2,4,6-Triisopropylbenzene-sulfonyl azide

ChemicalBook > CAS DataBase List > 2,4,6-Triisopropylbenzene-sulfonyl azide

2,4,6-Triisopropylbenzene-sulfonyl azide

Product Name: 2,4,6-Triisopropylbenzene-sulfonyl azide
CAS No.: 36982-84-0
Chemical Name: 2,4,6-Triisopropylbenzene-sulfonyl azide
Synonyms: Trisyl azide;2,4,6-TRIISOPROPYLBENZENESULFONYL AZIDE;TPS-N3;Trisyl azide solution;NSC 646156;2,4,6-Triisopropylbe;2,4,6-Triisopropylbenzenesulfonyl;2,4,6-Triisopropylp henylsulfonyl azide;2,4,6-Triisopropylbenzenesulphonylazide;2,4,6-Triisopropylbenzenesulfonic acid azide
CBNumber: CB0748197
Molecular Formula: C15H23N3O2S
Formula Weight: 309.43
MOL File: 36982-84-0.mol

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2,4,6-Triisopropylbenzene-sulfonyl azide Property

Melting point:: 39-44 °C
refractive index: n20/D1.499
Flash point:: 4℃
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
form: Solid
color: White to Off-White
Water Solubility: Insoluble in water.
BRN: 2391566
InChIKey: AEMWUHCKKDPRSK-UHFFFAOYSA-N
CAS DataBase Reference: 36982-84-0(CAS DataBase Reference)

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Safety

Hazard Codes: T,Xn,F
Risk Statements: 36/37/38-25-67-65-48/20-38-22-11-63-5
Safety Statements: 15-26-36-45-62-36/37-16-37
RIDADR: UN1294 - class 3 - PG 2 - Toluene, solution
WGK Germany: 3
HS Code: 29350090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 778443
Product name: 2,4,6-Triisopropylbenzenesulfonyl azide solution
Purity: 10%±2% in toluene, ≥98% (HPLC)
Packaging: 25g
Price: $275
Updated: 2024/03/01

TCI Chemical

Product number: T3434
Product name: 2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis)
Purity: >98.0%(HPLC)
Packaging: 1g
Price: $34
Updated: 2024/03/01

TCI Chemical

Product number: T3434
Product name: 2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis)
Purity: >98.0%(HPLC)
Packaging: 5g
Price: $140
Updated: 2024/03/01

Alfa Aesar

Product number: L19383
Product name: 2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water
Packaging: 5g
Price: $155
Updated: 2021/12/16

Alfa Aesar

Product number: L19383
Product name: 2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water
Packaging: 1g
Price: $51.7
Updated: 2021/12/16

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2,4,6-Triisopropylbenzene-sulfonyl azide Chemical Properties,Usage,Production

Chemical Properties

White wet solid

Uses

2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives.

Uses

Reagent for:• ;Stereoselective diversity-oriented synthesis of functionalized saccharides1• ;Meyer′s lactamization2Reagent for synthesis of:• ;Antidote to anthrax lethal factor intoxication3• ;Bacterial RNA polymerase inhibitor4• ;Bicyclic extended dipeptide surrogates5• ;Single enantiomers of mycobacterial keomycolic acids6

2,4,6-Triisopropylbenzene-sulfonyl azide Preparation Products And Raw materials

Raw materials

Sodium azide 2,4,6-Triisopropylbenzenesulfonyl chloride

Preparation Products

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View Lastest Price from 2,4,6-Triisopropylbenzene-sulfonyl azide manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: 2,4,6-Triisopropylbenzene-sulfonyl azide 36982-84-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2,4,6-Triisopropylbenzene-sulfonyl azide 36982-84-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2,4,6-Triisopropylbenzene-sulfonyl azide 36982-84-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

36982-84-0, 2,4,6-Triisopropylbenzene-sulfonyl azideRelated Search:

Sulforhodamine B Tosyl cyanide Dimethyl sulfone Sulfosulfuron Tributyltin azide Azidotris(diethylamino)phosphonium bromide Trityl azide Azidotrimethylsilane Diphenylphosphoryl azide Tetrabutylammonium azide Cumene 2,4,6-TRIISOPROPYLBENZENESULFONAMIDE Tosyl azide Sodium azide Azide Fibroblast Growth Factor 2 (basic), Rabbit anti-Human 2,4,6-Triisopropylbenzene-sulfonyl azide

2,4,6-Triisopropylbenzenesulphonylazide

Trisyl azide

2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water

2,4,6-Triisopropylbenzenesulfonyl azide ,90% [stab. With ca 10% water]

2,4,6-Triisopropylbenzenesulfonic acid azide

2,4,6-Triisopropylbe

2,4,6-Triisopropylp henylsulfonyl azide

2,4,6-Tris(1-methylethyl)-benzenesulfonyl azide

2,4,6-TRIISOPROPYLBENZENESULFONYL AZIDE

2,4,6-Triisopropylbenzenesulfonyl azide, stabilized with 10% H2O

2,4,6-triisopropylbenzenesulfonyl azide(TPS-N3)

2,4,6-Triisopropylbenzenesulfonyl azide ,90% [stab.

TPS-N32,4,6-triisopropylbenzenesulfonyl azide

TPS-N3

2,4,6-Triisopropylbenzenesulfonyl azide solution

Trisyl azide solution

Benzenesulfonyl azide, 2,4,6-tris(1-methylethyl)-

2,4,6-Triisopropylbenzenesulfonyl azide contains 15 wt. % water as stabilizer, 97%

2,4,6-Triisopropylbenzenesulfonyl azide, stabilized with &ap:10% water

2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis)

2,4,6-Triisopropylbenzenesulfonyl azide, 90%, stabilized with 10% H2O

2,4,6-Triisopropylbenzenesulfonyl azide, 97%, for synthesis, contains 15wt.% water as stabilizer

2,4,6-Triisopropylbenzenesulfonyl Azide (with ca.10% water)

NSC 646156

N-diazo-2,4,6-tri(propan-2-yl)benzenesulfonamide

2,4,6-Triisopropylbenzenesulfonyl

36982-84-0

63982-84-0

C15H23N3O2S

Azidation/Diazo Transfer

C-X Bond Formation (Non-Halogen)

Various Azides

Azides

Building Blocks

Chemical Synthesis

Nitrogen Compounds

Organic Building Blocks

Synthetic Reagents