3-Iodobenzaldehyde
- Product Name
- 3-Iodobenzaldehyde
- CAS No.
- 696-41-3
- Chemical Name
- 3-Iodobenzaldehyde
- Synonyms
- 3-IODOBENZALDEHYDE;m-Iodobenzaldehyde;3-Iodobenzaldehyde>Benzaldehyde, 3-iodo-;3-Iodobenzaldehyde 99%;1-Formyl-3-iodobenzene;3-IODOBENZALDEHYDE, 99+%
- CBNumber
- CB0696735
- Molecular Formula
- C7H5IO
- Formula Weight
- 232.02
- MOL File
- 696-41-3.mol
3-Iodobenzaldehyde Property
- Melting point:
- 57-60 °C (lit.)
- Boiling point:
- 124-125°C 13mm
- Density
- 1.8576 (estimate)
- Flash point:
- 124-125°C/13mm
- storage temp.
- 2-8°C
- form
- Crystalline Powder, Crystals or Needles
- color
- White to pale yellow
- Water Solubility
- Slightly soluble in water.
- Sensitive
- Air & Light Sensitive
- BRN
- 1854653
- InChIKey
- RZODAQZAFOBFLS-UHFFFAOYSA-N
- CAS DataBase Reference
- 696-41-3(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 550760
- Product name
- 3-Iodobenzaldehyde
- Purity
- 97%
- Packaging
- 1g
- Price
- $50.8
- Updated
- 2023/06/20
- Product number
- I0611
- Product name
- 3-Iodobenzaldehyde
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $82
- Updated
- 2025/07/31
- Product number
- I0611
- Product name
- 3-Iodobenzaldehyde
- Purity
- >96.0%(GC)
- Packaging
- 25g
- Price
- $277
- Updated
- 2025/07/31
- Product number
- I737060
- Product name
- 3-Iodobenzaldehyde
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 2615-H-X3
- Product name
- 3-Iodobenzaldehyde
- Packaging
- 1g
- Price
- $16
- Updated
- 2021/12/16
3-Iodobenzaldehyde Chemical Properties,Usage,Production
Chemical Properties
Pale yellow crystalline powder
Uses
3-Iodobenzaldehyde is used as an organic reagent.
General Description
3-Iodobenzaldehyde can be prepared by the iodination of benzaldehyde using 1,3-diiodo-5,5-dimethylhydantoin in sulfuric acid.
Synthesis
57455-06-8
696-41-3
3-Iodobenzaldehyde (12) was synthesized as follows: pyridinium chlorochromate (2.45 g, 11.4 mmol) and dry diatomaceous earth (about 2.00 g) were suspended in anhydrous dichloromethane (20 ml) at room temperature and stirred for 15 minutes. Subsequently, a solution of 3-iodobenzyl alcohol (11) (1.02 g, 4.35 mmol) in anhydrous dichloromethane (5 ml) was added to this suspension. The reaction mixture was protected from light and stirring was continued for 2 hours at room temperature. After completion of the reaction, the reaction solution was diluted with ether and filtered through diatomaceous earth. The resulting turbid brown filtrate was concentrated to a reddish brown gelatinous paste, which was redissolved in dichloromethane and purified by short silica gel column chromatography using dichloromethane as eluent. A clarified colorless solution was finally obtained, and 3-iodobenzaldehyde (12) was concentrated to give 3-iodobenzaldehyde (12) as a white solid (0.953 g, 95% yield).1H NMR (400 MHz, CDCl3) data were as follows: δ 7.29 (t, J = 7.8 Hz, 1H, H5); 7.85 (br d, J = 7.8 Hz, 1H, H6); 7.96 (br d, J =7.8 Hz, 1H, H4); 8.21 (br s, 1H, H2); 9.93 (s, 1H, CHO).
References
[1] Advanced Synthesis and Catalysis, 2004, vol. 346, # 7, p. 767 - 776
[2] Patent: WO2005/82894, 2005, A1. Location in patent: Page/Page column 41-42
[3] Bulletin of the Chemical Society of Ethiopia, 2013, vol. 27, # 1, p. 131 - 136
[4] Bioorganic and Medicinal Chemistry Letters, 1999, vol. 9, # 20, p. 3047 - 3052
[5] Tetrahedron Asymmetry, 2001, vol. 12, # 4, p. 585 - 596
3-Iodobenzaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
3-Iodobenzaldehyde Suppliers
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View Lastest Price from 3-Iodobenzaldehyde manufacturers
- Product
- 3-Iodobenzaldehyde 696-41-3
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-07-18
- Product
- 3-Iodobenzaldehyde 696-41-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-19
- Product
- 3-Iodobenzaldehyde 696-41-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 10mg
- Purity
- 99%HPLC
- Supply Ability
- 2000tons
- Release date
- 2020-01-15