Methyl 2-furoate

Product Name: Methyl 2-furoate
CAS No.: 611-13-2
Chemical Name: Methyl 2-furoate
Synonyms: METHYL FURAN-2-CARBOXYLATE;2-FURANCARBOXYLIC ACID METHYL ESTER;MEFAT;FEMA 2703;2-METHYLFUROATE;Methyle furoate;METHYL 2-FUROATE;METHYL PYROMUCATE;Methyl 2-furanoate;RARECHEM AL BF 0007
CBNumber: CB3306772
Molecular Formula: C6H6O3
Formula Weight: 126.11
MOL File: 611-13-2.mol

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Methyl 2-furoate Property

Boiling point:: 181 °C (lit.)
Density: 1.179 g/mL at 25 °C (lit.)
refractive index: n20/D 1.487(lit.)
FEMA: 2703 | METHYL 2-FUROATE
Flash point:: 164 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Liquid
color: Clear pale yellow to brown
Odor: fruity, mushroom-like odor
Odor Type: fungal
Water Solubility: slightly soluble
Sensitive: Lachrymatory
JECFA Number: 746
Merck: 14,4307
BRN: 111110
LogP: 0.99
CAS DataBase Reference: 611-13-2(CAS DataBase Reference)
NIST Chemistry Reference: Methyl 2-furoate(611-13-2)
EPA Substance Registry System: 2-Furancarboxylic acid, methyl ester (611-13-2)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 36/37/38-21/22-22
Safety Statements: 26-36-36/37/39
RIDADR: UN 2810 6.1/PG 3
WGK Germany: 3
RTECS: LV1950000
Hazard Note: Irritant
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29321900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W270318
Product name: Methyl 2-furoate
Purity: ≥98%, FG
Packaging: sample-k
Price: $54.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: W270318
Product name: Methyl 2-furoate
Purity: ≥98%, FG
Packaging: 100g
Price: $75.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: W270318
Product name: Methyl 2-furoate
Purity: ≥98%, FG
Packaging: 1kg
Price: $212
Updated: 2024/03/01

Sigma-Aldrich

Product number: W270318
Product name: Methyl 2-furoate
Purity: ≥98%, FG
Packaging: 5kg
Price: $480
Updated: 2024/03/01

Sigma-Aldrich

Product number: 129852
Product name: Methyl 2-furoate
Purity: 98%
Packaging: 25g
Price: $35.4
Updated: 2024/03/01

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Methyl 2-furoate Chemical Properties,Usage,Production

Description

Methyl 2-furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy. May be prepared from 2-furoic acid in methanol solution in the presence of HCL as catalyst (oxidation or Carmizzaro reaction).

Chemical Properties

Methyl furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy

Chemical Properties

Colorless to light yellow liqui

Occurrence

Reported found in cranberry, guava, baked potato, raisin, papaya, blackberry, baked potato, tomato, cognac, coffee, filbert, peanut, cocoa, passion fruit, almonds, tamarind, soursop, dried bonito, kiwifruit, mountain papaya, wild rice, okra, grape brandy and roasted hazelnut.

Uses

Solvent, organic synthesis.

Uses

Methyl 2-furoate (Methyl furan-2-carboxylate, Methyl pyromucate) was used to synthesize cis-fused 5-oxofuro[2,3-b]furans. It was also used in the preparation of sesquiterpene lactone.

Preparation

From 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)

Definition

ChEBI: Methyl 2-Furancarboxylate is a carboxylic ester. It is functionally related to a 2-furoic acid.

Aroma threshold values

Aroma characteristics at 1.0%: musty, sweet caramel, fruity, cocoa, bready and slightly rubbery.

Taste threshold values

Taste characteristics at 20 ppm: brothy, yeasty, caramellic and burnt with a sweet bready, acetoin, buttery nuance

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 37, p. 3225, 1989 DOI: 10.1248/cpb.37.3225

General Description

Methyl 2-furoate has been identified as one of the volatile flavor compounds in tequila, okra, berrycactus and black currant juice.

Safety Profile

Poison by intraperitoneal route. A skin irritant and lachrymator. When heated to decomposition it emits acrid smoke and irritating fumes.

Methyl 2-furoate Preparation Products And Raw materials

Raw materials

2-Furoic acid

Preparation Products

METHYL 5-NITRO-2-FUROATE

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Methyl 2-furoate Suppliers

Americas 1 Belgium 3 China 315 Europe 1 France 1 Germany 8 India 31 Japan 6 Singapore 1 Slovakia 1 South Korea 1 Switzerland 3 Ukraine 1 United Kingdom 24 United States 68 USA 1 Global 466

J & K SCIENTIFIC LTD.

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View Lastest Price from Methyl 2-furoate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Methyl 2-Furoate 611-13-2
Price: US $75.00-20.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-06-03

Hebei Weibang Biotechnology Co., Ltd

Product: Methyl 2-furoate 611-13-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-31

Hebei Yanxi Chemical Co., Ltd.

Product: Methyl 2-furoate 611-13-2
Price: US $20.00-1.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-03

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