ChemicalBook > CAS DataBase List > METHYL ISOCYANOACETATE

METHYL ISOCYANOACETATE

Product Name
METHYL ISOCYANOACETATE
CAS No.
39687-95-1
Chemical Name
METHYL ISOCYANOACETATE
Synonyms
Methyl 2-isocyanoacetate;ISOCYANOACETIC ACID METHYL ESTER;ROXA-015;METHYL ISOCYANOACETATE;Methyl isocyanoformate;Methyl Isocyanoacetate >Methyl Isocyanoacetate,>97%;2-Oxo-2-methoxyethyl isocyanide;(2-Oxo-2-methoxyethyl) isocyanide;39687-95-1 METHYL ISOCYANOACETATE
CBNumber
CB0700977
Molecular Formula
C4H5NO2
Formula Weight
99.09
MOL File
39687-95-1.mol
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METHYL ISOCYANOACETATE Property

Boiling point:
75-76 °C10 mm Hg(lit.)
Density 
1.09 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.417(lit.)
Flash point:
193 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear yellow to brown
Water Solubility 
Miscible with organic solvents. Slightly miscible with water.
BRN 
3537963
CAS DataBase Reference
39687-95-1(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
20/21/22-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2922 8/PG 2
WGK Germany 
3
F 
8-9-32-13-19
HazardClass 
8
PackingGroup 
II
HS Code 
29291090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
238880
Product name
Methyl isocyanoacetate
Purity
technical grade, 95%
Packaging
1g
Price
$63.7
Updated
2024/03/01
Sigma-Aldrich
Product number
238880
Product name
Methyl isocyanoacetate
Purity
technical grade, 95%
Packaging
5g
Price
$177
Updated
2024/03/01
TCI Chemical
Product number
M2549
Product name
Methyl Isocyanoacetate
Purity
>97.0%(GC)
Packaging
1g
Price
$35
Updated
2024/03/01
TCI Chemical
Product number
M2549
Product name
Methyl Isocyanoacetate
Purity
>97.0%(GC)
Packaging
5g
Price
$119
Updated
2024/03/01
Alfa Aesar
Product number
H31069
Product name
Methyl isocyanoacetate, 95%
Packaging
1g
Price
$38.1
Updated
2024/03/01
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METHYL ISOCYANOACETATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW TO BROWN LIQUID

Uses

Methyl isocyanoacetate is used in the copper-catalyzed, diastereoselective synthesis of oxazolines. It is involved in the direct aldol reaction with carbonyl compounds to prepare corresponding oxazoline by using catechol-copper network catalyst. Further, it is also involved in four-component Ugi condensation reaction. It undergoes asymmetric aldol reaction with fluorinated benzaldehyde using gold(I) as a catalyst.

Uses

Methyl isocyanoacetate has been used in the copper-catalyzed, diastereoselective synthesis of oxazolines.

General Description

Methyl isocyanoacetate undergoes direct aldol reaction with carbonyl compounds in the presence of solid-phase catechol-copper network catalyst to yield corresponding oxazolines. It also participates in four-component Ugi condensation reaction.

METHYL ISOCYANOACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

5-Phenyl-1,3-oxazole-4-carboxylic acid
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View Lastest Price from METHYL ISOCYANOACETATE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
METHYL ISOCYANOACETATE 39687-95-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

39687-95-1, METHYL ISOCYANOACETATERelated Search:

ISONICOTINOYL CHLORIDE HYDROCHLORIDE 2-Isocyanatoethyl Acrylate ISOPROPYLHYDRAZINE HYDROCHLORIDE Isopropylsulfonamide 2,3,5,6-tetrafluoro-4-methoxymethylbenzyl-1R, trans-(Z)-3-(3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropane carboxylate HYDROGEN IONOPHORE IV alpha-Cypermethrin Isobutaneboronic acid Methyl isobutyrate Ethyl isobutyrylacetate Isopropenylboronic acid pinacol ester ETHYL 4-METHYLVALERATE URANIUM Potassium cyanate Ethyl isocyanoacetate 2-BROMOPHENYL ISOCYANATE Benzyl isocyanate 1,3,5-Tri-2-propenyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione

  • Methyl isocyanoacetate, technical grade
  • Methyl isocyanoacetate, 95%, tech.
  • (2-Oxo-2-methoxyethyl) isocyanide
  • 2-Isocyanoacetic acid methyl ester
  • 2-Oxo-2-methoxyethyl isocyanide
  • Methyl 2-isocyanoacetate
  • Methyl isocyanoacetate, tech., 95% 5GR
  • Acetic acid, 2-isocyano-, Methyl ester
  • ISOCYANOACETIC ACID METHYL ESTER
  • METHYL ISOCYANOACETATE
  • METHYL ISOCYANOACETATE, TECH., 95%
  • Methyl isocyanoformate
  • ROXA-015
  • Methyl isocyanoacetate, 95%, for synthesis
  • Methyl Isocyanoacetate &gt
  • Methyl Isocyanoacetate,>97%
  • METHYL ISOCYANOACETATE ISO 9001：2015 REACH
  • 39687-95-1 METHYL ISOCYANOACETATE
  • 39687-95-1
  • CNCH2COOCH3
  • ISOCYANATE
  • Building Blocks
  • Organic Building Blocks
  • Isocyanides
  • Nitrogen Compounds
  • straight chain compounds
  • Naphthyridine,Quinoline
  • Isocyanides
  • Nitrogen Compounds
  • Organic Building Blocks
  • Building Blocks
  • Chemical Synthesis
  • Nitrogen Compounds
  • Organic Building Blocks
  • pharmacetical