ChemicalBook > CAS DataBase List > (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER

(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER

Product Name
(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER
CAS No.
37031-30-4
Chemical Name
(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER
Synonyms
Dimethyl-D-tartrate Acetonide;DIMETHYL 2,3-O-ISOPROPYLIDENE-D-TARTRATE;(+)-DIMETHYL 2,3-O-ISOPROPYLIDENE TARTRATE;DIMETHYL (+)-2,3-O-ISOPROPYLIDENE-D-TARTRATE;(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate;Dimethyl(+)-2,3-O-Isopropylidene-D-tartrate>(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate,97%;(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate 98%;(2S,3S)-(+)-DIMETHYL-2,3-O-ISOPROPYLIDENE TARTRATE;(2S,3S)-(+)-DIMETHYL 2,3-O-ISOPROPYLIDENE- D-TARTRATE
CBNumber
CB0715324
Molecular Formula
C9H14O6
Formula Weight
218.2
MOL File
37031-30-4.mol
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(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Property

Boiling point:
80-82 °C0.1 mm Hg(lit.)
alpha 
[α](c=1, CHCl3) +41.0～+45.0°
Density 
1.19 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.439(lit.)
Flash point:
275 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform, Methanol
form 
Liquid
color 
Clear colorless to slightly yellow
optical activity
[α]20/D +54°, neat
BRN 
3548490
InChI
InChI=1S/C9H14O6/c1-9(2)14-5(7(10)12-3)6(15-9)8(11)13-4/h5-6H,1-4H3/t5-,6-/m0/s1
InChIKey
MCNKHXZIPATURB-YUMQZZPRSA-N
SMILES
O1[C@H](C(OC)=O)[C@@H](C(OC)=O)OC1(C)C
CAS DataBase Reference
37031-30-4(CAS DataBase Reference)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
F 
21
HS Code 
29329900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
384313
Product name
(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate
Purity
98%
Packaging
5g
Price
$63.6
Updated
2025/07/31
TCI Chemical
Product number
I0474
Product name
Dimethyl (+)-2,3-O-Isopropylidene-D-tartrate
Purity
>95.0%(GC)
Packaging
5g
Price
$98
Updated
2025/07/31
TRC
Product number
I868910
Product name
2,3-O-Isopropylidene-D-tartaricAcid,DimethylEster
Packaging
5g
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD60139
Product name
Dimethyl (+)-2,3-O-Isopropylidene-D-tartrate
Packaging
5G
Price
$75
Updated
2021/12/16
AK Scientific
Product number
4718AB
Product name
(4S,5S)-Diethyl2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate
Packaging
1g
Price
$84
Updated
2021/12/16
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(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate can be used as a starting material for the synthesis of:

  • Deuterated 1-deoxy-D-xylose.
  • C-terminal peptide -oxo-aldehydes using Fmoc solid-phase peptide synthesis methodology (SPPS).
  • Bis-Weinreb amide, a key intermediate for the preparation of myo-inositol analog via ring-closing metathesis.

General Description

(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate is a chiral reagent used in organic synthesis. It is prepared by the reaction-rectification process from D -tartrate, and 2,2-dimethoxypropane.{138]

(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER Suppliers

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View Lastest Price from (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER 37031-30-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
(4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER 37031-30-4
Price
US $0.10/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
1kg; 100kg; 1000kg
Release date
2019-12-24

37031-30-4, (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTERRelated Search:

L(+)-Gulonic acid gamma-lactone (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER (S)-5-Hydroxymethyldihydrofuran-2-one D-SACCHARIC ACID 1,4-LACTONE (1S)-(-)-Camphanic acid (S)-(+)-5-OXOTETRAHYDROFURAN-2-CARBOXYLIC ACID D-Glucurono-6,3-lactone acetonide TEREBIC ACID Isoalantolactone (+)-CAMPHANIC ACID CHLORIDE (4R,5R)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER D-MANNONO-1,4-LACTONE gibberellin A4 methyl ester ALPHA,BETA-GLUCOOCTANOIC GAMMA-LACTONE (1R)-(+)-CAMPHANIC ACID (R)-(-)-DIHYDRO-5-(HYDROXYMETHYL)-2(3H)-FURANONE 1,6-DIOXASPIRO[4.4]NONANE-2,7-DIONE GIBBERELLIN A9 METHYL ESTER

