ChemicalBook > CAS DataBase List > 2-FLUORO-4-PYRIDINEMETHANOL

2-FLUORO-4-PYRIDINEMETHANOL

Product Name
2-FLUORO-4-PYRIDINEMETHANOL
CAS No.
131747-60-9
Chemical Name
2-FLUORO-4-PYRIDINEMETHANOL
Synonyms
(2-Fluoropyridin-4-yl)methanol;2-FLUORO-4-PYRIDINEMETHANOL;(2-fluoro-4-pyridyl)methanol;4-PyridineMethanol, 2-fluoro-;2-Fluoro-4-hydroxymethylpyridine;2-Fluoro-4-pyridinemethanol ,96%;4-Pyridinemethanol,2-fluoro-(9CI);(2-fluoro-4-pyridyl)methanol - [F82319]
CBNumber
CB0752138
Molecular Formula
C6H6FNO
Formula Weight
127.12
MOL File
131747-60-9.mol
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2-FLUORO-4-PYRIDINEMETHANOL Property

Melting point:
59.3-60.4 °C
Boiling point:
247.4±25.0 °C(Predicted)
Density 
1.262±0.06 g/cm3(Predicted)
storage temp. 
Storage temp. 2-8°C
form 
solid
pka
13.05±0.10(Predicted)
Appearance
White to off-white Solid
InChIKey
IAFXOPAZVVMMLE-UHFFFAOYSA-N
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Safety

Hazard Codes 
F
Risk Statements 
10-36/37/38-20/21/22
Safety Statements 
16-26-36
HazardClass 
IRRITANT
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
MNO000064
Product name
(2-Fluoropyridin-4-yl)methanol
Purity
Aldrich
Packaging
1g
Price
$185
Updated
2025/07/31
TRC
Product number
B435035
Product name
(2-Fluoropyridin-4-yl)methanol
Packaging
50mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
064055
Product name
(2-Fluoropyridin-4-yl)methanol
Purity
97%
Packaging
1g
Price
$69
Updated
2021/12/16
SynQuest Laboratories
Product number
4H01-3-32
Product name
(2-Fluoropyridin-4-yl)methanol
Purity
97%
Packaging
250mg
Price
$113
Updated
2021/12/16
Apolloscientific
Product number
PC905392
Product name
(2-Fluoropyridin-4-yl)methanol
Purity
98%
Packaging
1g
Price
$232
Updated
2021/12/16
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2-FLUORO-4-PYRIDINEMETHANOL Chemical Properties,Usage,Production

Chemical Properties

Light yellow low melting solid

Synthesis

1006300-11-3

131747-60-9

General procedure for the synthesis of 2-fluoro-4-pyridinemethanol (37) from 2-fluoro-4-pyridinecarboxylic acid phenylmethyl ester (36) (4.536 g, 19.62 mmol): to a stirred solution of 2-fluoro-4-pyridinecarboxylic acid phenylmethyl ester (36) in anhydrous methanol (40 mL) was added sodium methanolate (1.06 g, 19.62 mmol) under ice bath cooling. After stirring for 30 min, an excess of ammonium chloride was added to the reaction mixture. Subsequently, the mixture was concentrated by evaporation under vacuum and the residue was purified by silica gel column chromatography (eluent: ether/hexane, 1:1, v/v) to afford 2.34 g (94% yield) of 2-fluoro-4-pyridinylmethanol (37) as a white solid with a melting point of 70-71°C. 1H NMR (200 MHz, CDCl3) δ: 2.40 (1H, t, J = 4.0 Hz), 4.78 (2H, d, J = 4.0 Hz), 6.97 (1H, s), 7.15 (1H, m), 8.15 (1H, d, J = 5.0 Hz); Mass Spectrum (EI): m/z 127 (M+).

References

[1] Patent: US2008/70920, 2008, A1. Location in patent: Page/Page column 37-38
[2] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 5, p. 1585 - 1588

2-FLUORO-4-PYRIDINEMETHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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2-FLUORO-4-PYRIDINEMETHANOL Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
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China
ProdList
15883
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64
SynAsst Chemical.
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021-60343070
Fax
021-35122006
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China
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12740
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Amatek Scientific Co. Ltd.
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0512-56316828 4008675858
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+86-512-56316826
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sales@amateksci.com
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Bide Pharmatech Ltd.
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400-164-7117 13681763483
Fax
+86-21-61629029
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product02@bidepharm.com
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China
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42446
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Bellen Chemistry Co., Ltd.
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010-60400365-8001 15910885229
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010-60400361
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service@bellenchem.com
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China
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JW & Y Pharmlab Co., Ltd.
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021-64340559 13651849907;
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021- 64345308
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China
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Shanghai Chenzhu Pharmaceutical Co., Ltd.
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13162380607
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QQ:1696175688
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1696175688@qq.com
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China
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parabiochem
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025-83453382-8005
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025-83453382
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sale@parabiochem.com
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China
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9595
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ChengDu TongChuangYuan Pharmaceutical Co.Ltd
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028-83379370 13880556291
Fax
028-87747383
Email
tcy@tcypharm.com
Country
China
ProdList
7218
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58
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View Lastest Price from 2-FLUORO-4-PYRIDINEMETHANOL manufacturers

Career Henan Chemical Co
Product
2-FLUORO-4-PYRIDINEMETHANOL 131747-60-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KGS
Release date
2020-01-02