ChemicalBook > CAS DataBase List > DIHYDRO CUMINYL ALCOHOL

DIHYDRO CUMINYL ALCOHOL

Product Name: DIHYDRO CUMINYL ALCOHOL
CAS No.: 536-59-4
Chemical Name: DIHYDRO CUMINYL ALCOHOL
Synonyms: PERILLYL ALCOHOL;p-Mentha-1,8-dien-7-ol;PERILLA ALCOHOL;Perillol;1-Cyclohexene-1-methanol, 4-(1-methylethenyl)-;perilla;1-perillalcohol;Perillic alcohol;(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)Methanol;1,8-p-Menthadien-7-ol
CBNumber: CB0695703
Molecular Formula: C10H16O
Formula Weight: 152.23
MOL File: 536-59-4.mol

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DIHYDRO CUMINYL ALCOHOL Property

Melting point:: 271-272 °C
Boiling point:: 119-121 °C11 mm Hg(lit.)
Density: 0.96 g/mL at 25 °C(lit.)
refractive index: n20/D 1.501(lit.)
FEMA: 2664 | P-MENTHA-1,8-DIEN-7-OL
Flash point:: >230 °F
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Very slightly soluble in water, soluble in alcohol and oils
form: Liquid
pka: 14.85±0.10(Predicted)
color: Colorless to light yellow
Odor: at 100.00 %. green cumin spicy aromatic woody cardamom floral waxy violet
Odor Type: green
JECFA Number: 974
LogP: 3.170
CAS DataBase Reference: 536-59-4
EPA Substance Registry System: 1-Cyclohexene-1-methanol, 4-(1-methylethenyl)- (536-59-4)

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Safety

Hazard Codes: Xi
Risk Statements: 37/38-41-36/37/38
Safety Statements: 26-39-36
WGK Germany: 3
RTECS: OS8395000
HS Code: 29061990
Toxicity: LD50 orl-rat: 2100 mg/kg FCTXAV 19,253,81

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: P835188
Product name: (4-(Prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol
Packaging: 500mg
Price: $40
Updated: 2021/12/16

TRC

Product number: P835188
Product name: (4-(Prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol
Packaging: 2.5g
Price: $60
Updated: 2021/12/16

ChemScene

Product number: CS-W019441
Product name: Perillylalcohol
Packaging: 100mg
Price: $50
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FP70326
Product name: (-)-Perillyl alcohol
Packaging: 10g
Price: $65
Updated: 2021/12/16

AK Scientific

Product number: 8575AJ
Product name: Dihydrocuminylalcohol
Packaging: 10g
Price: $80
Updated: 2021/12/16

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DIHYDRO CUMINYL ALCOHOL Chemical Properties,Usage,Production

Description

p-Mentha-1,8-dien-7-ol has a characteristic odor similar to linalool and terpineol. The L-form is obtained starting from (3-pinene or by reducing perillic aldehyde with zinc dust and acetic acid, followed by saponification of the acetate.

Chemical Properties

p-Mentha-1,8-dien-7-ol has a characteristic odor similar to linalool and terpineol.

Chemical Properties

clear colorless to light yellow liquid

Occurrence

The d- and l-forms occur naturally in gingergrass essential oil; the l-form is found in lavandin and bergamot, while the d-form is found in caraway; also reported found in the essential oils of Juniperus sabina L. and East Indian geranium. Also reported found in citrus peel oils, berries, peppermint oil, Scotch peppermint oil, hop oil, cardamom, laurel, lemon balm, lamb’s let tuce, mastic gum oil and bullock’s head (Annona reticulata).

Uses

(4-(Prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol is used in preparation of perilla alcohol leaf alcohol carbonate as perfume.

Uses

antineoplastic, apoptosis inducer; skin irritant, LD50(rat) 2100 mg/kg po

Definition

ChEBI: A limonene monoterpenoid consists of a cyclohexene ring substituted by a hydroxymethyl and a prop-1-en-2-yl group at positions 1 and 4 respectively. It is a constituent of a variety of essential oils including lavender.

Preparation

The l-form is obtained starting from β-pinene or by reducing perillic aldehyde with zinc dust and acetic acid, followed by saponification of the acetate.