  • 4S,5S-diethyl 2,2-diMethyl-1,3-dioxolane-4,5-dicarboxylate
  • Dimethyl (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylate (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic Acid Dimethyl Ester (+)-2,3-O-Isopropylidene-D-tartaric Acid Dimethyl Ester
  • 2,2-Dimethyl-(4S-trans)-1,3-Dioxolane-4,5-dicarboxylic acid dimethyl ester
  • Dimethyl (4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate, (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic acid dimethyl ester
  • (+)-Dimethyl 2,3-O-isopropylidene-D-tartrate,97%
  • (+)-DiMethyl 2,3-O-isopropylidene-D-tartarate , GC 97%
  • (+)-Dimethyl 2,3-O-isopropylidene-D-tartrate 98%
  • (4S,5S)- 2,2-dimethyl-1,3-Dioxolane-4,5-dicarboxylic acid 4,5-dimethyl ester
  • (+)-dimethyl-2,3-O-isopropylidene-D-tartrate, dimethyl (4S,5S)-(-)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate, (4S,5S)-dimethyl-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate, dimethyl (4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate, dimethyl (2S,3S)-2,3-(propane-2,2-dioxy)succinate, dimethyl (2S,3S)-2,3-O-isopropylidene-D-tartrate, (+)-dimethyl 2,3-O-isopropylidene-D-tartrate
  • (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLIC ACID DIMETHYL ESTER
  • (+)-DIMETHYL 2,3-O-ISOPROPYLIDENE TARTRATE
  • DIMETHYL (+)-2,3-O-ISOPROPYLIDENE-D-TARTRATE
  • DIMETHYL 2,3-O-ISOPROPYLIDENE-D-TARTRATE
  • DIMETHYL (4S,5S)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DICARBOXYLATE
  • Dimethyl-D-tartrate Acetonide
  • 1,3-Dioxolane-4,5-dicarboxylic acid, 2,2-dimethyl-, dimethyl ester, (4S,5S)-
  • (2S,3S)-(+)-DIMETHYL-2,3-O-ISOPROPYLIDENE TARTRATE 97%
  • (2S,3S)-(+)-DIMETHYL 2,3-O-ISOPROPYLIDENE- D-TARTRATE
  • (2S,3S)-(+)-DIMETHYL-2,3-O-ISOPROPYLIDENE TARTRATE
  • (+)-2,3-O-ISOPROPYLIDENE-D-TARTARIC ACID DIMETHYL ESTER
  • (4S,5S)-Dimethyl 2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate
  • Dimethyl(+)-2,3-O-Isopropylidene-D-tartrate&gt
  • 1,3-Dioxolane-4,5-dicarboxylic acid, 2,2-dimethyl-, 4,5-dimethyl ester, (4S,5S)-
  • (+)-Dimethyl 2,3-O-isopropylidene-D-tartrate
  • (+)-dimethyl-2,3-O-isopropylidene-D-tartrate, dimethyl (4S,5S)-(-)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate, (4S,5S)-dimethyl-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate, dimethyl (4S,5S)-2,2-dim
  • (+)-Dimethyl 2,3-<i>O</i>-isopropylidene-<sc>D</sc>-tartrate
  • (4S,5S)-Dimethyl 2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate - [D90030]
  • 4,5-dimethyl (4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate
  • 37031-30-4
  • Organic Building Blocks
  • Esters
  • Asymmetric Synthesis
  • Dioxanes & Dioxolanes
  • Chiral Building Blocks
  • Esters (Chiral)
  • Dioxolanes
  • chiral
  • Amino Acids 13C, 2H, 15N
  • Chiral Building Blocks
  • Dioxanes & Dioxolanes
  • Dioxolanes
  • Esters (Chiral)
  • Synthetic Organic Chemistry
  • Amino Acids & Derivatives