5-Benzyloxyindole
- Product Name
- 5-Benzyloxyindole
- CAS No.
- 1215-59-4
- Chemical Name
- 5-Benzyloxyindole
- Synonyms
- NSC 62895;bredreck`s;5-Benzyindole;5-BENZYLOXYINDOLE;5-benzyloxy-indol;Benzyloxy-5 indole;BENZYLOXYINDOLE(5-);TIMTEC-BB SBB003331;5-BENZYLOXY-1H-INDOLE;5-Benzyloxyindole,95%
- CBNumber
- CB0772987
- Molecular Formula
- C15H13NO
- Formula Weight
- 223.27
- MOL File
- 1215-59-4.mol
5-Benzyloxyindole Property
- Melting point:
- 100-104 °C (lit.)
- Boiling point:
- 364.56°C (rough estimate)
- Density
- 1.0707 (rough estimate)
- refractive index
- 1.5500 (estimate)
- storage temp.
- 2-8°C
- solubility
- ethanol: may be hazy yellow
- form
- powder
- pka
- 16.63±0.30(Predicted)
- color
- white to light yellow
- BRN
- 173532
- Exposure limits
- ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) - CAS DataBase Reference
- 1215-59-4(CAS DataBase Reference)
- NIST Chemistry Reference
- 1H-indole, 5-(phenylmethoxy)-(1215-59-4)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-24/25-22
- WGK Germany
- 3
- RTECS
- NL4850000
- F
- 8-10
- HazardClass
- IRRITANT
- HS Code
- 29339990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H333May be harmful if inhaled
H335May cause respiratory irritation
H361Suspected of damaging fertility or the unborn child
- Precautionary statements
-
P201Obtain special instructions before use.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B27803
- Product name
- 5-(Benzyloxy)indole
- Purity
- 95%
- Packaging
- 5g
- Price
- $33.7
- Updated
- 2024/03/01
- Product number
- B27803
- Product name
- 5-(Benzyloxy)indole
- Purity
- 95%
- Packaging
- 25g
- Price
- $90.9
- Updated
- 2024/03/01
- Product number
- B1833
- Product name
- 5-Benzyloxyindole
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 5g
- Price
- $114
- Updated
- 2024/03/01
- Product number
- B25143
- Product name
- 5-Benzyloxyindole, 94%, may contain up to ca 7% toluene
- Packaging
- 1g
- Price
- $36.5
- Updated
- 2024/03/01
- Product number
- B25143
- Product name
- 5-Benzyloxyindole, 94%, may contain up to ca 7% toluene
- Packaging
- 5g
- Price
- $107
- Updated
- 2024/03/01
5-Benzyloxyindole Chemical Properties,Usage,Production
Chemical Properties
Off-white to beige powder
Uses
Reactant in regio- and stereoselective morpholine-catalyzed direct C-3 alkenylation with α,β-unsaturated aldehydes Reactant in selective debenzylation of protective groups using SiliaCat-palladium under mild reaction conditions Reactant in metal-free Friedel-Crafts alkylation reactions Reactant in preparation of protein kinase (PKC) inhibitors Reactant in preparation of indole/quinoline carbothioic acid amide derivatives.
Uses
- Reactant in regio- and stereoselective morpholine-catalyzed direct C-3 alkenylation with α,β-unsaturated aldehydes
- Reactant in selective debenzylation of protective groups using SiliaCat-palladium under mild reaction conditions
- Reactant in metal-free Friedel-Crafts alkylation reactions
- Reactant in preparation of protein kinase (PKC) inhibitors
- Reactant in preparation of indole/quinoline carbothioic acid amide derivatives
Uses
5-Benzyloxyindole is used as reagent/reactant in regioselective preparation of CF3-β-tryptamine derivatives via base-free thermal ring-opening reaction of N-nosyl-2-CF3-aziridine with indoles.
Purification Methods
It is recrystallised from *C6H6/pet ether or pet ether. The picrate forms red crystals from *C6H6 and has m 142-143o. [Burton & Leong Chem Ind (London) 1035 1953, Ek & Witkop J Am Chem Soc 76 5579 1954, fluorescence: Bridges & Williams Biochem J 107 225 1968, Beilstein 27 III/IV 1758.]
5-Benzyloxyindole Preparation Products And Raw materials
Raw materials
Preparation Products
5-Benzyloxyindole Suppliers
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
- sales@tcieurope.eu
- Country
- Europe
- ProdList
- 23680
- Advantage
- 75
View Lastest Price from 5-Benzyloxyindole manufacturers
- Product
- 5-Benzyloxyindole 1215-59-4
- Price
- US $10.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-28
- Product
- 5-Benzyloxyindole 1215-59-4
- Price
- US $24.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-12-27
- Product
- 5-Benzyloxyindole 1215-59-4
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-09-18