2-(TRIMETHYLSILYLOXY)FURAN
- Product Name
- 2-(TRIMETHYLSILYLOXY)FURAN
- CAS No.
- 61550-02-5
- Chemical Name
- 2-(TRIMETHYLSILYLOXY)FURAN
- Synonyms
- TRIMETHYLSILYLOXYFURAN;2-(TRIMETHYLSILOXY)FURAN;2-Furyloxytrimethylsilane;2-(TRIMETHYLSILYLOXY)FURAN;(2-Furyloxy)trimethylsilane;2-(Trimethylsilyloxy)furane;2-(TriMethylsiloxy)furan 97%;Trimethyl(2-furanyloxy)silane;(2-FURANYLOXY)TRIMETHYLSILANE;2-Furyl(trimethylsilyl) ether
- CBNumber
- CB0749048
- Molecular Formula
- C7H12O2Si
- Formula Weight
- 156.25
- MOL File
- 61550-02-5.mol
2-(TRIMETHYLSILYLOXY)FURAN Property
- Boiling point:
- 34-35 °C/9 mmHg (lit.)
- Density
- 0.929 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.436(lit.)
- Flash point:
- 76 °F
- storage temp.
- -20°C
- solubility
- sol most organic solvents, e.g. CH2Cl2, Et2O, benzene, THF, MeCN.
- form
- clear liquid
- color
- Colorless to Light orange to Yellow
- Specific Gravity
- 0.950
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- BRN
- 1423066
- CAS DataBase Reference
- 61550-02-5(CAS DataBase Reference)
Safety
- Hazard Codes
- F,Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 26
- RIDADR
- UN 1993 3/PG 2
- WGK Germany
- 3
- F
- 10-21
- TSCA
- No
- HS Code
- 2932.19.5100
- HazardClass
- 3.2
- PackingGroup
- III
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 308064
- Product name
- 2-(Trimethylsiloxy)furan
- Purity
- 97%
- Packaging
- 5g
- Price
- $176.4
- Updated
- 2024/03/01
- Product number
- 308064
- Product name
- 2-(Trimethylsiloxy)furan
- Purity
- 97%
- Packaging
- 1g
- Price
- $187
- Updated
- 2024/03/01
- Product number
- T1536
- Product name
- 2-(Trimethylsilyloxy)furan
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $280
- Updated
- 2024/03/01
- Product number
- T1536
- Product name
- 2-(Trimethylsilyloxy)furan
- Purity
- >96.0%(GC)
- Packaging
- 25g
- Price
- $876
- Updated
- 2024/03/01
- Product number
- T896600
- Product name
- 2-(Trimethylsilyloxy)furan
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
2-(TRIMETHYLSILYLOXY)FURAN Chemical Properties,Usage,Production
Physical properties
bp 44–46 °C/17 mmHg; d 0.93 gmL?1.
Uses
2-Trimethylsilyloxyfuran provides 5-substituted 2(5H)-furanones by alkylation, aldolization, 3 and conjugate addition; transforms quinones into furo-[3,2-b]benzofurans; useful for the four-carbon elongation of sugars. It is used in Synthetic Applications, Carbon–Heteroatom Bond Formation, Alkylation, Aldol-Type Reactions, Conjugate Addition, and Diels–Alder Reaction.
Uses
2-(Trimethylsilyloxy)furan is a useful reagent for the preparation of natural and synthetic furanones with anticancer activity.
Preparation
Accessible by silylation of 2(5H)-furanone, which is obtained at very low cost by oxidation of furfural.
Purification Methods
Fractionally distil it using a short path column. 1H NMR in CCl4 has : 4.90 (dd, J 1.3Hz, 3H), 6.00 (t, J 3Hz, 4H) and 6.60 (m, 5H). [Yoshii et al. Heterocycles 4 1663 1976.] 4-Trimethylsilyloxy-3-penten-2-one (cis) (acetylacetone enol trimethylsilyl ether) [13257-81-3] M 172.3, b 66-68o/4mm, 61-63o/5mm, d 4 0.917, n D 1.452. Fractionally distil it and store it in glass ampoules which are sealed under N2. It hydrolyses readily in contact with moisture giving, as likely impurities, hexamethyldisiloxane and 2,4-pentanedione. [West J Am Chem Soc 80 3246 1958, Beilstein 4 IV 4003.]
2-(TRIMETHYLSILYLOXY)FURAN Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-(TRIMETHYLSILYLOXY)FURAN manufacturers
- Product
- 2-(TRIMETHYLSILYLOXY)FURAN 61550-02-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- 2-(TRIMETHYLSILYLOXY)FURAN 61550-02-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98% HPLC
- Supply Ability
- 10 tons/month
- Release date
- 2020-01-09