Physical Properties Occurrence and Uses Production
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Zinc sulfate monohydrate

Physical Properties Occurrence and Uses Production
Product Name
Zinc sulfate monohydrate
CAS No.
7446-19-7
Chemical Name
Zinc sulfate monohydrate
Synonyms
ZINC SULFATE;ZINC SULPHATE MONOHYDRATE;Zinc Sulfate mono;Gunningite;SULFURIC ACID ZINC SALT MONOHYDRATE;zincfertilizer;ZINCSULFATE,FCC;ZINC SULPHATE H2O;ZincSulphateDried;ZINC SULPHATE 1H2O
CBNumber
CB0684031
Molecular Formula
H2O4S.H2O.Zn
Formula Weight
181.47
MOL File
7446-19-7.mol
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Zinc sulfate monohydrate Property

Melting point:
decomposes at 238℃ [KIR84]
Density 
1.005 g/mL at 25 °C
storage temp. 
2-30°C
solubility 
water: soluble(lit.)
form 
Powder
color 
White
PH
4.0-5.6 (20°C, 50g/L in H2O)
Water Solubility 
Soluble in water and alcohol.
Merck 
14,10159
BCS Class
3
Stability:
Stable.
InChI
InChI=1S/H2O4S.H2O.Zn/c1-5(2,3)4;;/h(H2,1,2,3,4);1H2;
InChIKey
MZNYADCLSDCSHV-UHFFFAOYSA-N
SMILES
S(O)(O)(=O)=O.O.[Zn]
LogP
-1.031 (est)
CAS DataBase Reference
7446-19-7(CAS DataBase Reference)
EPA Substance Registry System
Zinc sulfate monohydrate (7446-19-7)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
22-41-50/53
Safety Statements 
22-26-39-46-60-61
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
3
TSCA 
Yes
HazardClass 
9
HS Code 
28332930
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
PHR2917
Product name
Zinc Sulfate
Purity
certified reference material, pharmaceutical secondary standard
Packaging
1G
Price
$185
Updated
2025/07/31
Sigma-Aldrich
Product number
307491
Product name
Zinc sulfate monohydrate
Purity
≥99.9% trace metals basis
Packaging
100g
Price
$73.6
Updated
2025/07/31
Sigma-Aldrich
Product number
307491
Product name
Zinc sulfate monohydrate
Purity
≥99.9% trace metals basis
Packaging
500g
Price
$235
Updated
2025/07/31
Sigma-Aldrich
Product number
1.08882
Product name
Zinc sulfate monohydrate
Purity
EMPROVE? ESSENTIAL, Ph. Eur., USP
Packaging
0.75KG
Price
$262
Updated
2025/07/31
Sigma-Aldrich
Product number
1.08882
Product name
Zinc sulfate monohydrate
Purity
EMPROVE? ESSENTIAL, Ph. Eur., USP
Packaging
5KG
Price
$1114
Updated
2025/07/31
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Zinc sulfate monohydrate Chemical Properties,Usage,Production

Physical Properties

Zinc sulfate monohydrate is a white, free-flowing powder that is hygroscopic and readily soluble in water. It is slightly soluble in alcohol and insoluble in acetone. This compound serves as a key raw material for the manufacture of zinc salts and zinc barium white.

The anhydrous sulfate is a colorless rhombohedral crystalline solid; refractive index 1.658; density 3.54 g/cm3; decomposes at 600°C; soluble in water, methanol, and glycerol. 
The heptahydrate, ZnSO4.7H2O, is a colorless crystalline solid; metallic taste; rhombohedral crystals; effloresces; refractive index 1.457; density 1.957 g/cm3 at 25°C; melts at 100°C; loses all its water molecules at 280°C; decomposes above 500°C; very soluble in water, 96.5 g/100mL at 20°C; soluble in glycerol, 40 g/100 mL; insoluble in alcohol. 
The hexahydrate, ZnSO4.6H2O constitutes colorless monoclinic or tetragonal crystals; density 2.072 g/cm3 at 15°C; loses five water molecules at 70°C; soluble in water.

Occurrence and Uses

Zinc sulfate occurs in nature as the mineral, zinkosite. The heptahydrate, ZnSO4•7H2O is the mineral, goslarite. The salt is used as a mordant in calicoprinting, in making rayon, in preserving wood, in animal feeds, in electroplating, and in preparing many zinc compounds.

Production

Zinc sulfate is produced as an intermediate in recovering zinc from mineral zinc blende, ZnS (see Zinc, Recovery). The mineral is roasted at about 1,000°C to form zinc oxide and sulfur dioxide which, on prolonged heating in excess air, converts to zinc sulfate:
2ZnS + 3O2 → 2ZnO + 2SO2
2ZnO + 2SO2 + O2 → 2ZnSO4
In the zinc recovery process, roasted products are leached with sulfuric acid, whereupon zinc oxide is converted to sulfate.
ZnO + H2SO4 → ZnSO4 + H2O
Also, zinc sulfate can be prepared by reacting metallic zinc with dilute sulfuric acid followed by evaporation and crystallization:
Zn + H2SO4 → ZnSO4 + H2

Chemical Properties

White, free-flowing powder. Soluble in water; insoluble in alcohol.

Uses

Zinc sulfate monohydrate is used as a zinc supplement in animal feeds, fertilizers, and agricultural sprays. It is a specific compound fertilizer for increasing rapeseed yield.
Zinc sulfate monohydrate may be used in the following applications:

  • 1. Preparation of rayon, agricultural sprays, and dyes.
  • 2. As a precipitating agent in the preparation of sample solutions for ultra-high-performance liquid chromatography (UHPLC) analysis.
  • 3. Synthesis of ZnO nanocrystals via the sol-gel combustion technique.
  • Purification Methods

    Crystallise it from aqueous EtOH or dilute H2SO4 below 39o when it forms the heptahydrate, and between 39o and 70o it forms the hexahydrate, and above 70o the monohydrate is stable. The anhydrous salt is obtained from the hydrates by heating at 280o or lower temperatures in a current of dry air. It decomposes to ZnO and SO2 at 767o. The solubility of the heptahydrate in H2O is 5.88% at 0o, 61.92% at 30o, 66.61% at 35o and 70.05% at 39o.

    References

    [1] S. LEE. Fabrication and Characterizations of Hot-Melt Extruded Nanocomposites Based on Zinc Sulfate Monohydrate and Soluplus[J]. Applied Sciences-Basel, 2017, 7 1: 902. DOI:10.3390/APP7090902.

    Zinc sulfate monohydrate Preparation Products And Raw materials

    Raw materials

    Preparation Products

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    Zinc sulfate monohydrate Suppliers

    Lianyungang Kexin Chemical Co., Ltd.
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    View Lastest Price from Zinc sulfate monohydrate manufacturers

    Hebei Chuanghai Biotechnology Co., Ltd
    Product
    Zinc sulfate monohydrate 7446-19-7
    Price
    US $10.00/kg
    Min. Order
    1kg
    Purity
    99%
    Supply Ability
    100 mt
    Release date
    2024-11-11
    HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
    Product
    Zinc sulfate monohydrate 7446-19-7
    Price
    US $100.00-75.00/kg
    Min. Order
    1kg
    Purity
    99%
    Supply Ability
    5000
    Release date
    2024-08-21
    Hebei Andu Technology Com.,Ltd
    Product
    Zinc sulfate monohydrate 7446-19-7
    Price
    US $1.50/kg
    Min. Order
    1kg
    Purity
    ≥99%
    Supply Ability
    3000tons/month
    Release date
    2024-07-31

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