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4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE

Product Name
4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE
CAS No.
2450-27-3
Chemical Name
4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE
Synonyms
4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE;3-Methoxy-2-nitro-4-(phenylmethoxy)benzaldehyde;Benzaldehyde, 3-methoxy-2-nitro-4-(phenylmethoxy)-
CBNumber
CB11109761
Molecular Formula
C15H13NO5
Formula Weight
287.27
MOL File
Mol file
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4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE Property

Melting point:
111.5-112.5 °C
Boiling point:
487.8±45.0 °C(Predicted)
Density 
1.296±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Matrix Scientific
Product number
114401
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenzaldehyde
Purity
97%
Packaging
1g
Price
$764
Updated
2021/12/16
AK Scientific
Product number
5479CC
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenzaldehyde
Packaging
5g
Price
$1680
Updated
2021/12/16
Ambeed
Product number
A125613
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenzaldehyde
Purity
97%
Packaging
100mg
Price
$115
Updated
2021/12/16
Atlantic Research Chemicals
Product number
AH001223
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenaldehyde
Purity
95%
Packaging
250mgs:
Price
$173.19
Updated
2021/12/16
Crysdot
Product number
CD12092290
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenzaldehyde
Purity
97%
Packaging
250mg
Price
$178
Updated
2021/12/16
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4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE Chemical Properties,Usage,Production

Synthesis

2450-26-2

100-39-0

2450-27-3

Step 3: Preparation of 4-(benzyloxy)-3-methoxy-2-nitrobenzaldehyde; 4-hydroxy-3-methoxy-2-nitrobenzaldehyde (155 g, 786 mmol) was dissolved in N,N-dimethylformamide (DMF, 1500 mL), and potassium carbonate (217 g, 1.57 mol) and benzyl bromide (161 g, 0.94 mol). The reaction mixture was stirred at room temperature for 16 h. Most of the DMF was removed by distillation under reduced pressure. the organic layer was separated by partitioning the residue between water (2 L) and ethyl acetate (EtOAc, 2 L). The organic layer was washed with saturated saline (3 x 2 L), dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting solid was ground with ether (Et2O, 1 L) to afford the target compound 4-(benzyloxy)-3-methoxy-2-nitrobenzaldehyde (220 g, 97% yield).1H NMR (DMSO-d6) δ: 9.77 (1H, s), 7.87 (1H, d), 7.58 (1H, d), 7.51 (1H, m), 7.49 (1H, m) , 7.39 (3H, m), 5.36 (2H, s), 3.05 (3H, s).

References

[1] Patent: WO2008/70150, 2008, A1. Location in patent: Page/Page column 66
[2] Tetrahedron, 2009, vol. 65, # 16, p. 3246 - 3260
[3] Patent: WO2012/62748, 2012, A1. Location in patent: Page/Page column 56
[4] Patent: WO2012/62743, 2012, A1. Location in patent: Page/Page column 60
[5] Patent: WO2012/62745, 2012, A1. Location in patent: Page/Page column 61

4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE Suppliers

China 29 India 2 United States 3 Global 34
Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
52923
Advantage
58
Synthonix Inc
Tel
--
Fax
--
Email
info@synthonix.com
Country
United States
ProdList
6872
Advantage
58
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80

2450-27-3, 4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDERelated Search:

3-Methoxy-2-nitrobenzaldehyde Vanillin

  • 4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE
  • Benzaldehyde, 3-methoxy-2-nitro-4-(phenylmethoxy)-
  • 3-Methoxy-2-nitro-4-(phenylmethoxy)benzaldehyde
  • 2450-27-3