4-(2-FURYL)ANILINE
- Product Name
- 4-(2-FURYL)ANILINE
- CAS No.
- 59147-02-3
- Chemical Name
- 4-(2-FURYL)ANILINE
- Synonyms
- AKOS BAR-0084;4-Fur-2-ylaniline;4-(2-FURYL)ANILINE;CHEMBRDG-BB 4003073;4-(Furan-2-yl)aniline;2-(4-Aminophenyl)furan;4-(2-Furyl)aniline 97%;4-(Fur-2-yl)aniline 97%;4-FURAN-2-YL-PHENYLAMINE;4-(2-Furanyl)benzenamine
- CBNumber
- CB0749194
- Molecular Formula
- C10H9NO
- Formula Weight
- 159.18
- MOL File
- 59147-02-3.mol
4-(2-FURYL)ANILINE Property
- Melting point:
- 55.5-57
- Boiling point:
- 276.8±15.0 °C(Predicted)
- Density
- 1.138±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- solid
- pka
- 3.99±0.10(Predicted)
- color
- Orange-brown
- CAS DataBase Reference
- 59147-02-3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H227Combustible liquid
H302Harmful if swallowed
H318Causes serious eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- CBR00754
- Product name
- 4-(2-Furyl)aniline hydrochloride
- Purity
- Aldrich<SUP>CPR</SUP>
- Packaging
- 1 g
- Price
- $216
- Updated
- 2025/07/31
- Product number
- Y9561
- Product name
- 4-(2-Furyl)aniline
- Packaging
- 1g
- Price
- $350
- Updated
- 2021/12/16
- Product number
- 081153
- Product name
- 4-(2-Furyl)aniline
- Purity
- 97%
- Packaging
- 1g
- Price
- $360
- Updated
- 2021/12/16
- Product number
- CM253868
- Product name
- 4-(Furan-2-yl)aniline
- Purity
- 95%
- Packaging
- 5g
- Price
- $468
- Updated
- 2021/12/16
- Product number
- CD11098370
- Product name
- 4-(Furan-2-yl)aniline
- Purity
- 95+%
- Packaging
- 5g
- Price
- $495
- Updated
- 2021/12/16
4-(2-FURYL)ANILINE Chemical Properties,Usage,Production
Definition
ChEBI: 4-(2-Furyl)aniline is a substituted aniline.
Synthesis
13331-23-2
540-37-4
59147-02-3
General procedure for the synthesis of 4-(furan-2-yl)aniline from 2-furanboronic acid and p-iodoaniline: to a 20 mL Schlenk tube equipped with a magnetic stirrer were added sequentially p-iodoaniline (2 mmol), 2-furanboronic acid (2.4 mmol), K2CO3 (5 mmol), 10 mL of mixed solvents [H2O, H2O-MeOH (1:1), H2O-EtOH (1:1), H2O-EG (1:1)] and 0.01 M palladium catalyst PdCl2(L)2 or Pd[(L)4]Cl2 in MeOH (0.001-0.2 mol%). The reaction mixture was placed in a preheated oil bath and the temperature was set according to the solvent: 100°C for MeOH-H2O, 110°C for EtOH-H2O, 140°C for pure H2O, and 160°C for EG-H2O, and stirred under reflux conditions for the indicated time. Upon completion of the reaction, the mixture was cooled to room temperature, acidified with 5 M HCl (if desired), and subsequently diluted with 10 mL of H2O and 10 mL of Et2O (or EtOAc). The organic phase was separated and the aqueous phase was extracted with Et2O (or EtOAc) (2 x 10 mL). The organic layers were combined and washed sequentially with H2O (10 mL), saturated saline (10 mL) and dried over anhydrous Na2SO4. The ether solution was filtered through a silica gel short column and the filtrate was concentrated under reduced pressure to give pure 4-(furan-2-yl)aniline.
References
[1] Catalysis Communications, 2016, vol. 79, p. 17 - 20
4-(2-FURYL)ANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
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