
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H250Catches fire spontaneously if exposed to air

H252Self-heating in large quantities; may catch fire

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P222Do not allow contact with air.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5985
Product name
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane
Packaging
100MG
Price
$132
Updated
2024/03/01
TCI Chemical
Product number
B5985
Product name
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane
Packaging
500MG
Price
$552
Updated
2024/03/01
Alfa Aesar
Product number
H60071
Product name
1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane, 97+%
Packaging
250mg
Price
$86.8
Updated
2021/12/16
Alfa Aesar
Product number
H60071
Product name
1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane, 97+%
Packaging
1g
Price
$325
Updated
2021/12/16
Strem Chemicals
Product number
15-0104
Product name
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE
Packaging
100mg
Price
$75
Updated
2024/03/01
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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Chemical Properties,Usage,Production

Reactions

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.

Chemical Properties

Clear colorless oily liquid

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Suppliers

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129648-07-3, (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANERelated Search:


  • (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
  • (R,R)-ME-BPE
  • Bisdimethylphospholanoethane
  • (+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane, Kanata purity
  • (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE
  • (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95%
  • 1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ethane, 97+%
  • (+)-1,2-Bis((2R,5R)-2,5-diMethylphospholano)ethane (R,R)-Me-BPE
  • (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane, 97% (R,R-Me-BPE)
  • 1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane
  • 1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane
  • ano)ethane
  • Phospholane, 1,1'-(1,2-ethanediyl)bis[2,5-dimethyl-, (2R,2'R,5R,5'R)-
  • (+)-1,2-Bis((2R,5R)-2,5-dimethyL
  • (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane
  • (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane
  • (+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane
  • 129648-07-3
  • C14H28P2
  • organophosphine ligand