ChemicalBook > CAS DataBase List > METHYL 3-METHYL-2-FUROATE

METHYL 3-METHYL-2-FUROATE

Product Name: METHYL 3-METHYL-2-FUROATE
CAS No.: 6141-57-7
Chemical Name: METHYL 3-METHYL-2-FUROATE
Synonyms: NSC 508754;Methyl 3-Methylfuroate;METHYL 3-METHYL-2-FUROATE;Methyl3-methyl-2-furoate,98%;Methyl 3-methyl-2-furoate 96%;Methyl 3-Methyl-2-furancarboxylate;Methyl 3-Methylfuran-2-carboxylate;Methyl3-Methyl-2-furancarboxylate>3-METHYLFURAN-2-CARBOXYLIC ACID METHYL ESTER;3-Methyl-2-furancarboxylic acid methyl ester
CBNumber: CB1104448
Molecular Formula: C7H8O3
Formula Weight: 140.14
MOL File: 6141-57-7.mol

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METHYL 3-METHYL-2-FUROATE Property

Melting point:: 32-36 °C
Boiling point:: 60 °C (1 mmHg)
Density: 1.1624 (rough estimate)
refractive index: 1.4850 (estimate)
Flash point:: 60°C/1mm
storage temp.: Sealed in dry,Room Temperature
form: Crystalline Low Melting Mass
color: White
Water Solubility: Insoluble in water.
BRN: 116835
InChI: InChI=1S/C7H8O3/c1-5-3-4-10-6(5)7(8)9-2/h3-4H,1-2H3
InChIKey: AQQYRDKMXXSIMP-UHFFFAOYSA-N
SMILES: O1C=CC(C)=C1C(OC)=O
LogP: 1.510
CAS DataBase Reference: 6141-57-7(CAS DataBase Reference)

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Safety

Safety Statements: 24/25-22
WGK Germany: 3
HS Code: 29321900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 667986
Product name: Methyl 3-methyl-2-furoate
Purity: 96%
Packaging: 1g
Price: $32.2
Updated: 2023/06/20

Sigma-Aldrich

Product number: 667986
Product name: Methyl 3-methyl-2-furoate
Purity: 96%
Packaging: 5g
Price: $114
Updated: 2023/06/20

TCI Chemical

Product number: M2377
Product name: Methyl 3-Methyl-2-furancarboxylate
Purity: >98.0%(GC)
Packaging: 1g
Price: $45
Updated: 2025/07/31

TCI Chemical

Product number: M2377
Product name: Methyl 3-Methyl-2-furancarboxylate
Purity: >98.0%(GC)
Packaging: 5g
Price: $132
Updated: 2025/07/31

TRC

Product number: M322650
Product name: Methyl3-Methylfuroate
Packaging: 1g
Price: $130
Updated: 2021/12/16

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METHYL 3-METHYL-2-FUROATE Chemical Properties,Usage,Production

Chemical Properties

white crystalline low melting mass

Uses

Methyl 3-methyl-2-furoate is an important raw material used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.It is a volatile substance in the unfermented apple pomace.

Uses

Methyl 3-Methylfuroate is a volatile substance in the unfermented apple pomace.

Synthesis Reference(s)

