3-Bromomethyl-3-oxetanemethanol
- Product Name
- 3-Bromomethyl-3-oxetanemethanol
- CAS No.
- 22633-44-9
- Chemical Name
- 3-Bromomethyl-3-oxetanemethanol
- Synonyms
- 3-BroMoMethyl-3-(hydroxyM...;3-Bromomethyl-3-oxetanemethanol;3-Oxetanemethanol, 3-(bromomethyl)-;3-Bromomethyl-3-oxetanemethanol,95%;[3-(Bromomethyl)-3-oxetanyl]methanol;3-Bromomethyl-3-hydroxymethyloxetane;[3-(BROMOMETHYL)OXETAN-3-YL]METHANOL;3-bromomethyl-3-hydroxymethyl-1-oxacyclobutane;(3-(Bromomethyl)oxetan-3-yl)methanol - [B5888];2-(Bromomethyl)-2-(hydroxymethyl)-1,3-epoxypropane
- CBNumber
- CB11122339
- Molecular Formula
- C5H9BrO2
- Formula Weight
- 181.03
- MOL File
- 22633-44-9.mol
3-Bromomethyl-3-oxetanemethanol Property
- Boiling point:
- 242℃
- Density
- 1.598
- refractive index
- 1.5130 to 1.5170
- Flash point:
- 100°(212°F)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- clear liquid
- pka
- 14.58±0.10(Predicted)
- color
- Colorless to Light yellow
- CAS DataBase Reference
- 22633-44-9
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 23-26-37-60
- RIDADR
- UN3265
- TSCA
- No
- HS Code
- 2932209090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B5442
- Product name
- 3-(Bromomethyl)-3-oxetanemethanol
- Purity
- >97.0%(GC)
- Packaging
- 1g
- Price
- $118
- Updated
- 2024/03/01
- Product number
- B697410
- Product name
- (3-(Bromomethyl)oxetan-3-yl)methanol
- Packaging
- 5g
- Price
- $195
- Updated
- 2021/12/16
- Product number
- B5888
- Product name
- (3-(Bromomethyl)oxetan-3-yl)methanol
- Purity
- 95%
- Packaging
- 1g
- Price
- $20
- Updated
- 2021/12/16
- Product number
- 300341
- Product name
- [3-(Bromomethyl)oxetan-3-yl]methanol, 96%
- Packaging
- 250mg
- Price
- $49.5
- Updated
- 2021/12/16
- Product number
- CS-W019428
- Product name
- (3-(Bromomethyl)oxetan-3-yl)methanol
- Purity
- 98.90%
- Packaging
- 5g
- Price
- $60
- Updated
- 2021/12/16
3-Bromomethyl-3-oxetanemethanol Chemical Properties,Usage,Production
Synthesis
3296-90-0
22633-44-9
A. Synthesis of 3-bromomethyl-3-hydroxymethyl oxetane 2,2-Bis(bromomethyl)propane-1,3-diol (150 g, 0.573 mol) was dissolved in 650 mL of ethanol, followed by the slow addition of an ethanolic solution of sodium ethoxide (21%, 185.74 g, 0.573 mol) over 10 min. The reaction mixture was refluxed for 2 hours followed by stirring at room temperature for 16 hours. After completion of the reaction, the reaction mixture was filtered and the solvent was evaporated to give an oil containing solids. The crude product was dissolved in 200 mL of dichloromethane, filtered and the solvent was evaporated to give 98 g of crude 3-bromomethyl-3-hydroxymethoxetane. The crude product was purified by reduced pressure distillation (113°C, 3 mmHg) to give 52.95 g of pure product in 52% yield. NMR data: 1H NMR (δ, ppm): 3.75 (s, 2H), 3.88 (d, J = 4.9 Hz, 2H), 4.45 (s, 4H). 13C NMR (δ, ppm): 36.336 (t, J = 152.78 Hz), 45.0935 (s), 63.995 (t, J = 143.3 Hz), 77.216 (t, J = 152.78 Hz).
References
[1] Tetrahedron Letters, 2011, vol. 52, # 5, p. 565 - 567
[2] Patent: US5489700, 1996, A
[3] DRP/DRBP Org.Chem.,
[4] Journal of Organic Chemistry, 1956, vol. 21, p. 997
[5] Mededelingen van de Koninklijke Vlaamse Academie voor Wetenschappen, Letteren en Schone Kunsten van Belgie, Klasse der Wetenschappen, 1954, vol. 16, # 8, p. 3,10
3-Bromomethyl-3-oxetanemethanol Preparation Products And Raw materials
Raw materials
Preparation Products
3-Bromomethyl-3-oxetanemethanol Suppliers
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
- sales@tcieurope.eu
- Country
- Europe
- ProdList
- 23671
- Advantage
- 75
View Lastest Price from 3-Bromomethyl-3-oxetanemethanol manufacturers
- Product
- 3-Bromomethyl-3-oxetanemethanol 22633-44-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-12-26