Description Preparation Genotoxicity Reaction
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Methyl benzenesulfonate

Description Preparation Genotoxicity Reaction
Product Name
Methyl benzenesulfonate
CAS No.
80-18-2
Chemical Name
Methyl benzenesulfonate
Synonyms
BENZENESULFONIC ACID METHYL ESTER;Methyl Besylate;20ND3-5;nsc06624;ai3-06624;AKOS BBS-00004424;Methyl benzenesulfon;Methylbenzoxysulfonate;METHYL BENZENESULFONATE;Methyl Benzensulfonate
CBNumber
CB0776273
Molecular Formula
C7H8O3S
Formula Weight
172.2
MOL File
80-18-2.mol
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Methyl benzenesulfonate Property

Melting point:
-4 °C
Boiling point:
147-150°C 13mm
Density 
1.3
refractive index 
1.514-1.516
Flash point:
143 °C
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
Liquid
color 
Clear colorless to slightly yellow
Water Solubility 
Miscible with chloroform, methanol, ethanol and ether. Immiscible with water.
BRN 
908448
InChIKey
CZXGXYBOQYQXQD-UHFFFAOYSA-N
CAS DataBase Reference
80-18-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzenesulfonic acid, methyl ester(80-18-2)
EPA Substance Registry System
Benzenesulfonic acid, methyl ester (80-18-2)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34-22-43
Safety Statements 
28A-26-45-36/37/39
RIDADR 
3265
WGK Germany 
3
RTECS 
DB7151000
Hazard Note 
Irritant/Corrosive
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29051990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
165956
Product name
Methyl benzenesulfonate
Purity
98%
Packaging
100g
Price
$135
Updated
2024/03/01
Sigma-Aldrich
Product number
165956
Product name
Methyl benzenesulfonate
Purity
98%
Packaging
500g
Price
$479
Updated
2024/03/01
TCI Chemical
Product number
B0033
Product name
Methyl Benzenesulfonate
Purity
>98.0%(GC)
Packaging
25mL
Price
$39
Updated
2024/03/01
TCI Chemical
Product number
B0033
Product name
Methyl Benzenesulfonate
Purity
>98.0%(GC)
Packaging
100mL
Price
$98
Updated
2024/03/01
Alfa Aesar
Product number
B24515
Product name
Methyl benzenesulfonate, 98%
Packaging
25g
Price
$45.65
Updated
2024/03/01
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Methyl benzenesulfonate Chemical Properties,Usage,Production

Description

Methyl benzenesulfonate is used as a raw material for the dye and pharmaceutical industries, used as an alkylating agent in organic synthesis for the production of some synthetic dye. It can also be used for the manufacturing the thin-cation exchanger film.

Preparation

Methyl benzenesulfonate is the effective methylating reagent of synthetic multiple organic intermediate, and industry is at present gone up and mainly adopted Phenylsulfonic acid and methyl alcohol to carry out after the esterification essence to steam, this technology starting material costliness, and reaction time is long, and product yield is low. How to get Methyl benzenesulfonate with high yield, scientists have lots of researcher.

Genotoxicity

Methyl benzenesulfonate is a sulfonate ester which acts as a potential genotoxic impurity in drug substances. Further, it exerts genotoxic effects in bacterial and mammalian cell systems. Incompatible with strong oxidizing agents, strong acids and strong bases.

Reaction

V. M. Nesterov and I. E. Chubova prepared theobromine from 3-methylxanthine, methyl benzenesulfonate, which has been used as the methylating agent. To obtain theobromine, 3-methylxanthine is generally methylated with dimethyl sulfate in an aqueous ethanolic solution of caustic potash. However, if in the reaction the pH exceeds 8.0, the methylation of 3-methylxanthine leads to caffeine, which forms a by-product.

Chemical Properties

clear colourless to slightly brown liquid

Uses

A sulfonate ester as potential genotoxic impurity in drug substances.

Uses

Methyl benzenesulfonate is a sulfonate ester which acts as a potential genotoxic impurity in drug substances. Further, it exerts genotoxic effects in bacterial and mammalian cell systems.

Methyl benzenesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl benzenesulfonate Suppliers

Shouguang Nuomeng Chemical Co Ltd.
Tel
536-5399456 13869682027
Fax
0536-5399456
Email
1972085497@qq.com
Country
China
ProdList
47
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9809
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8836
Advantage
52
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View Lastest Price from Methyl benzenesulfonate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Methyl benzenesulfonate 80-18-2
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-20
Shouguang Nuomeng Chemical Co Ltd.
Product
Methyl Benzenesulfonate, Methyl Benzene sulfonate 80-18-2
Price
US $4200.00/T
Min. Order
1KG
Purity
99% Min.
Supply Ability
200 tons per month
Release date
2020-07-21
Hebei Weibang Biotechnology Co., Ltd
Product
Methyl benzenesulfonate 80-18-2
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-05

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