The Journal of Organic Chemistry, 21, p. 102, 1956 DOI: 10.1021/jo01107a021

Synthesis

5436-21-5

96-34-4

6141-57-7

GENERAL STEPS: 4,4-dimethoxy-2-butanone (80 mL, 0.60 mol) and methyl chloroacetate (90 mL, 1.03 mol) were added to stirred ether (500 mL) under nitrogen protection and cooled to -5°C. The reaction temperature was kept at -5°C for a few minutes. Sodium methanol (54 g, 1.00 mol) was added slowly, keeping the reaction temperature at -5 °C. The reaction mixture was stirred at -5 °C for 2 h and then brought to room temperature and continued to stir overnight. Upon completion of the reaction, a mixture of glacial acetic acid (7 mL) and water (93 mL) was slowly added at 0 °C. The organic layer was separated and the aqueous phase was washed with ether. The organic layers were combined, washed with saturated sodium bicarbonate solution, then brine, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The residue was purified by distillation (boiling point 72-78 °C/8 mmHg) to give 2-methoxycarbonyl-3-methylfuran (71 g, 0.51 mol, 85% yield). 2-Methoxycarbonyl-3-methylfuran (26 g, 0.19 mol) was mixed with 20% aqueous sodium hydroxide solution (60 mL) and stirred at reflux for 2 hours. After cooling to 0 °C, concentrated hydrochloric acid (35 mL) was slowly added to precipitate colorless crystals of 3-methylfuran-2-carboxylic acid (3.20 g, 15% yield). A mixture of 3-methylfuran-2-carboxylic acid (3.20 g, 29 mmol), copper powder (0.90 g, 14.2 mmol), and quinoline (10 mL, 84.4 mmol) was heated to 260 °C, and a fraction with a boiling point of 65.5 °C was collected to give 3-methylfuran (colorless liquid, 65-70% yield).

References

[1] Journal of Photochemistry and Photobiology A: Chemistry, 2017, vol. 349, p. 7 - 17
[2] Journal of Organic Chemistry, 1956, vol. 21, p. 102
[3] Org. Synth. Coll. Vol., 1963, vol. IV, p. 628
[4] Tetrahedron, 1998, vol. 54, # 26, p. 7525 - 7538

METHYL 3-METHYL-2-FUROATE Preparation Products And Raw materials

Raw materials

Ethanol Acetylacetaldehyde dimethyl acetal Sodium chloride Sodium Diethyl ether Hydrochloric acid Acetic acid Methanol Sodium hydroxide Magnesium sulfate Methyl chloroacetate

Preparation Products

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View Lastest Price from METHYL 3-METHYL-2-FUROATE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Methyl 3-Methylfuran-2-carboxylate 6141-57-7
Price: US $2.20-8.80/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-24

Zhuozhou Wenxi import and Export Co., Ltd

Product: METHYL 3-METHYL-2-FUROATE 6141-57-7
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: METHYL 3-METHYL-2-FUROATE 6141-57-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-08

6141-57-7, METHYL 3-METHYL-2-FUROATERelated Search:

METHYL 3-METHYL-2-FUROATE 3-Furancarboxylicacid,5-methyl-,methylester(9CI) METHYL 5-(CHLOROMETHYL)-2-FUROATE METHYL 5-METHYL-2-FUROATE METHYL 2-METHYL-3-FUROATE 2-Furoic acid 3-Methyl-2-furoic acid Methyl 2-furoate 7-CHLORO-3-METHYL-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER 5-METHOXY-3-METHYL-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER 3-METHYLBENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER METHYL 3-METHYL-4-OXO-4,5,6,7-TETRAHYDRO-1-BENZOFURAN-2-CARBOXYLATE CHEMBRDG-BB 5137792 ETHYL 4-HYDROXY-3-METHYLBENZOFURAN-2-CARBOXYLATE METHYL 3-([[AMINO(IMINO)METHYL]THIO]METHYL)-2-FUROATE METHYL 3,6,6-TRIMETHYL-4-OXO-4,5,6,7-TETRAHYDRO-1-BENZOFURAN-2-CARBOXYLATE 5-BROMO-3-BROMOMETHYL-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER SALOR-INT L306053-1EA

3-METHYLFURAN-2-CARBOXYLIC ACID METHYL ESTER

METHYL 3-METHYL-2-FUROATE

Methyl3-methyl-2-furoate,98%

3-Methyl-2-furancarboxylic acid methyl ester

Methyl 3-Methylfuran-2-carboxylate

Methyl 3-Methyl-2-furancarboxylate

Methyl 3-Methylfuroate

NSC 508754

Methyl 3-methyl-2-furoate 96%

Methyl3-Methyl-2-furancarboxylate&gt

2-Furancarboxylic acid, 3-methyl-, methyl ester

6141-57-7

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