ChemicalBook > CAS DataBase List > 2-(TRIMETHYLSILYLOXY)FURAN

2-(TRIMETHYLSILYLOXY)FURAN

Product Name
2-(TRIMETHYLSILYLOXY)FURAN
CAS No.
61550-02-5
Chemical Name
2-(TRIMETHYLSILYLOXY)FURAN
Synonyms
TRIMETHYLSILYLOXYFURAN;2-(TRIMETHYLSILOXY)FURAN;2-Furyloxytrimethylsilane;2-(TRIMETHYLSILYLOXY)FURAN;(2-Furyloxy)trimethylsilane;2-(Trimethylsilyloxy)furane;2-(TriMethylsiloxy)furan 97%;Trimethyl(2-furanyloxy)silane;(2-FURANYLOXY)TRIMETHYLSILANE;2-Furyl(trimethylsilyl) ether
CBNumber
CB0749048
Molecular Formula
C7H12O2Si
Formula Weight
156.25
MOL File
61550-02-5.mol
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2-(TRIMETHYLSILYLOXY)FURAN Property

Boiling point:
34-35 °C/9 mmHg (lit.)
Density 
0.929 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.436(lit.)
Flash point:
76 °F
storage temp. 
-20°C
solubility 
sol most organic solvents, e.g. CH2Cl2, Et2O, benzene, THF, MeCN.
form 
clear liquid
color 
Colorless to Light orange to Yellow
Specific Gravity
0.950
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
1423066
CAS DataBase Reference
61550-02-5(CAS DataBase Reference)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
26
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
F 
10-21
TSCA 
No
HS Code 
2932.19.5100
HazardClass 
3.2
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
308064
Product name
2-(Trimethylsiloxy)furan
Purity
97%
Packaging
5g
Price
$176.4
Updated
2024/03/01
Sigma-Aldrich
Product number
308064
Product name
2-(Trimethylsiloxy)furan
Purity
97%
Packaging
1g
Price
$187
Updated
2024/03/01
TCI Chemical
Product number
T1536
Product name
2-(Trimethylsilyloxy)furan
Purity
>96.0%(GC)
Packaging
5g
Price
$280
Updated
2024/03/01
TCI Chemical
Product number
T1536
Product name
2-(Trimethylsilyloxy)furan
Purity
>96.0%(GC)
Packaging
25g
Price
$876
Updated
2024/03/01
TRC
Product number
T896600
Product name
2-(Trimethylsilyloxy)furan
Packaging
100mg
Price
$60
Updated
2021/12/16
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2-(TRIMETHYLSILYLOXY)FURAN Chemical Properties,Usage,Production

Physical properties

bp 44–46 °C/17 mmHg; d 0.93 gmL?1.

Uses

2-Trimethylsilyloxyfuran provides 5-substituted 2(5H)-furanones by alkylation, aldolization, 3 and conjugate addition; transforms quinones into furo-[3,2-b]benzofurans; useful for the four-carbon elongation of sugars. It is used in Synthetic Applications, Carbon–Heteroatom Bond Formation, Alkylation, Aldol-Type Reactions, Conjugate Addition, and Diels–Alder Reaction.

Uses

2-(Trimethylsilyloxy)furan is a useful reagent for the preparation of natural and synthetic furanones with anticancer activity.

Preparation

Accessible by silylation of 2(5H)-furanone, which is obtained at very low cost by oxidation of furfural.

Purification Methods

Fractionally distil it using a short path column. 1H NMR in CCl4 has : 4.90 (dd, J 1.3Hz, 3H), 6.00 (t, J 3Hz, 4H) and 6.60 (m, 5H). [Yoshii et al. Heterocycles 4 1663 1976.] 4-Trimethylsilyloxy-3-penten-2-one (cis) (acetylacetone enol trimethylsilyl ether) [13257-81-3] M 172.3, b 66-68o/4mm, 61-63o/5mm, d 4 0.917, n D 1.452. Fractionally distil it and store it in glass ampoules which are sealed under N2. It hydrolyses readily in contact with moisture giving, as likely impurities, hexamethyldisiloxane and 2,4-pentanedione. [West J Am Chem Soc 80 3246 1958, Beilstein 4 IV 4003.]

2-(TRIMETHYLSILYLOXY)FURAN Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(TRIMETHYLSILYLOXY)FURAN Suppliers

China 56 France 1 Germany 2 India 1 Japan 1 Singapore 1 Switzerland 1 United Kingdom 3 United States 9 Global 75
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View Lastest Price from 2-(TRIMETHYLSILYLOXY)FURAN manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
2-(TRIMETHYLSILYLOXY)FURAN 61550-02-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
2-(TRIMETHYLSILYLOXY)FURAN 61550-02-5
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons/month
Release date
2020-01-09

61550-02-5, 2-(TRIMETHYLSILYLOXY)FURANRelated Search:

4,5-Dihydro-3α,4α-bis(trimethylsilyloxy)furan-2(3H)-one 2-(TRIMETHYLSILYLOXY)FURAN

  • TRIMETHYLSILYLOXYFURAN
  • 2-(TRIMETHYLSILOXY)FURAN
  • 2-(TRIMETHYLSILYLOXY)FURAN
  • (2-FURANYLOXY)TRIMETHYLSILANE
  • 2-(TRIMETHYLSILOXY)FURAN, STAB.
  • 2-(Trimethylsilyloxy)furane
  • (2-Furyloxy)trimethylsilane
  • [(2-Furyl)oxy]trimethylsilane
  • 2-Furyl(trimethylsilyl) ether
  • 2-Furyloxytrimethylsilane
  • Trimethyl(2-furanyloxy)silane
  • (furan-2-yloxy)triMethylsilane
  • 2-(TriMethylsiloxy)furan 97%
  • 2- triMethylsilyloxyindane furan
  • Furan, 2-[(trimethylsilyl)oxy]-
  • 61550-02-5
  • Monoalkoxysilanes
  • Building Blocks
  • Si-O Compounds
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Heterocyclic Building Blocks
  • Furans
  • Monoalkoxysilanes
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Si-O Compounds
  • Synthetic Organic Chemistry
  • Building Blocks
  • Furans
  • Heterocyclic Building Blocks