IRON (III) BROMIDE

ChemicalBook > CAS DataBase List > IRON (III) BROMIDE

Preparation

Product Name: IRON (III) BROMIDE
CAS No.: 10031-26-2
Chemical Name: IRON (III) BROMIDE
Synonyms: IRON BROMIDE;FERRIC BROMIDE;iron tribromide;Tribromoiron(III);IRON (III) BROMIDE;Iron bromide(FeBr3);Ferric(III) bromide;Iron(III) tribromide;Iron(III) bromide 98%;Iron(iii) bromide, 90+%
CBNumber: CB0746623
Molecular Formula: Br3Fe
Formula Weight: 295.56
MOL File: 10031-26-2.mol

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IRON (III) BROMIDE Property

Melting point:: 200 °C
Density: 4.500
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in ethanol, ethyl ether
form: Powder
color: White to yellow-beige
Water Solubility: Soluble in water, ether and alcohol.
Sensitive: Hygroscopic
Merck: 14,4018
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability:: hygroscopic
InChIKey: FEONEKOZSGPOFN-UHFFFAOYSA-K
CAS DataBase Reference: 10031-26-2(CAS DataBase Reference)
EPA Substance Registry System: Iron bromide (FeBr3) (10031-26-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
RIDADR: UN3260
WGK Germany: 3
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 28275900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 217883
Product name: Iron(III) bromide
Purity: 98%
Packaging: 10g
Price: $101
Updated: 2024/03/01

Sigma-Aldrich

Product number: 217883
Product name: Iron(III) bromide
Purity: 98%
Packaging: 50g
Price: $382
Updated: 2024/03/01

Alfa Aesar

Product number: 031125
Product name: Iron(III) bromide, anhydrous, 98+%
Packaging: 5g
Price: $44
Updated: 2024/03/01

Alfa Aesar

Product number: 031125
Product name: Iron(III) bromide, anhydrous, 98+%
Packaging: 25g
Price: $152
Updated: 2023/06/20

Strem Chemicals

Product number: 93-2665
Product name: Iron(III) bromide, anhydrous, 99%
Packaging: 10g
Price: $69
Updated: 2024/03/01

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IRON (III) BROMIDE Chemical Properties,Usage,Production

Preparation

Iron(III) bromide is prepared by the action of bromine with iron filings:
2Fe + 3Br2 → 2FeBr3
The compound should be stored in dark bottles protected from air or light. It also may be obtained by double decompostion reactions between a ferric salt and a bromide (alkali metal bromide) in aqueous solution followed by evaporation and crystallization:
Fe2(SO4)3 + LiBr → 2FeBr3 + 3Li2SO4
It also may be prepared in high yield by photochemical reaction of dibromoirontetracarbonyl with bromine in hexane (Yoon, K.B. and J.K. Kochi.
1990. Inorg. Chem. 29, pp. 869):
(CO)4FeBr2 + ½ Br2 → FeBr3 + 4CO

Chemical Properties

Brown-red crystalline powder

Physical properties

Dark red hexagonal crystal; hygroscopic; partially decomposes to FeBr₂,losing some bromine on exposure to air or light; density 4.50 g/cm3; decomposes on heating; soluble in water, ethanol, and ether.

Uses

Iron(III) bromide is used as a Lewis acid catalyst in the halogenation of aromatic compounds. It is also used in the preparation of 2,5-dibromo-4-aryl-1,3-pentadiene by reacting with homoallenic bromohydrin.

Uses

Catalyst for organic reactions, particularly in bromination of aromatic Compounds.

General Description

This product has been enhanced for catalytic efficiency.

Purification Methods

Sublime it in a sealed tube with Br2 at 120o-200o. [Lux in Handbook of Preparative Inorganic Chemistry (Ed.Brauer) Academic Press Vol II p 1494 1965.]

IRON (III) BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from IRON (III) BROMIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: IRON (III) BROMIDE 10031-26-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: IRON (III) BROMIDE 10031-26-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-08

10031-26-2, IRON (III) BROMIDERelated Search:

Potassium bromide Sodium bicarbonate Phosphoric acid Aluminum oxide Calcium chloride Zinc chloride TERBIUM BROMIDE TIN (II) BROMIDE Magnesium bromide Zinc bromide Cupric bromide Sodium bromide NICKEL BROMATE Magnesium bromide hexahydrate COBALT(II) BROMIDE HYDRATE Managanese bromide CADMIUM BROMIDE TETRAHYDRATE Cesium bromide

IRON BROMIDE

IRON (III) BROMIDE

FERRIC BROMIDE

iron tribromide

IRON(III) BROMIDE ANHYDROUS

Iron(III)bromide,anhydrous,99%

Iron(iii) bromide, 90+%

Iron bromide(FeBr3)

Iron(III) tribromide

Tribromoiron(III)

Iron(III) bromide, anhydrous, 98+%

Iron(III) bromide 98%

Iron(III) Bromide, Anhydrous 99.9%

Iron(III) broMide, 90+% 25GR

Ferric(III) bromide

Iron(III) bromide, 97%, reagent grade

IRON (III) BROMIDE ISO 9001：2015 REACH

Neotame Impurity 3（Iron(III) Bromide）

10031-26-2

FeBrBrBr

FeBr3

Synthetic Reagents

Lewis Acids

metal halide

bc0001