ChemicalBook > CAS DataBase List > 2-AMINO-3-METHYLBENZYL ALCOHOL

2-AMINO-3-METHYLBENZYL ALCOHOL

Product Name
2-AMINO-3-METHYLBENZYL ALCOHOL
CAS No.
57772-50-6
Chemical Name
2-AMINO-3-METHYLBENZYL ALCOHOL
Synonyms
2-AMINO-3-METHYLBENZYL ALCOHOL;2-Amino-3-methylbenzenemethanol;Benzenemethanol, 2-amino-3-methyl-;2-AMino-3-Methylbenzyl alcohol 97%;(2-AMINO-3-METHYL-PHENYL)-METHANOL;2-AMINO-3-METHYLBENZYL ALCOHOL USP/EP/BP
CBNumber
CB0740737
Molecular Formula
C8H11NO
Formula Weight
137.18
MOL File
57772-50-6.mol
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2-AMINO-3-METHYLBENZYL ALCOHOL Property

Melting point:
67-69 °C (lit.)
Boiling point:
135-145℃ (12 Torr)
Density 
1.126±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly)
form 
Solid
pka
14.48±0.10(Predicted)
color 
White to Off-White
InChI
InChI=1S/C8H11NO/c1-6-3-2-4-7(5-10)8(6)9/h2-4,10H,5,9H2,1H3
InChIKey
FWTCWZZOKOBJIR-UHFFFAOYSA-N
SMILES
C1(CO)=CC=CC(C)=C1N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
334197
Product name
2-Amino-3-methylbenzyl alcohol
Purity
97%
Packaging
5g
Price
$87.5
Updated
2025/07/31
Sigma-Aldrich
Product number
334197
Product name
2-Amino-3-methylbenzyl alcohol
Purity
97%
Packaging
25g
Price
$369.6
Updated
2025/07/31
TRC
Product number
A638103
Product name
(2-Amino-3-methylphenyl)methanol
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
8531AB
Product name
(2-Amino-3-methylphenyl)methanol
Packaging
10g
Price
$303
Updated
2021/12/16
Apolloscientific
Product number
OR51830
Product name
2-Amino-3-methylbenzyl alcohol
Purity
97%
Packaging
5g
Price
$153
Updated
2021/12/16
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2-AMINO-3-METHYLBENZYL ALCOHOL Chemical Properties,Usage,Production

Uses

2-Amino-3-methylbenzyl alcohol may be used in chemical synthesis.

Synthesis

4389-45-1

57772-50-6

GENERAL PROCEDURE: A solution was prepared by dissolving 2-amino-3-methylbenzoic acid (8.5 mmol) in THF (24 mL) at room temperature. In a separate vessel, a suspension of lithium aluminum hydride (20.4 mmol) in THF (10 mL) was prepared. The benzoic acid solution was added dropwise to the lithium aluminum hydride suspension over a period of 20 minutes. After the dropwise addition, the reaction mixture continued to be stirred at room temperature for 3.5 hours. Upon completion of the reaction, the reaction mixture was cooled to 0 °C and quenched by slow addition of H2O (10 mL). Subsequently, the suspension was filtered through a diatomaceous earth plug and washed with EtOAc (100 mL). The organic phase was washed with brine (30 mL), dried over anhydrous MgSO4 and finally concentrated under vacuum to give 2-amino-3-methylbenzyl alcohol.

References

[1] Chemical Communications, 2017, vol. 53, # 1, p. 216 - 219
[2] Organic Letters, 2017, vol. 19, # 12, p. 3219 - 3222
[3] Tetrahedron Letters, 2017, vol. 58, # 40, p. 3795 - 3799
[4] Journal of the American Chemical Society, 2014, vol. 136, # 24, p. 8729 - 8737
[5] Journal of the American Chemical Society, 2017, vol. 139, # 2, p. 655 - 662

2-AMINO-3-METHYLBENZYL ALCOHOL Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-3-METHYLBENZYL ALCOHOL Suppliers

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View Lastest Price from 2-AMINO-3-METHYLBENZYL ALCOHOL manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2-AMINO-3-METHYLBENZYL ALCOHOL 57772-50-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2025-03-11
Career Henan Chemical Co
Product
2-AMINO-3-METHYLBENZYL ALCOHOL 57772-50-6
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1MT/month
Release date
2019-07-31