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ChemicalBook > CAS DataBase List > (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

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Product Name
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
CAS No.
129648-07-3
Chemical Name
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
Synonyms
ano)ethane;(R,R)-ME-BPE;Bisdimethylphospholanoethane;(+)-1,2-Bis((2R,5R)-2,5-dimethyL;(+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane;1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane;1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane;(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane;(+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95%;1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ethane, 97+%
CBNumber
CB0683443
Molecular Formula
C14H28P2
Formula Weight
258.32
MOL File
129648-07-3.mol
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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Property

Boiling point:
64-67 °C 0.06 mm Hg
alpha 
+263° ±3° (c 1, hexane)
Density 
0.940 g/mL at 25 °C
refractive index 
n20/D 1.534
storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
liquid
color 
colorless to pale-yellow
Sensitive 
Air Sensitive
CAS DataBase Reference
129648-07-3
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Safety

Hazard Codes 
F
Risk Statements 
11-17
Safety Statements 
24/25
RIDADR 
UN 2845 4.2/PG 1
WGK Germany 
3
HazardClass 
4.2
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H250Catches fire spontaneously if exposed to air

H252Self-heating in large quantities; may catch fire

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P222Do not allow contact with air.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5985
Product name
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane
Packaging
100MG
Price
$244
Updated
2025/07/31
TCI Chemical
Product number
B5985
Product name
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane
Packaging
500MG
Price
$1022
Updated
2025/07/31
Strem Chemicals
Product number
15-0104
Product name
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE
Packaging
100mg
Price
$75
Updated
2024/03/01
Strem Chemicals
Product number
15-0104
Product name
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE
Packaging
500mg
Price
$278
Updated
2024/03/01
Strem Chemicals
Product number
15-0104
Product name
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE
Packaging
2g
Price
$889
Updated
2024/03/01
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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Chemical Properties,Usage,Production

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The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.

Chemical Properties

Clear colorless oily liquid

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Suppliers

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129648-07-3, (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANERelated Search:


  • (R,R)-ME-BPE
  • Bisdimethylphospholanoethane
  • (+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane, Kanata purity
  • (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE
  • (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95%
  • 1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ethane, 97+%
  • (+)-1,2-Bis((2R,5R)-2,5-diMethylphospholano)ethane (R,R)-Me-BPE
  • (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane, 97% (R,R-Me-BPE)
  • 1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane
  • 1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane
  • ano)ethane
  • Phospholane, 1,1'-(1,2-ethanediyl)bis[2,5-dimethyl-, (2R,2'R,5R,5'R)-
  • (+)-1,2-Bis((2R,5R)-2,5-dimethyL
  • (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane
  • (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane
  • (+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane
  • 129648-07-3
  • C14H28P2
  • organophosphine ligand