Description References
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NICKEL BROMATE

Description References
Product Name
NICKEL BROMATE
CAS No.
13462-88-9
Chemical Name
NICKEL BROMATE
Synonyms
NiBr2;Nickel dibromide;Nickel(II)-bromid;Nickel-bromid;NICKEL BROMATE;Nickel(Ⅱ) bromide;Dibromonickel(II);Nickeleus bromide;nickelbromide(nibr2);Nickel(II) dibromide
CBNumber
CB2669337
Molecular Formula
Br2Ni
Formula Weight
218.5
MOL File
13462-88-9.mol
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NICKEL BROMATE Property

Melting point:
963 °C (lit.)
Density 
5.098 g/mL at 25 °C (lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
H2O: slightly soluble(lit.)
form 
powder
color 
Brown
Specific Gravity
5.098
Water Solubility 
Soluble in water, alcohol and ether.
Sensitive 
Hygroscopic
Merck 
14,6502
Exposure limits
ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
IPLJNQFXJUCRNH-UHFFFAOYSA-L
CAS DataBase Reference
13462-88-9(CAS DataBase Reference)
EPA Substance Registry System
Nickel(II) bromide (13462-88-9)
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Safety

Hazard Codes 
T,N,Xi
Risk Statements 
45-22-43-50/53-68-48/23-42/43-61-49
Safety Statements 
53-36/37-45-60-61
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
28275900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H341Suspected of causing genetic defects

H350May cause cancer

H360May damage fertility or the unborn child

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
217891
Product name
Nickel(II) bromide
Purity
98%
Packaging
10g
Price
$37.9
Updated
2024/03/01
Sigma-Aldrich
Product number
217891
Product name
Nickel(II) bromide
Purity
98%
Packaging
50g
Price
$76.8
Updated
2024/03/01
Alfa Aesar
Product number
053115
Product name
Nickel(II) bromide, anhydrous, 99%
Packaging
50g
Price
$106
Updated
2024/03/01
Alfa Aesar
Product number
053115
Product name
Nickel(II) bromide, anhydrous, 99%
Packaging
250g
Price
$446
Updated
2024/03/01
Strem Chemicals
Product number
28-1140
Product name
Nickel(II) bromide, anhydrous (99+%-Ni)
Packaging
50g
Price
$118
Updated
2024/03/01
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NICKEL BROMATE Chemical Properties,Usage,Production

Description

Nickel bromide (chemical formula: NiBr2) is the nickel salt of hydrobromic acid. It is a weak reducing agent made by the reaction of nickel, nickel oxide, nickel carbonate or nickel hydroxide with hydrobromic acid, or the reaction between nickel and bromine. Nickel bromide has many kinds of applications. It is mostly an electron acceptor, being capable of catalyze organic structure such as carbonamides, and convert aryl bromides into aryl phosphines. It can also be used as a catalyst in cross-coupling reactions. It is also applied for bonding to other ligands. For example, graphene supported NrBr2 is used in a condensation reaction consisting of aromatic aldehyde, acetoacetate and urea for manufacturing 3, 4- dihydropyrimidiones.

References

https://en.wikipedia.org/wiki/Nickel(II)_bromide

Chemical Properties

Brownish powder

Uses

Nickel(II) Bromide, is used as a source of bromide ion. It is also an important raw material used in various chemical synthesis and also as a catalyst in cross-coupling reactions.

General Description

Yellowish-green odorless solid. Sinks in and mixes with water.

Air & Water Reactions

Deliquescent. Soluble in water.

Reactivity Profile

NICKEL BROMATE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMATE produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMATE emits toxic bromide fumes. [M. K.]

Health Hazard

Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.

Fire Hazard

Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.

Purification Methods

Crystallise it from dilute HBr (0.5mL/g) by partial evaporation in a desiccator. The anhydrous salt is yellow, but the trihydrate is green.

NICKEL BROMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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NICKEL BROMATE Suppliers

Shanghai Titan Enterprise Development Co., Ltd
Tel
16621224781
Email
syy@titansci.com
Country
China
ProdList
2776
Advantage
58
Hunan Yongshuo New Material Technology Co., Ltd
Tel
0375-0375218-0375 19207499233
Email
3574468540@qq.com
Country
China
ProdList
147
Advantage
58
Suzhou Nordica Biopharma Co.,LTD
Tel
15150674956
Email
dannilee@nordicabio.com
Country
China
ProdList
88
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
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View Lastest Price from NICKEL BROMATE manufacturers

Suzhou Nordica Biopharma CO.,LTD
Product
Nickel(II) bromide 13462-88-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
5 tons
Release date
2024-11-15
Hebei Mojin Biotechnology Co.,Ltd
Product
NICKEL BROMATE 13462-88-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-07-23
Hebei Henghe Import and Export Trading Co. LTD
Product
Nickel(II) bromide 13462-88-9
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100
Release date
2020-12-11

13462-88-9, NICKEL BROMATERelated Search:


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