Aroma threshold values

Detection: 7 ppm

Safety Profile

Moderately toxic by ingestion. A severe skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

Synthesis

2111-75-3

536-59-4

GENERAL STEPS: Example 13: The hydrogenation reaction for the synthesis of (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol from 4-(prop-1-en-2-yl)cyclohex-1-enecyclohexene carboxaldehyde was carried out in a stainless steel autoclave equipped with a glass inner tube. The autoclave was pre-charged with [Cu(NO3)(PPh3)2] (11.7 mg, 0.018 mmol) and DPPB (7.7 mg, 0.018 mmol). Subsequently, the atmosphere inside the autoclave was replaced with nitrogen. An ethanol solution of sodium hydroxide (0.03 M, 6.0 mL, 0.18 mmol) and 4-(prop-1-en-2-yl)cyclohex-1-enecarboxaldehyde (2.02 mL, 9 mmol) was added to the autoclave. The reaction was stirred at hydrogen pressure of 5 MPa and 50 °C for 16 hours. Upon completion of the reaction, hydrogen was carefully released and the reaction conversion (>99%) was analyzed by gas chromatography (GC). The reaction mixture was concentrated and purified by silica gel column chromatography to give 1.26 g of the target product (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol.

References

[1] Tetrahedron Letters, 1993, vol. 34, # 2, p. 257 - 260
[2] Chemistry - A European Journal, 2017, vol. 23, # 35, p. 8473 - 8481
[3] Synlett, 2009, # 8, p. 1295 - 1298
[4] Patent: US2011/201819, 2011, A1. Location in patent: Page/Page column 10
[5] Patent: EP2377841, 2011, A1. Location in patent: Page/Page column 13-14

DIHYDRO CUMINYL ALCOHOL Preparation Products And Raw materials

Raw materials

Preparation Products

Ambroxide

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View Lastest Price from DIHYDRO CUMINYL ALCOHOL manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: Perillyl alcohol 536-59-4
Price: US $45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-11-29

Henan Aochuang Chemical Co.,Ltd.

Product: DIHYDRO CUMINYL ALCOHOL 536-59-4
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-29

Hebei Chuanghai Biotechnology Co,.LTD

Product: perillyl alcohol 536-59-4
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-23

536-59-4, DIHYDRO CUMINYL ALCOHOLRelated Search:

Murexide Shikonin ELEUTHEROSIDE B (-)-PERILLALDEHYDE Pterostilbene Perillartine (-)-PERILLALDEHYDE Paclitaxel perillen Sageone CASTICIN VIOLAXANTHIN Shikalkin Alkannin Dihydroechinofuran Sesamol (-)-PERILLYL ALCOHOL DIHYDRO CUMINYL ALCOHOL

DIHYDRO CUMINYL ALCOHOL

Perilla alcohol Dihydrocuminyl alcohol

(4-Isopropenyl-1-cyclohexen-1-yl)methanol

1,8-p-Menthadien-7-ol

1-perillalcohol

4-(1-methylethenyl)-1-cyclohexene-1-methano

(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)Methanol

1-HYDROXYMETHYL-4-(1-METHYLVINYL)-CYCLOHEXENE

PERILLYL ALCOHOL

PERILLA ALCOHOL

(S)-(-)-PeriL

PARA-MENTHA-1,8-DIEN-7-OL

1-Cyclohexene-1-methanol, 4-(1-methylethenyl)-

(4-prop-1-en-2-yl-1-cyclohexenyl)methanol

PERILLYL ALCOHOL, (-)-(RG)

4-(1-Methylvinyl)-1-cyclohexene-1-methanol

L(-)-Perillyl alcohol,85%

4-(Prop-1-en-2-yl)-cyclohex-1-enyl)-methanol

4-(1-methylethenyl)-1-Cyclohexene-1-methanol

4-(1-methylethenyl)-cyclohex-1-ene-1-methano

4-isopropenylcyclohex-1-en-1-ylmethanol

(S)-(-)-PERILLYL ALCOHOL 90+%

L-(-)-Perilly Alcohol

4-Isopropenyl-cyclohex-1-ene-1-methanol

Cyclohex-1-ene-1-methanol, 4-(1-methylethenyl)-

perill alcohol

perilla

Perillic alcohol

Perillol

p-Mentha-1,8-dien-7-ol

UNII:319R5C7293

536-59-4 DIHYDRO CUMINYL ALCOHOL

Perillyl alcohol, 10 mM in DMSO

Perilla alcohol 90% (liquid)

(±)-Perillyl Alcohol

536-59-4

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