NICKEL BROMATE
Description References- Product Name
- NICKEL BROMATE
- CAS No.
- 13462-88-9
- Chemical Name
- NICKEL BROMATE
- Synonyms
- NiBr2;Nickel dibromide;Nickel(II)-bromid;Nickel-bromid;NICKEL BROMATE;Nickel(Ⅱ) bromide;Dibromonickel(II);Nickeleus bromide;nickelbromide(nibr2);Nickel(II) dibromide
- CBNumber
- CB2669337
- Molecular Formula
- Br2Ni
- Formula Weight
- 218.5
- MOL File
- 13462-88-9.mol
NICKEL BROMATE Property
- Melting point:
- 963 °C (lit.)
- Density
- 5.098 g/mL at 25 °C (lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- H2O: slightly soluble(lit.)
- form
- powder
- color
- Brown
- Specific Gravity
- 5.098
- Water Solubility
- Soluble in water, alcohol and ether.
- Sensitive
- Hygroscopic
- Merck
- 14,6502
- Exposure limits
- ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 - Stability:
- Stable. Incompatible with strong oxidizing agents.
- InChIKey
- IPLJNQFXJUCRNH-UHFFFAOYSA-L
- CAS DataBase Reference
- 13462-88-9(CAS DataBase Reference)
- EPA Substance Registry System
- Nickel(II) bromide (13462-88-9)
Safety
- Hazard Codes
- T,N,Xi
- Risk Statements
- 45-22-43-50/53-68-48/23-42/43-61-49
- Safety Statements
- 53-36/37-45-60-61
- RIDADR
- UN 3077 9/PG 3
- WGK Germany
- 3
- TSCA
- Yes
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 28275900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H317May cause an allergic skin reaction
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H341Suspected of causing genetic defects
H350May cause cancer
H360May damage fertility or the unborn child
H372Causes damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 217891
- Product name
- Nickel(II) bromide
- Purity
- 98%
- Packaging
- 10g
- Price
- $37.9
- Updated
- 2024/03/01
- Product number
- 217891
- Product name
- Nickel(II) bromide
- Purity
- 98%
- Packaging
- 50g
- Price
- $76.8
- Updated
- 2024/03/01
- Product number
- 053115
- Product name
- Nickel(II) bromide, anhydrous, 99%
- Packaging
- 50g
- Price
- $106
- Updated
- 2024/03/01
- Product number
- 053115
- Product name
- Nickel(II) bromide, anhydrous, 99%
- Packaging
- 250g
- Price
- $446
- Updated
- 2024/03/01
- Product number
- 28-1140
- Product name
- Nickel(II) bromide, anhydrous (99+%-Ni)
- Packaging
- 50g
- Price
- $118
- Updated
- 2024/03/01
NICKEL BROMATE Chemical Properties,Usage,Production
Description
Nickel bromide (chemical formula: NiBr2) is the nickel salt of hydrobromic acid. It is a weak reducing agent made by the reaction of nickel, nickel oxide, nickel carbonate or nickel hydroxide with hydrobromic acid, or the reaction between nickel and bromine. Nickel bromide has many kinds of applications. It is mostly an electron acceptor, being capable of catalyze organic structure such as carbonamides, and convert aryl bromides into aryl phosphines. It can also be used as a catalyst in cross-coupling reactions. It is also applied for bonding to other ligands. For example, graphene supported NrBr2 is used in a condensation reaction consisting of aromatic aldehyde, acetoacetate and urea for manufacturing 3, 4- dihydropyrimidiones.
References
https://en.wikipedia.org/wiki/Nickel(II)_bromide
Chemical Properties
Brownish powder
Uses
Nickel(II) Bromide, is used as a source of bromide ion. It is also an important raw material used in various chemical synthesis and also as a catalyst in cross-coupling reactions.
General Description
Yellowish-green odorless solid. Sinks in and mixes with water.
Air & Water Reactions
Deliquescent. Soluble in water.
Reactivity Profile
NICKEL BROMATE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMATE produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMATE emits toxic bromide fumes. [M. K.]
Health Hazard
Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.
Fire Hazard
Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.
Purification Methods
Crystallise it from dilute HBr (0.5mL/g) by partial evaporation in a desiccator. The anhydrous salt is yellow, but the trihydrate is green.
NICKEL BROMATE Preparation Products And Raw materials
Raw materials
Preparation Products
NICKEL BROMATE Suppliers
- Tel
- 16621224781
- wanghao@titansci.com
- Country
- China
- ProdList
- 2781
- Advantage
- 58
- Tel
- 0375-0375218-0375 19207499233
- 3574468540@qq.com
- Country
- China
- ProdList
- 147
- Advantage
- 58
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 821-50328103-801 18930552037
- Fax
- 86-21-50328109
- 3bsc@sina.com
- Country
- China
- ProdList
- 15848
- Advantage
- 69
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30132
- Advantage
- 84
- Tel
- 0757-86329057 18501085097
- Fax
- 010-89508210
- sales3.gd@hwrkchemical.com
- Country
- China
- ProdList
- 7583
- Advantage
- 55
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44751
- Advantage
- 61
- Tel
- 010-82967028 13552068683
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12426
- Advantage
- 60
- Tel
- 13817811078
- Fax
- 86-021-50426522,50426273
- sales@jingyan-chemical.com
- Country
- China
- ProdList
- 9984
- Advantage
- 60
- Tel
- 400-6009262 16621234537
- Fax
- 021-64823266
- zhangsn@titansci.com
- Country
- China
- ProdList
- 14113
- Advantage
- 59
View Lastest Price from NICKEL BROMATE manufacturers
- Product
- Nickel(II) bromide 13462-88-9
- Price
- US $10.00/KG
- Min. Order
- 100KG
- Purity
- 99%
- Supply Ability
- 100
- Release date
- 2020-12-11
- Product
- NICKEL BROMATE 13462-88-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 25kg
- Release date
- 2019-07-10